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Study of the Isotope Effects in the Hydrogen Transport in Polycrystalline Tungsten

G.A. Esteban、A. Perujo、F. Legarda2005-03-01Materials science forum

A time-dependent gas-phase isovolumetric desorption technique has been used to evaluate the diffusive transport parameters of hydrogen isotopes in polycrystalline tungsten in the temperatures range 673 to 1073 K and driving pressures from 1.3 104 to 105 Pa. Experiments have been run with both protium and deuterium obt…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Martensitic α↔γ Phase Transition and Ionic Conductivity in "Pure" and Doped LiIO<sub>3</sub> Single Crystals

Viera Trnovcová、F. Hanic、Tatjana Šrámková 等 4 位作者2005-03-01Materials science forum

The polymorphism and anisotropy of electrical, dielectric, and thermophysical properties of “pure” and doped LiIO3 single crystals are studied. The hexagonal a-LiIO3 phase is a 1-D ionic conductor (along the c axis). The anisotropy of the ionic conductivity of the a-phase can be reduced by doping with transitive metal…

Advanced Battery Materials and TechnologiesIonic liquids properties and applicationsSolid-state spectroscopy and crystallography

Non-linear Crystalline Spherulitic Growth Behavior for LLDPE

Musa R. Kamal、Lijun Feng2005-03-01International Polymer Processing

Abstract Nonlinear growth behavior was observed in two crystallization regimes, depending on the temperature. Non-linearity may be explained by the reduction of the concentration of crystallizable ethylene sequences (CES) in the melt phase. In the two regimes, the concentration of uncrystallizable ethylene sequences (…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Corrosion inhibition of 70Cu-30Zn alloy in 0,5 M HNO3by 3-amino-1,2,4-triazole

S. El Issami、L. Bazzi、M. Mihit 等 6 位作者2005-03-01Journal de Physique IV (Proceedings)

The inhibitive action of 3-amino-1,2,4-triazole (ATA) on 70Cu-30Zn alloy corrosion in HNO 3 0,5M was examined. Gravimetric and electrochemical tests were used. The results obtained show that the ATA reduces effectively the dissolution of 70Cu-30Zn alloy. The inhibition efficiency in aerated acid increased with increas…

Corrosion Behavior and Inhibition

Drying Rates in Resin Treatment of Lyocell Fabrics

Avinash P. Manian、Thomas Bechtold2005-03-01Textile Research Journal

Many properties of lyocell fibers are markedly different from those of other cellulosic fibers. Hence, it is necessary to study Lyocell wet processing to determine and characterize variables that have a significant influence on the properties of finished products. At the Christian-Doppler Laboratory, we are conducting…

Natural Fiber Reinforced CompositesTextile materials and evaluationsMaterial Properties and Processing

Europium nitride synthesized by direct nitridation with ammonia

Takayuki Suehiro、Naoto Hirosaki、Tohru Wada 等 5 位作者2005-03-01Powder Diffraction

Europium nitride (EuN), which is potentially used as an activator for nitride luminescent materials, was prepared by direct nitridation at 600 °C in a NH 3 atmosphere. X-ray powder diffraction and composition analysis of the nitrided sample were carefully conducted under an oxygen-free environment. The nitrided sample…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsInorganic Chemistry and Materials

Structures and Magnetic Properties of First-Row Transition Metal Complexes with Bridging Ligands, Squarate or Pyrazine

A. Jimbo-Kobayashi、Akiko Kobayashi、Itaru Tamura 等 5 位作者2005-03-01Bulletin of the Chemical Society of Japan

Abstract For the purpose of construction of the hydrogen-bonded and coordination-bonded supramolecular network, MnII complex bridged by squarate molecules was synthesized, and their structural and magnetic properties were studied. X-ray structure determination revealed that MnII complex, [MnII4(C4O4)4(C4H4N2)(H2O)8],…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The role of boron impurity in the activation of free charge carriers in layers of porous silicon during the adsorption of acceptor molecules

Л. А. Осминкина、Е. А. Константинова、Konstantin S. Sharov 等 5 位作者2005-03-01Semiconductors

Infrared-absorption spectroscopy and electron spin resonance are used to study the role of boron impurity in the activation of free charge carriers in layers of porous silicon that have been exposed to nitrogen dioxide acceptor molecules. It is found that the higher the level of doping is for the substrates used in th…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Purification and Characterization of a Novel Sialidase from a Strain of Arthrobacter nicotianae

I Abrashev2005-03-01The Journal of Biochemistry

The nonpathogenic strain Arthrobacter nicotianae produces two sialidase isoenzymes, NA1 and NA2, with molecular masses of 65 kDa and 54 kDa, respectively, as determined by 10% SDS-polyacrylamide gel electrophoresis. NA1 and NA2 exhibit maximum activities at pH 4 and 5, and both show clear thermal optima at 40 degrees…

Glycosylation and Glycoproteins ResearchEnzyme Structure and FunctionEnzyme Production and Characterization

Synthesis of Y(P,V)O4:Eu3+ Red Phosphor by Spray Pyrolysis without Postheating

Y. Shimomura、Tomoyuki Kurushima、Risa Olivia 等 4 位作者2005-03-01Japanese Journal of Applied Physics

We synthesized europium-activated yttrium phosphovanadate (Y(P,V)O 4 :Eu 3+ ) red phosphor, which is expected to be applicable in plasma display panels, by spray pyrolysis. The effect of pyrolysis temperature on luminescence characteristics was clarified and the mechanism of this effect is discussed. A precursor solut…

Luminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallographyAmmonia Synthesis and Nitrogen Reduction

In Situ Soft X-ray Studies of Ethylene Oxidation Mechanisms and Intermediates on the Pt(111) Surface

Daniel J. Burnett、Aaron M. Gabelnick、Daniel A. Fischer 等 5 位作者2005-03-01The Journal of Physical Chemistry B

In situ studies of ethylene oxidation on Pt(111) have been performed using a powerful combination of fluorescence yield soft X-ray methods for temperatures up to 600 K and oxygen pressures up to 0.01 Torr. Absolute carbon coverages have been determined both in steady-state and dynamic catalytic conditions on the Pt(11…

Advanced Chemical Physics StudiesMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Orientation Distribution Functions Based upon Both 〈 P 1 〉, 〈 P 3 〉 Order Parameters and upon the Four 〈 P 1 〉 up to 〈 P 4 〉 Values: Application to an Electrically Poled Nonlinear Optical Azopolymer Film

Vincent Rodriguez、F. Lagugné-Labarthet、C. Sourisseau2005-03-01Applied Spectroscopy

The most probable orientational distribution functions of rod-like polar molecules contained in a noncentrosymmetric uniaxial system are established using the first-rank and third-rank Legendre polynomials, (P1(cos theta)) and (P3(cos theta)) order parameters, and the maximum entropy method. Emphasis is put on the dif…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Optical Materials Research

High intensity pulse x-ray generation by using graphite-nanocrater cold cathode

Takahiro Matsumoto、Hidenori Mimura2005-03-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Graphite nanostructures fabricated by a simple plasma etching onto a graphite substrate provide an intense emission source of electrons. This cathode does not have the adherence problem commonly seen in carbon deposited emission layera such as carbon nanotubes and graphite nanofibers, thus making it promising for appl…

Carbon Nanotubes in CompositesPulsed Power Technology ApplicationsIon-surface interactions and analysis

The Effect of Clay Content on PMMA-Clay Nanocomposite Foams

Allan R. Manninen、Hani E. Naguib、A. Victoria Nawaby 等 5 位作者2005-03-01Cellular Polymers

In this study the CO 2 sorption at 45 °C in PMMA nanocomposite films containing 2 wt.% of nanoclay has been measured using an in-situ gravimetric technique. The films examined were prepared by compression moulding material obtained by dry-blend and solvent co-precipitation techniques. The CO 2 diffusion coefficients w…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Effect of displacement and distortion of potential energy surfaces and overlapping resonances of electronic transitions on surface-enhanced Raman scattering: Models and ab initio theoretical calculation

M. T. Lee、De‐Yin Wu、Zhong‐Qun Tian 等 4 位作者2005-03-01The Journal of Chemical Physics

A previously developed theory for the temperature-dependent resonance Raman scattering is used to study the surface-enhanced Raman scattering. Two models, the displaced oscillator model and the displaced-distorted oscillator model, based on the harmonic potential energy surfaces are carried out to calculate the surfac…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Quantum Chemical StudiesElectrochemical Analysis and Applications

Magnetic and transport properties of monocrystallineFe 3 O 4

Karen Paul2005-03-01Open Physics

Abstract A monocrystal ofFe 3 O 4 is characterized by resistance, magnetoresistance and magnetic measurements in a temperature range from 4.2 K to 350 K and magnetic field-cycling from −9 T to 9 T. The resistance measurements revealed a metal-insulator Verwey transition (VT) atT v=123.76 K with activation energy E=92.…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesAdvanced Condensed Matter Physics

Comparison of Mehlich 2, Mehlich 3, CAL, Schachtschabel, 0.01 M CaCl2and Aqua Regia Extractants for Determination of Potassium in Soils

Jiří Zbíral、Pavel Němec2005-03-01Communications in Soil Science and Plant Analysis

Mehlich 3, Mehlich 2, CAL (calcium lactate), Schachtschabel, 0.01 M CaCl2, and aqua regia were compared as soil potassium extractants. Comparison was focused on the relationships between Mehlich 3 as a Czech official soil‐testing method and the extractants used for this purpose in the past (Mehlich 2, Schachtschabel)…

Soil and Unsaturated FlowSoil Geostatistics and MappingClay minerals and soil interactions

Diamonds

George E. Harlow、R. Davies2005-03-01Elements

Research Article| March 01, 2005 Diamonds George E. Harlow; George E. Harlow American Museum of Natural History, New York, NY 10024-5192, USA E-mail: gharlow@amnh.org Search for other works by this author on: GSW Google Scholar Rondi M. Davies Rondi M. Davies American Museum of Natural History, New York, NY 10024-5192…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Modulated Air Layer Heat and Moisture Transport by Ventilation and Diffusion From Clothing With Open Aperture

Nesreen Ghaddar、Kamel Ghali、Jihad Harathani2005-03-01ASME Journal of Heat and Mass Transfer

A two-dimensional model is developed for the modulated internal airflow, due to walking, in the gap between clothing and skin surface in the presence of clothing apertures. The normal airflow renewing the air layer through the fabric is modeled using the Ghali et al. three-node fabric ventilation model with corrected…

Infection Control and VentilationThermoregulation and physiological responsesTextile materials and evaluations

Natural behavior of the magnetization under spontaneous reorientation: TmFeO3, ErFeO3

L. T. Tsymbal、Ya. B. Bazaliı̆、G. N. Kakazeı̆ 等 5 位作者2005-03-01Low Temperature Physics

A SQUID magnetometer is used to study the behavior of the magnetization of TmFeO3 single crystals along the a and c principal crystallographic axes in the Γ4–Γ24–Γ2 spin reorientation range. The temperature dependences are obtained as the moduli of the magnetization vector M and its turn angle θ in the reorientation r…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsGeomagnetism and Paleomagnetism Studies