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Cellulose acetate-Al2O3 hybrid material coated with N-Propyl-1,4-diazabicyclo [2.2.2] octane chloride: preparation, characterization and study of some metal halides adsorption from ethanol solution

Gislene Splendore、Edilson Valmir Benvenutti、Yuriy V. Kholin 等 4 位作者2005-04-01Journal of the Brazilian Chemical Society

The preparation, characterization as well as the adsorption properties of MCl n (M= Fe(III), Co(II) and Cu(II)) from ethanol solutions by the new hybrid material cellulose acetate /Al2O3 coated with N-propyl-1,4 diazabicyclo [2.2.2] octane chloride group are described. The diamine is bonded to the cellulose acetate /A…

Synthesis and properties of polymers

Spreading Characteristics of Aqueous Surfactant Solutions on Polymer Surfaces

Victoria Dutschk、B. Breitzke2005-04-01Tenside Surfactants Detergents

Abstract The objective of this work was the analysis of dynamic wetting behaviour of aqueous surfactant solutions on polymer surfaces in respect of spreading characteristics evaluation. Surfactants with different ionogeneity (ionics and non-ionics) in a wide concentration range were used in this study. The sessile dro…

Surface Modification and SuperhydrophobicitySurfactants and Colloidal SystemsFluid Dynamics and Heat Transfer

Evidence from infrared spectroscopy of structural relaxation during field assisted and chemically driven ion exchange in soda-lime-silica glasses

Malcolm D. Ingram、Ming Hong Wu、Alison M. Coats 等 7 位作者2005-04-01National Hellenic Research Foundation Helios Repository (National Hellenic Research Foundation)

Journal URL: http://www.ingentaconnect.com/content/sgt/pcg; http://www.societyofglasstechnology.org.uk/cgi-bin/open.cgi?page=journal&sessionid=85597106; http://www.societyofglasstechnology.org.uk/cgi-bin/open.cgi?page=%20PC/PC-00a&sessionid=85597106

Glass properties and applicationsPhase-change materials and chalcogenidesMineralogy and Gemology Studies

Effect of Low Molecular Weight Organic Anions on Adsorption of Potassium by Variable Charge Soils

Ren‐kou Xu、Anzhen Zhao、Guoliang Ji2005-04-01Communications in Soil Science and Plant Analysis

Low‐molecular‐weight (LMW) organic acids exist widely in soils and have been implicated in many soil processes. In the present paper, the effect of the anions of four LMW organic acids on the adsorption of potassium (K) by two variable charge soils was investigated. The results showed that the presence of organic anio…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Characteristics of the minerals associated with gold in the Shewushan supergene gold deposit, China

Hanlie Hong、Liyun Tie2005-04-01Clays and Clay Minerals

Abstract The mineralogical properties of goethite and clay minerals from the Shewushan supergene gold deposit have been studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). These results show that in the weathering zone of the Shewushan supergene gold deposit the mineral assemblage is main…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Molecular Study of Thermal Immobilization of Chromium(VI) with Clay

Yu‐Ling Wei、Huei-Fang Hsieh、Yao-Wen Yang 等 5 位作者2005-04-01Journal of the Air & Waste Management Association

Clay that contains kaolinite has been used extensively as a raw material for manufacturing of bricks and china at 900-1100 degrees C. This study used clay to stabilize the contaminant chromium(VI) [Cr(VI)] through a heating process at 500-1100 degrees C. X-ray absorption spectroscopic results indicated that the 500-90…

Recycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactionsX-ray Diffraction in Crystallography

Effect of steric factors on mesomorphic stability I. 4‐(4‐Substituted phenylazo)‐1‐naphthyl 4‐alkoxybenzoates

Sayed Z. Mohammady、Refaat I. Nessim、Ola R. Shehab 等 4 位作者2005-04-01Liquid Crystals

Four homologous series belonging to the family of 4‐(4‐substituted phenylazo)‐1‐naphthyl 4‐alkoxybenzoates (I a–d) (C n H2 n +1O–C6H4–COO–C10H6–N = N–C6H4–X) were prepared in which the 4‐ substituent (X) was varied between CH3O, CH3, Cl and NO2; while, within each homologous series, the number of carbon atoms, n, was…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

Effects of Fabrication Process on Current–Voltage Characteristics of Carbon Nanotube Field Effect Transistors

Takashi Mizutani、Shinya Iwatsuki、Yutaka Ohno 等 4 位作者2005-04-01Japanese Journal of Applied Physics

The effects of the fabrication process on the current–voltage ( I – V ) characteristics of carbon nanotube field effect transistors (CNT-FETs) were studied in detail. A large hysteresis observed in the I – V characteristics of the CNT-FETs having no passivation film became small by passivating the device surface with…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Enhancement of nitrogen physisorption in coadsorption with oxygen on free, positively charged silver clusters

Martin Schmidt、A. Masson、C. Bréchignac2005-04-01The Journal of Chemical Physics

The coadsorption of molecular nitrogen and oxygen on small cationic silver clusters in the gas phase is experimentally studied. The presence of oxygen enhances the adsorption probabilities of N2. This indicates a partial charge transfer out of the finite free electron reservoir of the small silver particles into the c…

Advanced Chemical Physics StudiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Reductive Functionalization of Carbon Nanotubes

Ferenc Borondics、M. Bokor、Péter Matus 等 6 位作者2005-04-01Fullerenes Nanotubes and Carbon Nanostructures

We present sidewall functionalization of carbon nanotubes via various dissolving metal reduction methods. Carbanion complexes of lithium were prepared in liquid ammonia and THF and reacted with a series of alkyl and aryl halogenides, as well as methanol resulting in the formations of alkylated, arylated, and hydrogena…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

A new mineral, zincolibethenite, CuZnPO4OH, a stoichiometric species of specific site occupancy

R. S. W. Braithwaite、R.G. Pritchard、W. H. Paar 等 4 位作者2005-04-01Mineralogical Magazine

Abstract Tiny green crystals from Kabwe, Zambia, associated with hopeite and tarbuttite (and probably first recorded in 1908 but never adequately characterized because of their scarcity) have been studied by X-ray diffraction, microchemical and electron probe microanalysis, infrared spectroscopy, and synthesis experim…

Crystal Structures and PropertiesClay minerals and soil interactionsIron oxide chemistry and applications

In situ HVEM study on copper oxidation using an improved environmental cell

Masao Komatsu、Hirotaro Mori2005-04-01Microscopy

A window-type environmental cell that can be used over the temperature range from room temperature to approximately 1000 K was improved by incorporating a new window material that increases resolution and contrast in high voltage electron microscopy. With this improvement, the resolution was a few nanometers and the m…

ZnO doping and propertiesCopper-based nanomaterials and applications

The Effect of MgO Addition on Grain Growth in PMN–35PT

Chang Eui Seo、Duk Yong Yoon2005-04-01Journal of the American Ceramic Society

When Pb(Mg 1/2 Nb 2/3 )O 3 –35PbTiO 3 (mol%) (PMN–35PT) is sintered at 1200°C after packing in PbZrO 3 powder, the grains show normal growth with time invariant normalized grain size distributions. If 0.5 wt% MgO is added to PMN–35PT, abnormal grain growth occurs with the large abnormal grains developing nearly cubic…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Improvement of Corrosion‐Wear Resistance of Ti‐6Al‐4V Alloy by Plasma Mo‐N Surface Modification

Bin Tang、Pengpeng Wu、Ailan Fan 等 6 位作者2005-04-01Advanced Engineering Materials

Ti‐6Al‐4V alloy has attracted increasing applications as a metallic biomaterial in recent years thanks to its good corrosion resistance and biocompatibility. However, the poor corrosion‐wear resistance of the alloy is thus a major concern to potential users. In this paper, the electrochemical noise technique is used a…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

The order-disorder character of FeOHSO4 obtained from the thermal decomposition of metahohmannite, Fe3+2(H2O)4[O(SO4)2]

Gennaro Ventruti2005-04-01American Mineralogist

The iron sulfate FeOHSO 4 studied was obtained as a dehydration product of metahohmannite Fe 2 (H 2 O) 4 [O(SO 4 ) 2 ] during a synchrotron real-time powder diffraction experiment. As quoted in the literature, FeOHSO 4 has iron atoms octahedrally coordinated with two hydroxyl groups and four sulfate O atoms, while eac…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Synthesis, Structure, and Luminescent Properties of Guanidinate‐Based Terbium Complexes

Xing'an Pang、Hongmei Sun、Yong Zhang 等 5 位作者2005-04-01European Journal of Inorganic Chemistry

Abstract Two guanidinate‐based terbium complexes [ i PrNC(N i Pr 2 )N i Pr] m TbCl 3– m [ m = 3 ( 1 ), 2 ( 2 )] were synthesized, and the crystal structure of 1 was determined by single‐crystal X‐ray diffraction. Complexes 1 and 2 were further characterized by elemental analysis, IR, and 1 H NMR spectroscopy. In compl…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Fabrication Routes for Yttria‐Stabilized Zirconia Suitable for the Production of Minor Actinide Transmutation Targets

Joseph Somers、Asunción Fernández2005-04-01Journal of the American Ceramic Society

The actual fabrication processes of targets for the transmutation of actinides in nuclear reactors will need to be dust‐free and compatible with automation and remote operation. The developments reported here mark an important technical breakthrough in the fabrication of highly active materials. The sol–gel external g…

Nuclear Materials and PropertiesAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Novel Low-Molecular-Weight Gelators Based on Azobenzene Containing l-Amino Acids

Daisaku Inoue、Masahiro Suzuki、Hirofusa Shirai 等 4 位作者2005-04-01Bulletin of the Chemical Society of Japan

Abstract A series of azobenzene derivatives containing glycine, l-alanine, l-valine, l-leucine, and l-isoleucine were synthesized and their gelation properties were examined. Although the azobenzene derivatives containing glycine, l-alanine, and l-leucine exhibited very low gelation abilities, other compounds of l-iso…

Porphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Use of a Mesoporous Material for Organic Synthesis

Tomasz Witula、Krister Holmberg2005-04-01Langmuir

A common problem in synthetic organic chemistry is attaining proper contact between lipophilic organic compounds and inorganic salts. Various strategies, for example, phase transfer catalysis (Starks, C. M.; Liotta, C. L.; Halpern, M. Phase Transfer Catalysis: Fundamentals, Applications and Industrial Perspectives; Ch…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Characteristics of Clay Minerals in Podzols and Podzolic Soils

Yasuo Kitagawa2005-04-01Soil Science & Plant Nutrition

The clay minerals in Podzols and podzolic soils developed under coniferous forests in the Subarctic and Cool-temperate zones are characterized by the predominance of smectite and/or mica-smectite interstratified minerals in the eluvial horizons and chlorite-vermiculite intergrade in the illuvial horizons. A large amou…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions