Materials Literature
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Abstract This study explores defect evolution in ceria thin films through combined experimental and theoretical approaches. Structural analyses confirm the retention of the cubic fluorite phase, with Raman spectra revealing additional features associated with oxygen vacancies and lattice disorder. Phonon lifetime eval…
Background/Objectives: Renal ischemia–reperfusion injury (IRI) and infection-associated renal damage are characterized by persistent inflammation, oxidative stress, microvascular dysfunction, and impaired tissue regeneration, creating a hostile microenvironment that limits effective repair. We developed an injectable,…
This study investigated the effect of the partial replacement of silica with carbon fillers, namely carbon black (CB), graphene, and carbon nanotubes (CNTs), on the curing behaviour, thermo-mechanical properties, ageing resistance, and degradation of styrene-butadiene rubber (SBR) vulcanizates. The aim was to determin…
This revised article addresses Q0027, 'Control interfacial assembly of nanoparticles and surfactants?' using a question-specific mathematical construction rather than a generic logarithmic template. The proposed model, termed the Interfacial Assembly Free-Energy Drift Model, uses surface coverage theta, particle order…
This paper develops a revised mathematical solution framework for the chemistry challenge "Create foundation models that generalize across molecules, reactions, spectra, and materials?". The proposed Adapter-Based Chemical Foundation Architecture (ACFA) was constructed after an earlier formulation failed or remained o…
The present work explores the formation of lithium metasilicate (Li2SiO3) crystalline grains in a photosensitive glass similar to Foturan® and the nonlinear optical characteristics displayed by the formed composite material. For partial crystallization of the glass, we applied the conventional three-step procedure: UV…
A novel hydrazone derivative, [(1E,8E)-9-(3-bromo-4-methoxyphenyl)-1,8-bis(2-(2,4-dinitrophenyl) hydrazone)-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine], with the molecular formula C₃₆H₃₆BrN₉O₉, was evaluated as a corrosion inhibitor for mild steel in oil-field water collected from the Niger Delta regio…
Large language models and agentic systems are increasingly embedded across the scientific work-flow, from literature synthesis and hypothesis generation to code execution, data analysis and writing. This broadening of use exposes a mismatch in evaluation: current benchmarks can test whether models answer difficult sci…
Abstract With the rapid advancement and widespread adoption of millimeter-wave technology, developing high-performance microwave-absorbing materials has become critical for addressing electromagnetic interference and radiation pollution. To meet electromagnetic compatibility requirements in the 18−40 GHz frequency ran…
This revised article addresses Q0038, 'Make AI chemical predictions physically constrained and uncertainty-aware?' using a question-specific mathematical construction rather than a generic logarithmic template. The proposed model, termed the Physics-Constrained Calibrated Prediction Model, uses predicted mean yhat, pr…
Abstract Glycated hemoglobin (HbA1c) is an important clinical indicator for the diagnosis and therapeutic monitoring of diabetes mellitus. However, the existing analytical methods, including liquid chromatography, immunoassay, and mass spectrometry, heavily rely on column resolution, extra labeling bioreagents, or cos…
This study investigates the mechanical enhancement of long-fibre hemp non-woven mats—utilising both epoxy and bicomponent polypropylene/polyethylene (PP/PE) binders, through the incorporation of microfibrillated cellulose (MFC) processed at varying energy levels. The research provides a systematic evaluation of these…
In this study, the relationship between the microstructure and electrical conductivity of doped lanthanum gallate was investigated to identify the origin of the relatively high resistivity of the grain boundaries in this ceramic solid electrolyte. LaGaO3 containing acceptor dopants, Sr and Mg, was chemically synthesiz…
Abstract Optoelectronic imaging systems are crucial for various sectors, but traditional designs (traditional optoelectronic imaging systems and traditional computational imaging systems) suffer from complexity, limited multidimensional optical information utilization, and a lack of system-level optimization. Metasurf…
Covalent organic frameworks are a family of porous crystalline structures gaining attention due to their promising applications. However, despite significant efforts, the synthesis and understanding of uniform and specific morphologies remain a challenge. Herein, we report the first self-templated synthesis of hollow…
Chirality, a fundamental property of nature, plays a pivotal role in regulating cell fate and promoting tissue regeneration. Owing to their distinctive stereochemical properties and the inherent chiral selectivity of biological systems, chiral biomaterials offer novel strategies to address the immense clinical demands…
Abstract Accurate assessment of ligand coordinate–density consistency across different resolutions remains challenging in macromolecular crystallography. We introduce the atomic Box Correlation Coefficient (aBCC), an atom-level metric for evaluating the consistency between ligand atomic coordinates and electron densit…
Atomic Layer Deposition of Oxide Semiconductors for UV/Visible Photodetectors and Transparent Electronics" — A literature review synthesizing recent advances in ALD-grown wide-bandgap oxide semiconductors (Ga2O3, ZnO, ZnGaO) for solar-blind and deep-UV photodetection, and amorphous oxide semiconductors (ZnO, IGZO-fami…
Starch-water systems can be structured by extrusion into expanded edible matrices, where water acts simultaneously as a plasticizer, controlling matrix mobility, and as an internal blowing agent, driving vapor-induced expansion at the die exit. The resulting cellular architecture governs density, cell connectivity, an…
FINDING: Penrose tilings are aperiodic, 5-fold symmetric tilings that violate classical crystallographic restrictions, forming the basis for quasicrystal discovery. | MATH: Golden ratio φ = (1+√5)/2 ≈ 1.618; inflation/deflation scaling by φ; 5-fold rotational symmetry forbidden in periodic crystals; matching rules enf…