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Symmetry breaking and gap opening in two-dimensional hexagonal lattices

D. Malterre、B. Kierren、Y. Fagot‐Révurat 等 8 位作者2011-01-19New Journal of Physics

The inhibition in wave propagation at band gap energies plays a central role in many areas of technology such as electronics (electron gaps), nanophotonics (light gaps) and phononics (acoustic gaps), among others. Here we demonstrate that metal surfaces featuring free-electron-like bands may become semiconducting by p…

Graphene research and applicationsQuantum and electron transport phenomenaSurface and Thin Film Phenomena

DNA-Templated Fabrication of Two-Dimensional Metallic Nanostructures by Thermal Evaporation Coating

Yu He、Ye Tao、Alexander E. Ribbe 等 4 位作者2011-01-19Journal of the American Chemical Society

A biotemplating strategy for fabrication of metallic nanoparticle arrays has been developed. The templates are self-assembled DNA nanostructures, which dictate nanoparticle synthesis in the gas-solid phase (during thermal evaporation).

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesBiosensors and Analytical Detection

The archaeal PCNA proteins

Miao Pan、Lori M. Kelman、Zvi Kelman2011-01-19Biochemical Society Transactions

PCNA (proliferating-cell nuclear antigen) is a ring-shaped protein that encircles duplex DNA and plays an essential role in many DNA metabolic processes. The PCNA protein interacts with a large number of cellular factors and modulates their enzymatic activities. In the present paper, we summarize the structures, funct…

DNA Repair MechanismsDNA and Nucleic Acid ChemistryEnzyme Structure and Function

Studying biomolecular complexes with pulsed electron–electron double resonance spectroscopy

Gunnar W. Reginsson、Olav Schiemann2011-01-19Biochemical Society Transactions

The function of biomolecules is intrinsically linked to their structure and the complexes they form during function. Techniques for the determination of structures and dynamics of these nanometre assemblies are therefore important for an understanding on the molecular level. PELDOR (pulsed electron-electron double res…

Photochemistry and Electron Transfer StudiesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Spin-triplet supercurrent in Co-based Josephson junctions

Mazin A. Khasawneh、Trupti Khaire、Carolin Klose 等 5 位作者2011-01-19Superconductor Science and Technology

In the past year several groups have reported experimental evidence for spin-triplet supercurrents in Josephson junctions containing strong ferromagnetic materials. In this paper we present several new experimental results that follow up on our previous work. We study Josephson junctions of the form S/X/N/SAF/N/X/S, w…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsIron-based superconductors research

Synthesis of Aluminosilicate and Gallosilicate Zeolites via a Charge Density Mismatch Approach and Their Characterization

Min Bum Park、Sung June Cho、Suk Bong Hong2011-01-19Journal of the American Chemical Society

Aluminosilicate and gallosilicate zeolite syntheses via a charge density mismatch (CDM) approach are compared at intermediate-silica compositions (Si/Me = 5-16, where Me is Al or Ga). With a variation of the crystallization temperature and of the type and/or concentration of alkali metal ions added as a crystallizatio…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisChemical Synthesis and Characterization

Formation and Evolution Dynamics of Bipolarons in Conjugated Polymers

B. Di、Yichang Meng、Y. D. Wang 等 5 位作者2011-01-19The Journal of Physical Chemistry B

Combining the one-dimensional tight-binding Su-Schrieffer-Heeger (SSH) model and the extended Hubbard model (EHM), we analyze the scattering and combination in conjugated polymers of two polarons with the same charges and parallel or antiparallel spins using a nonadiabatic evolution method. Results show that collision…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Catalytic Mechanism and Three-Dimensional Structure of Adenine Deaminase,

Siddhesh S. Kamat、Ashima Bagaria、D. Kumaran 等 11 位作者2011-01-19Biochemistry

Adenine deaminase (ADE) catalyzes the conversion of adenine to hypoxanthine and ammonia. The enzyme isolated from Escherichia coli using standard expression conditions was low for the deamination of adenine (k(cat) = 2.0 s(-1); k(cat)/K(m) = 2.5 × 10(3) M(-1) s(-1)). However, when iron was sequestered with a metal che…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

I2 basal plane stacking fault in GaN: Origin of the 3.32 eV luminescence band

Ingo Tischer、Martin Feneberg、M. Schirra 等 11 位作者2011-01-19Physical Review B

We investigate the $3.32 \mathrm{eV}$ defect-related emission band in GaN correlating transmission electron microscopy and spatially and spectrally resolved cathodoluminescence at low temperature. The band is unambiguously associated with basal plane stacking faults of type ${I}_{2}$, which are a common defect type in…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Yb3AuGe2In3: An Ordered Variant of the YbAuIn Structure Exhibiting Mixed-Valent Yb Behavior

Maria Chondroudi、Sebastian C. Peter、Christos D. Malliakas 等 6 位作者2011-01-19Inorganic Chemistry

Yb(3)AuGe(2)In(3) was obtained as large single crystals in high yield from reactions run in liquid indium. Single crystal X-ray diffraction data show that Yb(3)AuGe(2)In(3) is an ordered variant of YbAuIn with lattice constants, a = b = 7.3153(8) Å and c = 4.4210(5) Å, and space group P(6)2m. The parent compound YbAuI…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Collagen gel three-dimensional matrices combined with adhesive proteins stimulate neuronal differentiation of mesenchymal stem cells

Jae Ho Lee、Hye‐Sun Yu、Gil‐Su Lee 等 6 位作者2011-01-19Journal of The Royal Society Interface

Three-dimensional gel matrices provide specialized microenvironments that mimic native tissues and enable stem cells to grow and differentiate into specific cell types. Here, we show that collagen three-dimensional gel matrices prepared in combination with adhesive proteins, such as fibronectin (FN) and laminin (LN),…

Bone Tissue Engineering MaterialsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Effect of Concentration on the Glass Transition and Viscoelastic Properties of Poly(methyl methacrylate)/Ionic Liquid Solutions

Michelle M. Mok、Xingcheng Liu、Zhifeng Bai 等 5 位作者2011-01-19Macromolecules

The glass transition behavior and viscoelastic properties of poly(methyl methacrylate) in mixtures with the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide are examined at compositions from 10 wt % polymer to pure polymer, over the temperature range from −180 to 230 °C. Polymers of two diffe…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesIonic liquids properties and applications

High Amplitude Direct Compressive Strain Enhances Mechanical Properties of Scaffold-Free Tissue-Engineered Cartilage

Elisa Hoenig、Thomas E. Winkler、Gabriela Mielke 等 9 位作者2011-01-19Tissue Engineering Part A

Adult cartilage has a limited healing capacity. Damages resulting from disease or injury increase over time and cause severe pain. One approach to reinstate the cartilage function is tissue engineering (TE). However, the generation of TE cartilage is time consuming and expensive and its properties are so far suboptima…

Osteoarthritis Treatment and MechanismsKnee injuries and reconstruction techniquesSilk-based biomaterials and applications

Magnetic Glyconanoparticles as a Versatile Platform for Selective Immunolabeling and Imaging of Cells

Isabel Garcı́a、Juan Gallo、Núria Genicio 等 5 位作者2011-01-19Bioconjugate Chemistry

A versatile nanoplatform based on magnetic glyconanoparticles (glyco-ferrites) to attach well-oriented antibodies is described. An efficient ligand exchange process has been used to prepare water-soluble 6-nm-sized core-shell Fe(3)O(4)@Au nanoparticles bearing amphiphilic carbohydrates and aliphatic ethylene glycol ch…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesMonoclonal and Polyclonal Antibodies Research

Darkfield-Confocal Microscopy detection of nanoscale particle internalization by human lung cells

Eugene A. Gibbs-Flournoy、Philip A. Bromberg、Thomas Hofer 等 5 位作者2011-01-19Particle and Fibre Toxicology

BACKGROUND: Concerns over the health effects of nanomaterials in the environment have created a need for microscopy methods capable of examining the biological interactions of nanoparticles (NP). Unfortunately, NP are beyond the diffraction limit of resolution for conventional light microscopy (~200 nm). Fluorescence…

Advanced Fluorescence Microscopy TechniquesDigital Holography and MicroscopyElectron and X-Ray Spectroscopy Techniques

A Cubic, 12-Connected, Microporous Metal−Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes

Sayon A. Kumalah Robinson、Marion-Vincent L. Mempin、Amy Cairns 等 4 位作者2011-01-19Journal of the American Chemical Society

A rare example of a microporous metal-organic phosphate, [Co(12)(L)(6)(μ(3)-PO(4))(4)(μ(3)-F)(4)(μ-H(2)O)(6)][NO(3)](2) (1), is synthesized by the reaction of a [(η(5)-C(5)H(5))Fe(II)](+)-functionalized terephthalate ligand with Co(NO(3))(2)·6H(2)O and phosphate and fluoride ions generated from the in situ hydrolysis…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Three-dimensional cooling and detection of a nanosphere with a single cavity

Zhang‐qi Yin、Tongcang Li、Mang Feng2011-01-19Physical Review A

We propose an experimental scheme to cool and measure the three-dimensional (3D) motion of an optically trapped nanosphere in a cavity. Driven by three lasers on TEM00, TEM01, and TEM10 modes, a single cavity can cool a trapped nanosphere to the quantum ground states in all three dimensions under the resolved-sideband…

Carbon Nanotubes in CompositesPhotonic and Optical DevicesMechanical and Optical Resonators

Kinetic-Energy Discrimination for Atom Probe Tomography

Thomas F. Kelly2011-01-19Microscopy and Microanalysis

The benefits of using kinetic-energy information to aid ion discrimination in atom probe tomography (APT) are explored. Ion peak interferences in time-of-flight (TOF) mass spectra are categorized by difficulty of discrimination using TOF and kinetic-energy information. Several of these categories, which are intractabl…

Fusion materials and technologiesIon-surface interactions and analysisAdvanced Materials Characterization Techniques

Spectroscopic ellipsometry and x-ray photoelectron spectroscopy of La2O3 thin films deposited by reactive magnetron sputtering

Victor V. Atuchin∥⊥、А. В. Калинкин、V. A. Kochubey 等 6 位作者2011-01-19Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Lanthanum oxide (La2O3) films were grown by the reactive dc magnetron sputtering and studied their structural, chemical and optical parameters. La2O3 films were deposited onto Si substrates by sputtering La-metal in a reactive gas (Ar+O2) mixture at a substrate temperature of 200 °C. Reflection high-energy electron di…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Highly anisotropic effective dielectric functions of silver nanoparticle arrays

Thomas W. H. Oates、Mukesh Ranjan、Stefan Facsko 等 4 位作者2011-01-19Optics Express

Variable-angle and Mueller matrix spectroscopic ellipsometry are used to determine the effective dielectric tensors of random and aligned silver nanoparticles and nanorods thin films. Randomly arranged particles are uniaxially anisotropic while aligned particles are biaxially anisotropic, with the anisotropy predomina…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications