Materials Literature
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We compared quantity and structures of food-derived gelatin hydrolysates in human blood from three sources of type I collagen in a single blind crossover study. Five healthy male volunteers ingested type I gelatin hydrolysates from fish scale, fish skin, or porcine skin after 12 h of fasting. Amounts of free form Hyp…
By using the highly oriented 1:1 stoichiometric blend of high-molecular-weight PLLA and middle-molecular-weight PDLA species and by choosing a suitable annealing condition, we have succeeded for the first time to observe the phase transition phenomenon in the heating and cooling processes by measuring the temperature…
Free radicals are generated by the collapse of ultrasound-induced cavitation bubbles when they are forcefully compressed by dynamic stimuli. Radical generation occurs as a result of the extremely high temperatures induced by adiabatic compression during the violent collapse process. It is generally believed that extre…
We report here the first example of a homogeneous first row transition-metal-based catalyst which is active for dehydrogenation of ammonia−borane, H 3 NBH 3, a promising chemical hydrogen storage material. Addition of ammonia−borane to an active catalyst formed in situ from the reaction of Ni(cod) 2 and 2 equiv of an…
The title compound, [Mn(C6H15N3)2][As2Se6], contains a sandwich-like centrosymmetric complex cation with two tridentate 9-aneN3 (1,4,7-triazacyclononane) ligands, which coordinate the MnII atom in an octahedral manner. AsSe3 pyramids are linked by two Se—Se bonds into the centrosymmetric chair-shaped six-membered…
We apply the technique of x-ray magnetic circular dichroism in total electron yield mode to study the magnitudes of the magnetic moments of Cr, Fe, and Co in Heusler alloy ${\mathrm{Co}}_{2}{\mathrm{Cr}}_{1\ensuremath{-}x}{\mathrm{Fe}}_{x}\mathrm{Al}$ epitaxial thin films, predicted to be half metallic for small value…
Thermal stability of amorphous system xFe2O[ 20Na2O30CaO50P2O5] , with mol%, was investigated by differential thermal analysis (DTA). Critical crystal radii are evaluated using the molar volumes and the thermal glass stabilities. Partial crystallisation of samples was obtained by heat treatment carried out for 24 hour…
An understanding of the adsorption behaviour of nitrogen in single-wall carbon nanotubes (SWCNTs) is necessary for obtaining information on its pores by nitrogen adsorption manometry. Non-local density functional theory was used to simulate nitrogen adsorption behaviour, including the adsorption isotherms, equilibrium…
X-ray excited optical luminescence (XEOL) and X-ray absorption near-edge structure (XANES) have been used to identify the origin of luminescence from chemical vapor deposited (CVD) diamond films. The XANES data provide direct evidence that luminescence from the CVD diamond films originates from the diamond phase, wher…
Temperature and frequency dependence of a.c. conductivity have been studied in glassy Se70Te30−xSbx (2 ≤ x ≤ 10). An agreement between experimental and theoretical results suggests that the a.c. conductivity behaviour of Se-Te-Sb system can be successfully explained by correlated barrier hopping (CBH) model. The obser…
Abstract Polypropylene (PP)/nylon 6/clay composites were prepared by compounding of PP, which had previously been treated with two kinds of silane compounds, with a master batch composed of 90 wt % of nylon 6 and 10 wt % of octadecyl amine‐modified sodium montmorillonite (NM10). The morphology of the composites was in…
Abstract Chitins produced via a conventional chemical route as well as from a new biological process were modified to increase the efficiency of enzymatic deacetylation reactions for the production of novel biological chitosan. These modified chitins were reacted for 24 h with extracellular fungal enzymes from Colleto…
Imitating nature: Different morphologies of linear polyethyleneimine (LPEI) aggregates regulated by monovalent, divalent, and trivalent metal cations act as biomimetic organic reactors for directing the formation of complicated silica structures. LPEI associated with Cu2+ resulted in turbinelike silica; when associate…
Umkehr! Kolumnare mesomorphe Anordnungen von propellerförmigen, wasserstoffverbrückten Komplexen wirken bei Bestrahlung mit zirkular polarisiertem Licht (CPL) einer bestimmten Händigkeit als supramolekulare Schalter (siehe Bild), die bei Bestrahlung mit entgegengesetzt polarisiertem Licht eine Helixinversion eingehen.
PbO-Sb2O3-B2O3 glasses containing different concentrations of MoO3 ranging from 0 to 5 mol % were prepared. A number of studies have been carried out on these glasses comprising differential thermal analysis, infrared and optical absorption, Raman and ESR spectra, magnetic susceptibility and measurements of dielectric…
A combined theoretical and experimental investigation of conjugated rod-coil block copolymer brushes is reported. The theoretical study for the surface structures of rod-coil block copolymer brushes was established based on the simulation method of dissipative particle dynamics. The effects of solvent stimuli, graftin…
The packing structure of bundled MoSI nanowires is investigated. Scanning and high-resolution transmission electron microscopy are used to determine both the nanowire structure and bundle superstructure. Shown is a high-resolution microscopy image of a small bundle. The image width is 8 nm. It is found that the nanowi…
This paper introduces the synthesis, characterization, surface properties, and reactions of maleic acid monoester end group functionalized polymers. Acylation using maleic acid anhydride of hydroxyl end groups present in either poly(ethylene glycol) (PEG) or poly(trimethylene carbonate) (PTMC) afforded the correspondi…
Transparent and conducting zirconium-doped zinc oxide films with high transparency and relatively low resistivity have been successfully prepared by radio frequency (RF) magnetron sputtering at room temperature. The RF power is varied from 75 to 150 W. At first the crystallinity and conductivity of the film are improv…
Sonolysis of argon-saturated aqueous solutions of the nonvolatile surfactants sodium dodecyl sulfate (SDS) and sodium 1-pentanesulfonate (SPSo) was investigated at three ultrasonic frequencies under both continuous wave (CW) and pulsed ultrasound. Secondary carbon-centered radicals were detected by spin trapping using…