Materials Literature
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The regeneration kinetics of the integral membrane protein bacteriorhodopsin have been investigated in a lipid-based refolding system. Previous studies on bacteriorhodopsin regeneration have involved detergent-based systems, and in particular mixed dimyristoylphosphatidylcholine (DMPC)/CHAPS micelles. Here, we show th…
The relative shift of the Eu(III) 7 F 0 − 5 D 0 transition toward lower energies due to the formation of inner-sphere Eu(III) complexes is shown to be linearly proportional to the total ligand donor number of the ligand bound to Eu(III) for 40 organic ligand complexed species in both water and DMSO solvents. Such a co…
This paper presents a brief survey of the structures and properties of early transition-metal oxides containing d0 and d1–d0 electronic configurations. The metal–oxygen (MO6) octahedron, which is the essential structure building unit of these materials, exhibits a characteristic out-of-centre distortion for the d0 con…
Template technique makes it possible to prepare Pt metal-filled uniform carbon nanotubes in which the metal is present as either nanorods or nanoparticles.
4-Substituted n -5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluorododecan-1-yloxybenzenes, n -5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecan-1-yloxybenzenes, and 2-methyl-4-substituted n -5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecan-1-yloxybenzenes were synthesized and characterized by a c…
In this paper, an extract from fruits pods of Caesalpinia spinosa (tara) a native leguminosae widely distributed in Peru, known by its high tannin content is evaluated for its utilization in wood adhesives. Commercial pods of tara were extracted for 1 hour with water (1:4w/v) at 65°C. The extract was spray-dried to ob…
The mechanism of the oxidation of cycloalkanes by tertiary alkyl hydroperoxides catalysed by iron(III) dichlorotris(2-pyridylmethyl)amine [FeIIICl2(TPA)]+ and by the acetate bridged (µ-oxo) di-iron complex [Fe2III(TPA)2O(OAc)]3+ has been investigated. Product studies do not support oxidation via a high valent iron–oxo…
We describe a simple method of controlling the channel diameter of the mesoporous molecular sieve MCM-41 in the 26.1–36.5 Å range and the wall thickness in the 13.4–26.8 Å range while using the same gel mixture. This is achieved by varying the synthesis temperature in the 70–200°C range and/or reaction times in the 0.…
Organ or tissue failure remains a frequent, costly, and serious problem in health care despite advances in medical technology. The large number of patients suffering from tissue losses or organ failures is demonstrated by the approximately 8 million surgical procedures and 40 to 90 million hospital days required annua…
The new oxygen-ion conductor La 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 3-x has been prepared by conventional solid-state reaction at high temperatures and characterised by X-ray diffraction, scanning and transmission electron microscopy, and conductivity (four-probe dc and impedance) measurements. The room-temperature structure i…
Electrical wear-out and dielectric breakdown of insulating polymers involve dissipation to the lattice of the energy of mobile or trapped space charges. Optical emissions are proof of such energy releases and can be used to define the onset of electrical aging and to investigate the dissipation mechanisms. They also c…
In a real system the heating is nonuniform, and a second-order phase transition to a broken-symmetry phase occurs by propagation of a temperature front. Two parameters, the cooling rate τ Q and the transition front velocity ν T determine the nucleation of topological defects. Depending on the relation of these paramet…
This paper presents a new arc furnace model which copes with the two main voltage disturbances normally associated with arc furnaces: voltage fluctuations; and harmonics. The model is based on the stochastic nature of the electric arc current-voltage characteristic. The model has been estimated from measurements made…
The Current Status of IPNs Phase Separation During Synthesis of Polyetherimide/Epoxy Semi-IPNs A Review of Kinetic Studies on the Formation of IPNs IPNs Based on Polyurethane and Poly(butyl-methacrylate): Interrelation Between Reaction Kinetics and Microphase Structure Latex IPNs: From Structures to Properties Poly(et…
CO chemisorption on Pt catalysts supported on non-acidic alumina prepared from platinum acetylacetonate has been studied by FTIR spectroscopy. The stretching frequency for isolated CO species is observed at 2032 cm−1 for highly dispersed Pt samples (dispersion 0.99) and at 2067 cm−1 for poorly dispersed samples (dispe…
This paper presents nanoscopic aspects of electronic aging in dielectrics, as the result of the interaction of excess non-thermalized carriers with the media. Hot electrons are hypothesized as the major source of non-thermal carriers and shown to be a decisive factor in electrical breakdown. The interaction of hot ele…
BACKGROUND AND OBJECTIVE: Linear birefringence is an anisotropic property of rat tail tendon, which is largely composed of collagen. Our goal is to show that the dynamic range and sensitivity of the linear birefringence loss of collagen during heating are sufficient for kinetic modeling of the reaction. STUDY DESIGN,…
A new, ambient-temperature method for the direct synthesis of organo-substituted polyphosphazenes is described. It involves the initiation of a series of organophosphoranimines R(R‘)XP NSiMe 3 ( 3, R = Ph, R‘ = X = Cl; 5, R = R‘ = Ph, X = Cl; 7, R = Me, R‘ = Et, X = Cl; 9, R = R‘ = CF 3 CH 2 O, X = Br) with catalytic…
Ruthenium porphyrin and porphycene complexes catalyse stereospecific cyclopropanation of styrenes; high product turnovers with up to 90.8% ee were achieved with the [Ru(P*)(CO)(EtOH)] catalyst (H 2 P* = chiral D 4 porphyrin).
The crystal structure of the R-phase was determined by combined use of the electron diffraction and the powder X-ray diffraction method. The Rietveld method was applied for the analysis of the powder diffraction data. The structure of the R-phase belongs to the space group P3 and is similar to that of ζ′2 Au–Cd marten…