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Effect of Symmetry and H‐bond Strength of Hard Segments on the Structure‐Property Relationships of Segmented, Nonchain Extended Polyurethanes and Polyureas

Sudipto Das、David F. Cox、Garth L. Wilkes 等 7 位作者2007-08-01Journal of Macromolecular Science Part B

Segmented, nonchain extended polyurethanes and polyureas based on PTMO soft segments (SS) and hard segments (HSs) based on only single molecules of a diisocyanate were synthesized. Type and nature of the diisocyanate was systematically varied in order to analyze the effect of HS symmetry and type of linkage between th…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer composites and self-healing

Cell Electrospinning Highly Concentrated Cellular Suspensions Containing Primary Living Organisms Into Cell-Bearing Threads and Scaffolds

Suwan N. Jayasinghe、Scott A. Irvine、Jean R. McEwan2007-08-01Nanomedicine

AIMS: We recently pioneered the cell electrospinning of living cells as viable biological threads and scaffolds. In that study, we demonstrated the process with an immortalized human brain astrocytoma (1321N1, European Collection of Cell Cultures) cell line at a cell concentration of 10(6) cells/ml. The next stage was…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Origin of Gate Hysteresis in Carbon Nanotube Field-Effect Transistors

Joon Sung Lee、Sunmin Ryu、Kwonjae Yoo 等 6 位作者2007-08-01The Journal of Physical Chemistry C

High Resolution Image Download MS PowerPoint Slide We have studied gate hysteresis of carbon nanotube field-effect transistors (CNFETs) on silicon oxide substrates in an ultrahigh vacuum (UHV) at low temperatures. It is found that the hysteresis is neither reduced by thermal annealing at temperatures over 300 °C under…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Accuracy control in ultra-large-scale electronic structure calculation

Takeo Hoshi2007-08-01arXiv

Numerical aspects are investigated in ultra-large-scale electronic structure calculation. Accuracy control methods in process (molecular-dynamics) calculation are focused. Flexible control methods are proposed so as to control variational freedoms, automatically at each time step, within the framework of generalized W…

Materials Science

Length-Dependent Optical Effects in Single-Wall Carbon Nanotubes

Jeffrey Fagan、Jeffrey R. Simpson、Barry J. Bauer 等 9 位作者2007-08-01Journal of the American Chemical Society

Among the novel chemical and physical attributes of single-wall carbon nanotubes (SWCNTs), the optical properties are perhaps the most compelling. Although much is known about how such characteristics depend on nanotube chirality and diameter, relatively little is known about how the optical response depends on length…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Ligand-free Self-Assembly of Ceria Nanocrystals into Nanorods by Oriented Attachment at Low Temperature

Ning Du、Hui Zhang、Bingdi Chen 等 5 位作者2007-08-01The Journal of Physical Chemistry C

Single-crystalline ceria nanorods have been fabricated by self-assembly of ceria nanocrystals via a simple, low-temperature, and ligand-free approach. Detailed high-resolution transmission electron microscopy shows that the nanorods are formed along the [211] or [110] direction by self-organization of truncated octahe…

Catalytic Processes in Materials ScienceQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Novel method for mechanical characterization of polymeric nanofibers

Mohammad Naraghi、Ioannis Chasiotis、H. Kahn 等 5 位作者2007-08-01Review of Scientific Instruments

A novel method to perform nanoscale mechanical characterization of highly deformable nanofibers has been developed. A microelectromechanical system (MEMS) test platform with an on-chip leaf-spring load cell that was tuned with the aid of a focused ion beam was built for fiber gripping and force measurement and it was…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Interfacial Property Modulation of Thermoresponsive Polymer Brush Surfaces and Their Interaction with Biomolecules

Kenichi Nagase、Jun Kobayashi、Akihiko Kikuchi 等 6 位作者2007-08-01Langmuir

Dense poly(N-isopropylacrylamide) (PIPAAm) brushes were created on silica bead surfaces by surface-initiated atom transfer radical polymerization (ATRP). Interfacial properties of PIPAAm brushes were characterized by thermoresponisve interaction with biomolecules. The grafted amounts of PIPAAm on silica bead surfaces…

Analytical chemistry methods developmentMicrofluidic and Capillary Electrophoresis ApplicationsPolymer Surface Interaction Studies

Designing Conducting Polymers Using Bioinspired Ant Algorithms

Bruno V. C. Martins、Gustavo Brunetto、Fernando Sato 等 5 位作者2007-08-01arXiv

Ant algorithms are inspired in real ants and the main idea is to create virtual ants that travel into the space of possible solution depositing virtual pheromone proportional to how good a specific solution is. This creates a autocatalytic (positive feedback) process that can be used to generate automatic solutions to…

Materials ScienceSoft Condensed Matter

Engineering silicon nanocrystals: Theoretical study of the effect of codoping with boron and phosphorus

Federico Iori、Elena Degoli、Rita Magri 等 9 位作者2007-08-01Physical Review B

We show that the optical and electronic properties of nanocrystalline silicon can be efficiently tuned using impurity doping. In particular, we give evidence, by means of ab initio calculations, that by properly controlling the doping with either one or two atomic species, a significant modification of both the absorp…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Magneto-gyrotropic photogalvanic effects due to inter-subband absorption in quantum wells

H. Diehl、V. A. Shalygin、S. N. Danilov 等 9 位作者2007-08-01arXiv

We report on the observation of the magneto-photogalvanic effect (MPGE) due to inter-subband transitions in (001)-oriented GaAs quantum wells. This effect is related to the gyrotropic properties of the structures. It is shown that inter-subband absorption of linearly polarized radiation may lead to spin-related as wel…

