Materials Literature
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Polypeptide-based diblock copolymers forming either well-defined self-assembled micelles or vesicles after direct dissolution in water or in dichloromethane have been studied combining light and neutron scattering with electron microscopy experiments. The size of these structures could be reversibly manipulated as a f…
Mg x Zn 1 − x O nanowires with Mg-content x from 0 to 0.2 have been grown by high-pressure pulsed-laser deposition (PLD) on gold-covered sapphire single crystals. The PLD process allows for a unique wide-range control of morphology, diameter, and composition of the MgxZn1−xO nanowires. The diameter of single ZnO wires…
The relationship between the luminescence at 1.9 eV and the absorption bands at 2.0 eV and at 4.8 eV were investigated in a wide variety of synthetic silica samples exposed to different gamma- and beta-ray irradiation doses. We found that the intensities of these optical bands are linearly correlated in agreement with…
Dielectric properties of material mixtures are of importance in diagnostics, characterization and design of systems in various engineering fields. In this Letter, we propose a peculiar dielectric mixture expression, which is based on the dielectric relaxation phenomena and the spectral density representation [E. Tunce…
A new type of elasticity of random (multifractal) structures is suggested. A closed system of constitutive equations is obtained on the basis of two proposed phenomenological laws of reversible deformations of multifractal structures. The results may be used for predictions of the mechanical behavior of materials with…
Novel donor-acceptor nanoassemblies (see cover) are prepared using pristine single-walled carbon nanotubes (SWNTs) as electron-acceptor components in supramolecular “polymer wraps”, with poly(methyl methacrylate) carrying porphyrin units (H2P) as excited-state electron donors (see Figure). In these novel donor–accepto…
Author: Liaw, D. J. et al.; Genre: Journal Article; Issued: 2005; Title: High thermal stability and rigid rod of novel organosoluble polyimides and polyamides based on bulky and noncoplanar naphthalene-biphenyldiamine
We have found that single-chain schizophyllan and curdlan (s-SPG and s-curdlan, respectively) can dissolve as-grown and cut single-walled carbon nanotubes (ag-SWNTs and c-SWNTs, respectively) in aqueous solution. The vis-NIR spectra of the composites suggest that c-SWNTs are dissolved as a bundle, whereas ag-SWNTs exi…
Abstract This paper reviews new approaches to size‐controlled silicon‐nanocrystal synthesis. These approaches allow narrowing of the size distribution of the nanocrystals compared with those obtained by conventional synthesis processes such as ion implantation into SiO 2 or phase separation of sub‐stoichiometric SiO x…
We describe a simple and versatile technique to produce magnetic tubes by filling carbon nanotubes (CNTs) with paramagnetic iron oxide particles ( approximately 10 nm diameter). Commercial ferrofluids were used to fill CNTs with an average outer diameter of 300 nm made via chemical vapor deposition into alumina membra…
Many microscopy studies require reconstruction from serial sections, a method of analysis that is sometimes difficult and time-consuming. When each section is cut, mounted and imaged separately, section images must be montaged and realigned to accurately analyse and visualize the three-dimensional (3D) structure. Reco…
Fourier transform (FT) is a fundamental step for the data reduction and interpretation of extended x-ray absorption fine structure (EXAFS) spectra. The FT separates backscattering atoms by their radial distance from the absorbing atom (so-called shells). We suggest to routinely complement the FT by a wavelet transform…
We report ultra-efficient multiple exciton generation (MEG) for single photon absorption in colloidal PbSe and PbS quantum dots (QDs). We employ transient absorption spectroscopy and present measurement data acquired for both intraband as well as interband probe energies. Quantum yields of 300% indicate the creation,…
Particularly uniform: Monodisperse ferrite microspheres can be synthesized to have diameters of about 200–800 nm (TEM image, left). High-resolution TEM analysis (image, right and inset) shows that each microsphere is a single crystal. Their hydrophilic and magnetic properties impart to the microparticles many potentia…
The electronic and atomic structures of quasi-one-dimensional blue bronze K0.3MoO3 were investigated by polarization-dependent O K-edge x-ray absorption near-edge structure (XANES) and Mo K-edge extended x-ray absorption fine structure (EXAFS) measurements at various temperature and applied voltages. The O K-edge XANE…
The effects of changing the host-lattice isotopes from natural silicon (approximately $^{28}\mathrm{Si}$) to $^{30}\mathrm{Si}$ are reported for some of the important local vibrational modes (LVMs) observed in as-grown and electron-irradiated Czochralski silicon. We show that the quanta of the LVMs shift to lower ener…
Recently, a hyperelastic-viscoplastic constitutive model was developed for PET and the noncrystallizing copolymer PETG (R. B. Dupaix, Ph.D. thesis, MIT, 2003). The materials were found to behave very similarly under monotonic loading conditions and the single constitutive model was able to capture both materials’ beha…
The sol–gel technique has been used to produce Ag–SiO2 nanocomposite thin films consisting of silver nanoparticles embedded in a SiO2 matrix. The size of the silver nanoparticles is of about (4±0.2)nm when the firing temperature is in the (500–700°C) range, as determined from ultraviolet-visible spectroscopy analysis.…
Abstract Isothermal and non‐isothermal crystallization kinetics of microbial poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyhexanoate) [P(3HB‐3HHx)] was investigated by differential scanning calorimetry (DSC) and 13 C solid‐state nuclear magnetic resonance (NMR). Avrami analysis was performed to obtain the kinetic parameters of…
We report a technique for the alignment of self-assembled protein systems, such as F-actin bundles and microtubules, in a surface-modified titanium or silicon microfluidic device. Assembling filamentous protein systems in a confined geometry produces highly aligned samples for structural and mechanical studies. Biomol…