Materials Literature
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A synthesis method for the production of amorphous metallic foam is introduced. This method utilizes the thermodynamic stability and thermoplastic formability of the supercooled liquid state to produce low-density amorphous metallic foams in dimensions that are not limited to the critical casting thickness. The method…
A high-vacuum plasma-assisted chemical-vapor deposition system was used to systematically study ZnO:N thin film synthesis. Nitrogen doping was achieved by mixing either N2O or N2 with O2 in a high-density inductively coupled plasma (ICP) source. In situ diagnostics showed that the ICP composition was predominantly a f…
This research investigated the expansion behavior of extruded polycarbonate (PC) foams blown with supercritical (sc) CO 2 to achieve low-density microcellular foams. The expansion behavior of PC foam was interpreted by the amount of gas retained in the cell structure in consideration of cell opening, cell-to-cell diff…
An intense infrared absorption band has been observed in a hydrothermally grown ZnO crystal. At 12K, the band peaks near 3577.3cm−1 and has a half width of 0.40cm−1, and at 300K, the band peaks at 3547cm−1 and has a half width of 41.3cm−1. This absorption band is highly polarized, with its maximum intensity occurring…
We report structure-property correlations in single-wall carbon nanotube (SWNT) fibers, among electrical, thermal, and chemical parameters with respect to stretch-induced preferential SWNT alignment along the fiber axis. Purified HiPco (high-pressure CO) conversion tubes are dispersed with the aid of an anionic surfac…
Strong attractive interaction between two clean diamond (001) slabs turns repulsive upon the hydrogenation of surfaces. This repulsive interaction serves as if a boundary lubricant and prevents the sliding surfaces from being closer to each other even under high normal forces. As a result, calculated lateral force var…
Nanostructured NbO 2 films have been prepared on Si (001) substrates by thermally oxidizing a spiral niobium coil in a vacuum of the order of 10 −2 Torr. The film consists of single-crystalline NbO 2 nanoslices (several tens of nanometres thick) that are aligned with each other. When excited with 512 nm light, the NbO…
Poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (P(3HB-co-3HV)) copolymers were prepared via shake-flask fermentations of Burkholderia cepacia (formerly Pseudomonas cepacia) containing 2.2% (w/v) xylose and concentrations of levulinic acid ranging from 0.07% to 0.67% (w/v). Periodic harvest of shake-flask cultures…
We investigate through direct molecular mechanics calculations the geometrical properties of hydrocarbon mantles subjected to percolation disorder. We show that the structures of mantles generated at the critical percolation point have a fractal dimension $d_{f} \approx 2.5$. In addition, the solvent access surface $A…
Poly(D,L-lactic-co-glycolic acid) (PLGA) microspheres were prepared by an oil/water emulsion solvent evaporation method to use as an injectable microcarrier for cell delivery. Three different kinds of PLGA microspheres having hydrophobic, negatively charged, and positively charged surfaces were prepared. Hydrophobic a…
To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu(2)(ophen)(2)](2) (Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and synthesized a series of such [M(2)L(2)](2) structures by varying the d(10) metal and/or the ligand (M=Cu(I) or Ag(I), L=ophen or obpy; Hobpy=1H-[2,2']bipy…
Directly meso-meso linked porphyrin rings CZ4, CZ6, and CZ8 that respectively comprise four, six, and eight porphyrins have been synthesized in a stepwise manner from a 5,10-diaryl zinc(II) porphyrin building block. Symmetric cyclic structures have been indicated by their very simple (1)H NMR spectra that exhibit only…
We have synthesized a series of amphiphilic molecules consisting of oligo(phenylene vinylene) (OPV) asymmetrically end-substituted with a hydrophilic poly(ethylene glycol) (PEG) segment and a hydrophobic alkyl chain. This amphiphilic structure induces self-assembly into both thermotropic and lyotropic lamellar liquid…
For the first time nanoparticles of CdP2 and CdP4 semiconductors were prepared and studied. The nanoparticles were prepared by incorporation into zeolite Na-X matrix. Absorption and photoluminescence (PL) spectra of CdP2 and CdP4 nanoparticles were measured at the temperature of 77 K. Two bands were observed in both t…
The intrinsic iron(III) impurity center in polycrystalline lead titanate was investigated by means of high-frequency electron paramagnetic resonance spectroscopy in order to determine the local-environment sensitive fine-structure parameter D. At a spectrometer frequency of 190GHz, a spectral analysis of a powder samp…
Impedance spectroscopy, transmission electron microscopy, and electron energy-loss spectroscopy are used to correlate local electrical properties with the microstructure and microchemistry of BaTiO3 in Ni-electrode multilayer ceramic capacitors. High densities of linear defects and some grains with structural modulati…
The microchemical and microstructural origins of insulation-resistance degradation in BaTiO3-based capacitors are studied by complementary impedance spectroscopy and analytical transmission electron microscopy. The degradation under dc-field bias involves electromigration and accumulation of oxygen vacancies at interf…
Phragmatopoma californica is a marine polychaete that builds protective tubes by joining bits of shell and sand grains with a secreted proteinaceous cement. The cement forms a solid foam (closed cells) via covalent crosslinking, as revealed by electron and laser scanning confocal microscopy. The cement contains extrac…
N-confused porphyrin (NCP) is a porphyrin isomer that is different largely from the parent porphyrin, particularly in the physical, chemical, structural, and coordination properties. Introduction of the confused pyrrole into the normal and expanded porphyrins leads to generation of the confused porphyrinoids having ri…
The electronic conduction through a ${\mathrm{Pr}}_{0.7}{\mathrm{Ca}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ thin film is investigated by measurements using dc and pulsed biases. Semiconducting ${\mathrm{Pr}}_{0.7}{\mathrm{Ca}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ films sandwiched by electrodes show both hysteretic and asymme…