Symmetrically tetra-substituted phthalocyanines
Symmetrically tetra-substituted phthalocyanines with four quinone or porphyrin units attached have been synthesised and some of their spectroscopic properties are reported.
Materials Literature
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The calcite-aragonite transition : mechanism and microstructures induced by the transformation stresses and strain
The calcite-aragonite transition has been experimentally investigated both under hydrostatic conditions and in the presence of deviatoric stresses. The calcite → aragonite experiments at high-pressure have been performed in a Griggs apparatus in the presence of deviatoric stresses whereas the aragonite → calcite exper…
A Reinvestigation of the Binding Energy Versus Atomic Charge Relation for Oxygen From X-Ray Photoelectron Spectroscopy
An improved correlation between the binding energy of oxygen core electrons (Eb (Ols)) and the effective charge of the oxygen atom (qo) is proposed: Eb(01s) =4.23-qo +534.1.
Engineering Dielectrics Volume IIB Electrical Properties of Solid Insulating Materials: Measurement Techniques
Description Fight chapters describe testing procedures suitable for the measurement of dielectric properties of solid insulating materials. They explain why dielectric measurements are made, their specialized uses, and their limitations.
Chapter 7. X-Ray spectroscopy
C. Bonnelle, Annu. Rep. Prog. Chem., Sect. C: Phys. Chem., 1987, 84, 201 DOI: 10.1039/PC9878400201
Asymmetric Epoxidation of Homoallylic Alcohols Using Zirconium Tetrapropoxide, Dicyclohexyltartramide, and t-Butyl Hydroperoxide System
Abstract In the asymmetric epoxidation of homoallylic alcohols, a combination of zirconium tetrapropoxide, dicyclohexyltartramide, and t-butyl hydroperoxide was found to give good enantiomeric selectivities (up to 77% ee) especially for (Z)-homoallylic substrates.
Crystal and magnetic structures of Fe0.25TiSe2 and Fe0.48TiSe2
The crystal and magnetic structures of the lamellar FexTiSe 2 (x = 0.25 and 0.48) antiferromagnets have been refined from neutron diffraction powder data at several temperatures ranging from 2 to 300 K. For both compounds, Ti is found to be substituted for 8 % of Fe so that the separation of the two metals is not comp…
The Tiling Patterns of Sebastien Truchet and the Topology of Structural Hierarchy
Cyril Stanley Smith, Pauline Boucher, The Tiling Patterns of Sebastien Truchet and the Topology of Structural Hierarchy, Leonardo, Vol. 20, No. 4, 20th Anniversary Special Issue: Art of the Future: The Future of Art (1987), pp. 373-385
Effect of Dislocation Trapping on Hydrogen and Deuterium Diffusion in Iron
The diffusion coefficients of hydrogen and deuterium in commercially pure iron deformed and annealed under various conditions have been measured at temperatures between 283 and 318 K by an electrochemical permeation method. The temperature dependence of the diffusion coefficients of hydrogen (DH) and deuterium (DD) is…
Water-soluble cryptophane binding lipophilic guests in aqueous solution
The first water-soluble cryptophane (4) has been synthesized in three steps from cryptophane-A (1); (4) has been found to complex chloroform and dichloromethane strongly in D2O, with binding constants in the range 103–104 dm3/mol.
Immobilization of Cesium into Pollucite Structure by Hydrothermal Hot-Pressing
In order to immobilize Cs into pollucite structure, hydrothermal reactions of Cs with amorphous aluminosilicate (siliceous sinter) and with mixtures of low-quartz (silicastone) and Al(OH)3, were performed. In both cases, pollucite was formed in 5-N NaOH solution above 200°C for 10 min. Synthesized pollucite was solid…
Alkali metal, chlorine and other promoters in the silver-catalysed selective oxidation of ethylene
Ethylene oxidation over well characterised Ag(111) surfaces has been investigated by temperature-programmed reaction measurements and by differential batch reactor studies at pressures up to 50 Torr. The influence of chlorine predosing on catalytic activity indicates that a chemisorbed atomic oxygen species is respons…
Electron microscope investigation of the structures of annealed carbons
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron microscope investigation of the structures of annealed carbonsPeter R. Buseck, Bojun Huang, and Lindsay P. KellerCite this: Energy Fuels 1987, 1, 1, 105–110Publication Date (Print):January 1, 1987Publication History Published online1 May 2002Published inissue 1 Janu…
Immobilization of cesium into pollucite structure by hydrothermal hot-pressing.
In order to immobilize Cs into pollucite structure, hydrothermal reactions of Cs with amorphous aluminosilicate (siliceous sinter) and with mixtures of low-quartz (silicastone) and Al(OH)3, were performed. In both cases, pollucite was formed in 5-N NaOH solution above 200°C for 10 min. Synthesized pollucite was solid…
Photochemical epoxidation of alkenes by visible light in a redox system involving tetraphenylporphyrinantimony(V) and water
Irradiation with visible light of a mixture of an alkene in degassed aqueous acetonitrile containing tetraphenylporphyrinantimony(V) as a sensitizer, methylviologen as an electron acceptor, and hydroxide ion, induced epoxidation of the alkene accompanied by hydrogen evolution, with water acting as the electron donor.
New spin-crossover iron(III) complexes with large hysteresis effects and time dependence of their magnetism
The new complexes [FeL12] ClO4(HL1= tridentate Schiff base formed by 1 : 1 condensation of o-aminophenol and pyridine-2-carbaldehyde) and [FeL22] NCS ( HL2= tridentate Schiff base formed by 1 : 1 condensation of 8-aminoquinoline and salicylaldehyde) were synthesized. The spin-crossover behaviour between S=½ and 5//2 w…
Radiative Wave Equations for Vector Electromagnetic Propagation in Dense Nontenuous Media
A set of radiative wave equations including all four Stokes parameters is derived for vector electromagnetic wave propagation in dense nontenuous media. The derivation is based on the quasi-crystalline approximation with coherent potential on the first moment of the field, and the modified ladder approximation on the…
Fiber Identification in Practice
Brief case studies of the problems in identification of a wide variety of ethnographic and archaeological fibers are given. The strategy of identification varied with the purpose (choice of treatment, assessment of damage or identification of its cause, or authentication) but most of all with the condition of the fibe…
Fourier transform mechanical analysis for determining the nonlinear viscoelastic properties of polymers
Abstract Fourier Transform Mechanical Analysis (FTMA) has been used to study the strain amplitude dependent nonlinear dynamic mechanical properties of two elastomer compounds, nitrile rubber (NBR) and Neoprene, at various frequencies up to 750 Hz. Basic theory and experimental results are presented for one‐dimensional…
Hindered internal conversion in rigid media. Thermally nonequilibrated 3IL and 3CT emissions from [Cu(5-X-phen)(PPh3)2]+ and [Cu(4,7-X2-phen)(PPh3)2]+ systems in a glass at 77 K
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHindered internal conversion in rigid media. Thermally nonequilibrated 3IL and 3CT emissions from [Cu(5-X-phen)(PPh3)2]+ and [Cu(4,7-X2-phen)(PPh3)2]+ systems in a glass at 77 KDominick J. Casadonte Jr. and David R. McMillinCite this: J. Am. Chem. Soc. 1987, 109, 2, 331–337P…