Materials Science

Monte Carlo simulations of the L10 long-range order relaxation in dimensionally reduced systems

Mohammed Allalen、Tarik Mehaddene、Hamid Bouzar2007-08-01arXiv

Monte Carlo simulations have been performed to investigate the relaxation of the L10 long-range order in dimensionally reduced systems. The effect of the number of (001)-type monatomic layers and of the pair interaction energies on these kinetics has been examined. The vacancy migration energies have been deduced from…

Materials ScienceSoft Condensed Matter

Synthesis and Characterization of Novel Coralloid Polyaniline/BaFe12O19 Nanocomposites

Ping Xu、Xijiang Han、Jingjing Jiang 等 6 位作者2007-08-01The Journal of Physical Chemistry C

By supplying inorganic ferrite nanoparticles of different morphologies as nucleation sites, PANI/ferrite nanocomposites with novel coralloid structures were synthesized successfully through a simple, conventional, and inexpensive one-step in situ polymerization method without the aid of any surfactant, organic dopant,…

Conducting polymers and applicationsMultiferroics and related materialsElectromagnetic wave absorption materials

Nanoparticle-Free Synthesis of Fluorescent Gold Nanoclusters at Physiological Temperature

Yuping Bao、Chang Zhong、Dung M. Vu 等 6 位作者2007-08-01The Journal of Physical Chemistry C

Few-atom gold nanoclusters exhibit strong size-dependent fluorescence emission. For many applications, these clusters are preferable to quantum dots or organic fluorophores as fluorescent labels. However, the published synthetic procedures to create these nanoclusters involve toxic chemicals, are of low synthetic yiel…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Towards a Thermal Moore's Law

Shankar Krishnan、Suresh V. Garimella、G. Chrysler 等 4 位作者2007-08-01IEEE Transactions on Advanced Packaging

Thermal design power trends and power densities for present and future single-core microprocessors are investigated. These trends are derived based on Moore's law and scaling theory. Both active and stand-by power are discussed and accounted for in the calculations. A brief discussion of various leakage power componen…

Advanced Thermoelectric Materials and DevicesAdvancements in Semiconductor Devices and Circuit DesignThermal properties of materials

Phase diagram and magnetocaloric effect of CoMnGe_{1-x}Sn_{x} alloys

J. B. A. Hamer、R. Daou、S. Özcan 等 6 位作者2007-08-01arXiv

We propose the phase diagram of a new pseudo-ternary compound, CoMnGe_{1-x}Sn_{x}, in the range x less than or equal to 0.1. Our phase diagram is a result of magnetic and calometric measurements. We demonstrate the appearance of a hysteretic magnetostructural phase transition in the range x=0.04 to x=0.055, similar to…

Materials ScienceStrongly Correlated Electrons

Energy-Transfer Mechanism in Photoluminescent Terbium(III) Complexes Causing Their Temperature-Dependence

Shinya Katagiri、Yasunori Tsukahara、Yasuchika Hasegawa 等 4 位作者2007-08-01Bulletin of the Chemical Society of Japan

Abstract Photoluminescence of Terbium(III) complexes was investigated as a function of temperatures in the range of 80–280 K for [Tb(bfa)3(H2O)2] (bfa: 4,4,4-trifluoro-1-phenyl-1,3-butanedionato), [Tb(hfa)3(H2O)3] (hfa: hexafluoroacetylacetonato), [Tb(tfa)3(H2O)2] (tfa: trifluoroacetylacetonato), [Tb(acac)3(H2O)3] (ac…

Magnetism in coordination complexesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Stabilization and “Debundling” of Single-Wall Carbon Nanotube Dispersions in N -Methyl-2-pyrrolidone (NMP) by Polyvinylpyrrolidone (PVP)

Tawfique Hasan、Vittorio Scardaci、Ping‐Heng Tan 等 6 位作者2007-08-01The Journal of Physical Chemistry C

We present a simple method to stabilize single-wall carbon nanotube (SWNT) dispersions in N -methyl-2-pyrrolidone (NMP) by polyvinylpyrrolidone (PVP). A significant population of isolated SWNTs as well as small bundles of SWNTs in NMP is obtained by ultrasonic treatment followed by vacuum filtration through glass fibe…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNanotechnology research and applications

Structure, magnetic property, and spin polarization of Co2FeAlxSi1−x Heusler alloys

Tomoya Nakatani、A. Rajanikanth、Z. Gercsi 等 6 位作者2007-08-01Journal of Applied Physics

We report the spin polarization of Co2FeAlxSi1−x (x=0.0, 0.3, 0.5, 0.7) bulk alloys measured by the point contact Andreev reflection method. All the Co2FeAlxSi1−x alloys had an L21 structure along with A2- and B2-type disorder. Several off-stoichiometric alloys (CoxFeyAl0.5Si0.5) were prepared to understand the effect…

2D Materials and ApplicationsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Simple synthesis of three primary colour nanoparticle inks of Prussian blue and its analogues

Akihito Gotoh、Hiroaki Uchida、Manabu Ishizaki 等 16 位作者2007-08-01Nanotechnology

Simple synthesis of three primary colour nanoparticle inks of Prussian blue and its analogues, Gotoh, Akihito, Uchida, Hiroaki, Ishizaki, Manabu, Satoh, Tetsutaro, Kaga, Shinichi, Okamoto, Shusuke, Ohta, Masaki, Sakamoto, Masatomi, Kawamoto, Tohru, Tanaka, Hisashi, Tokumoto, Madoka, Hara, Shigeo, Shiozaki, Hirofumi, Y…

Magnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications