Materials Literature
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Three porous metal–organic frameworks (MOFs) of {[Cd(HABTC)(H2O)2]·3H2O}n (1), {[Cd3(ABTC)2(H2O)9]·CH3OH·DMF·2H2O}n (2), and {[Mn3(ABTC)2(H2O)4]·9.5H2O}n (3) have been constructed using azobenzene-3,5,4′-tricarboxylic acid (H3ABTC) and Cd(NO3)2·4H2O/MnCl2·4H2O as building blocks. The results of single-crystal X-ray di…
A non-viral gene delivery nanovehicle based on Alkyl-PEI2k capped MnO nanoclusters was synthesized via a simple, facile method and used for efficient siRNA delivery and magnetic resonance imaging.
The interaction between biopolymers and metal nanoparticles (AgNPs) is a key element in the development of biomimetic nanomaterials with applications in catalysis, delivery, and recognition. Here we report a facile method for the functionalization of AgNPs by N-substituted glycine oligomers, "peptoids." Based on the e…
The influence of the Zn(2+) concentration and temperature on the electrochemical reduction of O(2) in a solution of zinc bis(trifluoromethanesulfonyl)imide (Zn(TFSI)(2)) salt in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR(14)TFSI) ionic liquid is presented. ZnO nanocrystalline films were then…
PVDF-g-[PBIEM-co-PPMA] graft copolymers were first synthesized in a “grafting from” process, involving thermally induced graft copolymerization of two inimers, 2-(2-bromoisobutyryloxy)ethyl methacrylate (BIEM) and propargyl methacrylate (PMA), from ozone-preactivated poly(vinylidene fluoride) (PVDF) chains. Microporou…
Our knowledge in the field of ocular drug delivery is rapidly expanding. An increase in the understanding of ocular drug absorption and disposition vis-à-vis developments in nanotechnology has led to the emergence of many of the nanotechnology-based ocular drug delivery systems including nanoparticles, microemulsions,…
The cone calorimeter and the fire propagation apparatus (FPA) are often used to carry out flammability studies of materials. There are various differences in the set-up of these two devices that could lead to different fire behaviour for the same material. Among these, the impact of the different heat sources used is…
We synthesized a Pt catalyst supported on nanometer-size titanium nitride particles (Pt/TiN) by the nanocapsule method. The titanium nitride (TiN) support, which was synthesized by the radio-frequency (RF) plasma method, had high electrical conductivity, up to 850 S cm −1 at room temperature, with a surface area of 40…
A series of phosphine ligands with different electronic and steric properties were evaluated at fully modified conditions in cobalt catalysed hydroformylation of 1-octene. The steric demand of the ligands was based on the Tolman cone angle model covering a range of 132-175°. The electron donating ability was evaluated…
Stability analysis of the radial pulsations of a gas microbubble that is encapsulated by a thin viscoelastic shell and surrounded by an ideal incompressible liquid is carried out. Small axisymmetric disturbances in the microbubble shape are imposed and their long and short term stability is examined depending on the i…
We report the synthesis of gold nanoparticles using coconut water through microwave irradiation. Synthesis was found to be very rapid with an optimum time of 17 s. The particles obtained were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and atomic force…
Initial cluster formation on silicon surfaces in cyclic deep reactive ion etching (c-DRIE) using c-C4F8/SF6 plasma is investigated. These clusters act as a nanomask for the fabrication of nanostructured surfaces such as silicon grass. Different wafer preconditioning regimes and subsequent x-ray photoelectron spectrosc…
We have constructed a novel class of light-activatable caged molecular beacons (cMBs) that are caged by locking two stems with a photo-labile biomolecular interaction or covalent bond. With the cMBs, the nucleic acid hybridization process can be easily controlled with light, which offers the possibility for a high spa…
We have developed a one-step method to prepare robust and smart gold nanoparticles (AuNPs) utilizing poly(N-isopropylacrylamide) (PNIPAAm)-grafted dextran (DexPNI) via a “grafting-onto” approach. Using NaBH4 as a reducing agent, and DexPNI as a nucleating and stabilizing agent, the AuNPs can be obtained at ambient tem…
X-ray photoelectron spectroscopy (XPS) is used to monitor the heterogeneous reaction of hydroxyl radicals (OH) and ozone with thin films (∼5 Å) of coronene. Detailed elemental and functional group analysis of the XPS spectra reveals that there is a competition between the addition of oxygenated functional groups (func…
The distribution of micro/nano-indentation hardness and microstructures of deformed Hadfield high manganese steel have been investigated by means of micro/nano-indentation tests, and optical and electron microscopic observations. Indentation tests demonstrated that there exists a very non-uniform distribution of hardn…
Novel indoline dyes, I-1-I-4, with structural modification of π-linker group in the D-π-A system have been synthesized and fully characterized. Molecular engineering through expanding the π-linker segment has been performed. The ground and excited state properties of the dyes have been studied by means of density func…
New catalytic systems based on in situ and preformed palladium nanoparticles in ionic liquids (characterised by TEM) starting from palladium acetate or dipalladiumtris(dibenzylideneacetone) have been applied in the synthesis of 4-phenylbutan-2-one (II), a model compound for the preparation of fragrances. Imidazolium-b…
A new metallofullerene Y(3)N@C(78)-C(2) was synthesized and characterized. It was shown that Y(3)N@C(78) has an unconventional C(78)-C(2) cage with two pairs of fused pentagons closely bonded with two yttrium atoms. DFT calculations showed that the size of the ionic radii of the metals forming the caged cluster plays…
peer reviewed