Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Blanket films of ultralow dielectric constant (ULK) materials and 193nm photoresist films have been processed downstream from hydrogen and deuterium-based discharges produced using an inductively coupled plasma reactor. Photoresist ashing rates and ULK modifications have been determined as a function of process parame…
Abstract Diamond is considered as tissue equivalent, due to its low atomic number, which makes it a particular attractive material for medical radiation dosimetry applications. X‐ray dosimeters made of natural single crystal diamonds are commercially available and routinely used, with typical gain values of about 0.5.…
The tuning of electron affinity and secondary electron emission on diamond (100) surfaces due to cycloaddition with 1,3-butadiene is investigated by photoemission experiments and density functional theory (DFT) calculations. A significant reduction in electron affinity up to 0.7 eV and enhancement of secondary electro…
A detailed comparison of the surface sensitivity of x-ray photoemission spectroscopy for hard and soft x rays is presented and discussed. Electron scattering parameters and their energy dependence are given for Si and two Si spectra are analyzed: a $\mathrm{Mg}\phantom{\rule{0.2em}{0ex}}K\ensuremath{\alpha}$ $(h\ensur…
Abstract A novel acid‐cleavable diacrylate crosslinker, DCDA, was used as a difunctional Michael acceptor in the synthesis of acid‐cleavable crosslinked networks via base‐catalyzed Michael addition of telechelic poly(ethylene glycol) bis(acetoacetate). Michael addition networks containing DCDA were degraded in the pre…
Abstract An assay method has been developed to detect oxalic acid from other structurally similar dicarboxylic acids using a cationic polythiophene derivative (PFT). Upon adding oxalic acid, the PFT can be cross‐linked through the bifunctional diacids of oxalic acid to form tense interpolymer π ‐stacking aggregation,…
Computational Nano-materials Design for Colossal Thermoelectric-cooling Power by Adiabatic Spin-Entropy Expansion in Nano-superstructures, Katayama-Yoshida, Hiroshi, Fukushima, Tetsuya, Dinh, Van An, Sato, Kazunori
Employing resonant x-ray diffraction, we observed unique pitch evolutions in the smectic-C*(alpha) phase in mixtures of two antiferroelectric liquid crystals. Our results show that the pitch in this phase continuously evolves across 4 layers, contradicting a theoretical model that predicts that the smectic-C*(FI2) pha…
A unique class of nanoclays was prepared by modification of pristine clays or organoclays (Cloisite C20A) with transition metal ions (TMIs). The composition, structure, morphology and thermal properties of TMI-modified nanoclays were investigated by atomic absorption spectroscopy (AAS), elemental analysis (EA), scanni…
Abstract Using a new aromatic 1,2,4‐triazole branching monomer (4.8–13.3 mol %), three hyperbranched polyfluorenes ( P2 – P4 ) were synthesized by the Suzuki coupling reaction to investigate the structural effect on optoelectronic properties. Poly(9,9‐dihexylfluorene) ( P1 ) was also prepared for comparative investiga…
We conclusively establish a direct link between formation of an Er-related donor gap state and the 1.5 microm emission of Er in Si. The experiment is performed on Si/Si:Er nanolayers where a single type of Er optical center dominates. We show that the Er emission can be resonantly induced by direct pumping into the bo…
Abstract The reactivities of the pristine and silicon doped (Si‐doped) single‐walled carbon nanotubes (CNTs) toward small gaseous molecules in the atmosphere, such as formaldehyde, carbon monoxide, and hydrogen sulfide, were studied by performing density functional theory calculations. Compared with the physisorptions…
Hydrogen-bonded hollow microcapsules with a lightly cross-linked shell structure were fabricated by polymerization of acrylic acid in a solution containing surface-modified silica particles and poly(vinylpyrrolidone) and a subsequent core removal with HF. By further incorporating additional cross-linkers, a highly cro…
Abstract Segmented block copolymers based on poly(ethylene oxide) (PEO) flexible segments and monodisperse crystallizable bisester tetra‐amide segments were made via a polycondensation reaction. The molecular weight of the PEO segments varied from 600 to 4600 g/mol and a bisester tetra‐amide segment (T6T6T) based on d…
Abstract Organic–inorganic hybrids were prepared with a diglycidyl ether of bisphenol A (DGEBA) type epoxy and silane‐modified isocyanuric acid triglycidyl ester via the sol–gel process. The DGEBA‐type epoxy was modified by a coupling agent to improve the compatibility of the organic and inorganic phases. The sol–gel…
The crystal structure of apo tryptophanase from Escherichia coli (space group F222, unit-cell parameters a = 118.4, b = 120.1, c = 171.2 A) was determined at 1.9 A resolution using the molecular-replacement method and refined to an R factor of 20.3% (R(free) = 23.2%). The structure revealed a significant shift in the…
Statistical cross-validation has become an integral part of the model-refinement process in macromolecular crystallography. However, the test set of reflections, for which the free R value is calculated, is used both to optimize the parameterization of the structure model and to validate the model itself. This practic…
Abstract Poly( D , L ‐lactide) and poly( D , L ‐lactide‐ co ‐glycolide) with various composition and with one methacrylate and one carboxylate end group were synthesized and grafted onto poly(vinyl alcohol) (PVA) via the carboxylate group. The graft copolymers were crosslinked via the methacrylate groups using a free…
We investigate the influence of the spin-phonon coupling in the triangular antiferromagnet where the coupling is of the exchange-striction type. The magnon dispersion is shown to be modified significantly at wave vector $(2\ensuremath{\pi},0)$ and its symmetry-related points, exhibiting a rotonlike minimum and an even…
The core structure of straight and curved dislocations is studied by developing a hybrid approach that links the parametric dislocation dynamics method with ab initio calculations. The approach is an extension of the Peierls–Nabarro (PN) model, with the following features: (Equation1) all three components of the displ…