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Heat capacity and entropy of nonstoichiometric magnetiteFe3(1−δ)O4: The thermodynamic nature of the Verwey transition

J. Shepherd、J. W. Koenitzer、R. Aragón 等 5 位作者1991-04-01Physical review. B, Condensed matter

The heat capacity of ${\mathrm{Fe}}_{3(1\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}})}$${\mathrm{O}}_{4}$, was systematically measured for nine samples in the composition range 00.012 and for temperatures between 5 and 200 K. The character of the heat-capacity anomaly at the Verwey transition changed at \ensure…

Magnetic Properties and Synthesis of FerritesAdvanced Condensed Matter PhysicsIron oxide chemistry and applications

Preparation of molecular sieves from dense layered metal oxides

Michael E. Landis、Brent A. Aufdembrink、Peir-Yung Chu 等 6 位作者1991-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of molecular sieves from dense layered metal oxidesMichael E. Landis, B. A. Aufdembrink, P. Chu, I. D. Johnson, G. W. Kirker, and M. K. RubinCite this: J. Am. Chem. Soc. 1991, 113, 8, 3189–3190Publication Date (Print):April 1, 1991Publication History Published on…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Phase diagrams of binary polymer solutions and blends

Caibao Qian、Stephen J. Mumby、B. E. Eichinger1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase diagrams of binary polymer solutions and blendsCaibao Qian, Stephen J. Mumby, and B. E. EichingerCite this: Macromolecules 1991, 24, 7, 1655–1661Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 April 1991https://pu…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Kinetic modeling of the reduction of nitric oxide in combustion products by isocyanic acid

James A. Miller、Craig T. Bowman1991-04-01International Journal of Chemical Kinetics

Abstract The RAPRENO x process for NO reduction in combustion products involves reaction of nitric oxide with isocyanic acid. We have developed a mechanism for the gas‐phase reaction of isocyanic acid with nitric oxide in the presence of various amounts of O 2 , H 2 O, and CO. Kinetics calculations using the mechanism…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceIndustrial Gas Emission Control

Micelle formation of BAB triblock copolymers in solvents that preferentially dissolve the A block

Nitash P. Balsara、Matthew Tirrell、Timothy P. Lodge1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMicelle formation of BAB triblock copolymers in solvents that preferentially dissolve the A blockN. P. Balsara, M. Tirrell, and T. P. LodgeCite this: Macromolecules 1991, 24, 8, 1975–1986Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Publ…

Theoretical and Computational PhysicsPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Integrated ferroelectrics

Carlos A. Paz de Araújo、George W. Taylor1991-04-01Ferroelectrics

This paper attempts to formalize the field of Integrated Ferroelectrics. The history of devices that include ferroelectrics and semiconductor hybrids is reviewed. The modern ferroelectric device is a combination of ferroelectric thin-films onto a semiconductor single crystal substrate. The evolution of the field in th…

Ferroelectric and Piezoelectric MaterialsAdvanced Battery Materials and TechnologiesPolymer crystallization and properties

Three dimensionality of ‘‘metallic’’ states in conducting polymers: Polyaniline

Z. H. Wang、C. Li、E. M. Scherr 等 5 位作者1991-04-01Physical Review Letters

Anisotropic-conductiity (\ensuremath{\sigma}), thermopower, and dielectric-constant studies show that oriented polyaniline salt is representative of a class of quasi-one-dimensional disordered conductors where coupled parallel chains form ``metallic'' bundles in which electron wave functions are extended three dimensi…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Growth of Ge Microcrystals in SiO2 Thin Film Matrices: A Raman and Electron Microscopic Study

Minoru Fujii、Shinji Hayashi、Keiichi Yamamoto1991-04-01Japanese Journal of Applied Physics

The growth of Ge microcrystals in SiO 2 -Ge mixture films prepared by an rf co-sputtering method was studied by Raman spectroscopy and electron microscopy. It was found that in the as-deposited films, Ge clusters about 2 nm in diameter are embedded in SiO 2 matrices and they are grown to Ge microcrystals by thermal an…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Glass transition temperature as a function of conversion in thermosetting polymers

A. Hale、Christopher W. Macosko、H. E. Bair1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGlass transition temperature as a function of conversion in thermosetting polymersArturo Hale, Christopher W. Macosko, and Harvey E. BairCite this: Macromolecules 1991, 24, 9, 2610–2621Publication Date (Print):April 29, 1991Publication History Published online1 May 2002Publi…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesEpoxy Resin Curing Processes

Phonons at martensitic phase transitions of bcc-Ti, bcc-Zr and bcc-Hf

W. Petry1991-04-01Phase Transitions

Inelastic neutron scattering on in situ grown bcc single crystals of the group 4 metals Ti, Zr and Hf show a band of low energy and strongly damped phonons. Geometrical considerations show how these damped lattice vibrations achieve the displacements necessary for the two martensitic phase transitions from bcc to ω (u…

Rare-earth and actinide compoundsIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

The Concept of a Hydrophyte for Wetland Identification

Ralph W. Tiner1991-04-01BioScience

Ralph W. Tiner; The Concept of a Hydrophyte for Wetland Identification: Individual plants adapt to wet environments, BioScience, Volume 41, Issue 4, 1 April 199

Diatoms and Algae ResearchPeatlands and Wetlands EcologyMediterranean and Iberian flora and fauna

Design trades for Rotman lenses

R.C. Hansen1991-04-01IEEE Transactions on Antennas and Propagation

The foundation of a satisfactory Rotman lens design is geometric. The effects of seven design parameters (focal angle, focal ratio, beam angle ratio, maximum beam angle, beam port curve ellipticity, array element spacing, and focal length/ lambda ) on the shape, and on the geometric phase and amplitude errors of a Rot…

Microwave Engineering and WaveguidesAdvanced Antenna and Metasurface TechnologiesOptical Coatings and Gratings

Aggregation of coil-crystalline block copolymers: equilibrium crystallization

Thomas A. Vilgis、A. Halperin1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAggregation of coil-crystalline block copolymers: equilibrium crystallizationT. Vilgis and A. HalperinCite this: Macromolecules 1991, 24, 8, 2090–2095Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 April 1991https://pub…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Ferrite Materials: Science and Technology

B. Viswanathan、V. R. K. Murthy1991-04-01Medical Entomology and Zoology

Chemistry of ferrites theoretical models of electrical properties of ferrites electrical conductivity and thermoelectric power of ferrites low frequency dielectric properties of ferrites transport mechanism in mixed ferrites at microwave frequencies magnetic properties at microwave frequencies theory and design of non…

Magnetic Properties and Synthesis of Ferrites

Molecular dynamics simulation of an amorphous polymer under tension. 1. Phenomenology

David Brown、Julian H. R. Clarke1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular dynamics simulation of an amorphous polymer under tension. 1. PhenomenologyDavid Brown and Julian H. R. ClarkeCite this: Macromolecules 1991, 24, 8, 2075–2082Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 Apr…

Polymer crystallization and propertiesRheology and Fluid Dynamics Studies

Dipolar-glass model for lead magnesium niobate

D. Viehland、J. F. Li、S. J. Jang 等 5 位作者1991-04-01Physical review. B, Condensed matter

The static polarization of lead magnesium niobate has been studied using a standard Sawyer-Tower circuit. The square-to-slim-loop hysteresis transition was phenomenologically modeled by modifying N\'eel's equation for the magnetization of a superparamagnet to a similar relationship for a superparaelectric. A temperatu…

High-pressure geophysics and materialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Some new aspects related to the synthesis of meso‐substituted porphyrins

Α. Μ. d’A. Rocha Gonsalves、Jorge M.T.B. Varejão、Mariette M. Pereira1991-04-01Journal of Heterocyclic Chemistry

Abstract A general analysis of the steps of the Rothemund reaction, allowed for a better understanding and a significant improvement of this reaction as a synthetic method in some of the previously known difficult syntheses.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Long-range Finnis-Sinclair potentials for f.c.c. metallic alloys

Hashem Rafii‐Tabar、A. P. Sulton1991-04-01OpenAlex

Many-body, long-range potentials of a Finnis-Sinclair type are formulated for the atomistic description of binary f.c.c. metallic alloys. These potentials are generalizations of the scheme constructed by Sutton and Chen (1990), for the atomistic modelling of f.c.c. elemental metals. The parameters for the alloy potent…

Microstructure and mechanical propertiesHigh-pressure geophysics and materialsSurface and Thin Film Phenomena

Absorption and emission cross section of Er/sup 3+/ doped silica fibers

William L. Barnes、R.I. Laming、E.J. Tarbox 等 4 位作者1991-04-01OpenAlex

A detailed set of measurements is presented on determining the emission and absorption cross sections of Er/sup 3+/ doped fibers for the /sup 4/I/sub 13/2/ to /sup 4/I/sub 15/2/ transition. Two techniques are employed: the Fuchtbauer-Ladenberg analysis, based on spectroscopic data, and a more direct technique involvin…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystal and Fiber Optics

Magnetostructural correlations in magnetically coupled (.mu.-oxo)diiron(III) complexes

Sergiu M. Gorun、Stephen J. Lippard1991-04-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetostructural correlations in magnetically coupled (.mu.-oxo)diiron(III) complexesSergiu M. Gorun and Stephen J. LippardCite this: Inorg. Chem. 1991, 30, 7, 1625–1630Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 A…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies