Materials Literature
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The thermal investigation of matter by use of a very localized heat source, scanning thermal microscopy (SThM), permits materials to be probed at the level of very small subsurface volumes. Therefore, the technique appears to be a promising method to study the thermal properties of thin films of submicrometric thickne…
We present a comparative study of atomic and electronic structures, Young's modulus, and optical conductivity of trigonal bulk tellurium and its nanowires of different diameters using first-principles density-functional theory calculations based on pseudopotentials and a generalized gradient approximation to exchange-…
Using first-principles density functional calculations, we have studied the magnetic ordering in pure ${\mathrm{Mn}}_{n}$ $(n=2--10,13,15,19)$ and $\mathrm{As}@{\mathrm{Mn}}_{n}$ $(n=1--10)$ clusters. Although, for both pure and doped manganese clusters, there exists many collinear and noncollinear isomers close in en…
Al-doped zinc oxide (AZO) thin films containing trace Ag nanoparticles (Ag/Zn = 0–0.15 at.%) were prepared by the sol–gel process. It was found that the doping of Ag nanoparticles resulted in the significant sintering of AZO grains and further led to the enhancement of conductivity. From the analysis of surface morpho…
Abstract The viability of the thermomechanical recycling of postconsumer milk pouches [a 50 : 50 low‐density polyethylene/linear low‐density polyethylene (LDPE–LLDPE) blend] and their use as polymeric matrices for coir‐fiber‐reinforced composites were investigated. The mechanical, thermal, morphological, and water abs…
Abstract LaF 3 :Eu 3+ (5.0 mol‐% Eu 3+ ) nanodisks with perfect crystallinity were successfully synthesized by a simple method. The synthesis was carried out in an aqueous solution at room temperature without the use of templates or organic additives. The mechanism of formation of the nanodisks was explored, and the f…
It has been proven that the maximum cooling temperature of a thermoelectric material can be increased by using either pulsed operation or graded Seebeck profiles. In this paper, we show that the maximum cooling temperature can be further increased by the pulsed operation of optimal inhomogeneous thermoelectric materia…
It has been long known that polymers can be mixed with clay minerals, however, the ideas of microcomposites have been expanded recently to a new and emerging class of clay-filled polymers, called Polymer-Clay Nanocomposites (PCN), which has experienced the real breakthrough early in the past decade only. This is a nov…
We have performed atomistic simulations of the tensile loading of and copper nanowires to investigate the coupled effects of geometry and surface orientation on their mechanical behaviour and properties. By varying the nanowire cross section from square to rectangular, nanowires with dominant surface facets are create…
Abstract Biodegradable foams derived from poly(lactic acid) (PLA) and starch were prepared by extrution using water as a blowing agent and talc as nucleation agent. Foam cellular size and size distribution was significantly affected by extrusion conditions (i.e., extruder temperature profiles, die diameters, and screw…
In this article, branched NaYF(4) nanocrystals have been successfully synthesized via a simple hydrothermal method. On the basis of the analysis of HRTEM and TEM images, the growth modes of the branched structure and further branching behavior have been proposed. The up- and down-conversion luminescence of branched Na…
Abstract A series of new nonlinear optical chromophores based on configurationally locked polyenes (CLPs) with chiral pyrrolidine donors are synthesized. All CLP derivatives exhibit high thermal stability with decomposition temperatures T d at least > 270 °C. Acentric single crystals of enantiopure D ‐ and L ‐proli…
A novel tube-shape thermoelectric module is fabricated from four ring-shaped thermoelements and its performance in electrical power generation is evaluated by measuring the power output as a function of temperature differences across the device. A theoretical model of the proposed configuration is established and empl…
Chlorhexidine (CH) is an effective antimicrobial agent. There has been very little work published concerning the interactions of CH with, and its adsorption mechanism on, cellulose. In this paper, such physical chemistry parameters are examined and related to computational chemistry studies. Adsorption isotherms were…
Pyriporphyrins with three different orientations for the pyridine moiety have been prepared using a '3 + 1' strategy. The nonaromatic pyriporphyrins are stable so long as phenyl substituents are present at the meso-positions adjacent to the pyridine ring. An aromatic dihydropyriporphyrin with an external CO2Ph protect…
Theoretical studies of the fractional quantum Hall effect (FQHE) in graphene have so far focused on the plausibility and stability of the previously known FQHE states for the interaction matrix elements appropriate for graphene. We consider FQHE for SU(4) symmetry, as appropriate for the situation when all four spin a…
Selective catalytic oxidation of NH 3 to give N 2 under UV irradiation (photo-SCO) takes place at a low temperature over the TiO 2 catalyst. An active site for the photo-SCO is a Lewis acid site on TiO 2, and adsorption of NH 3 to the Lewis acid site is the first step in the photo-SCO. The adsorbed NH 3 on the Lewis a…
We report high-resolution optical absorption spectra for $\mathrm{Nd}{\mathrm{Fe}}_{3}{(\mathrm{B}{\mathrm{O}}_{3})}_{4}$ trigonal single crystal, which is known to exhibit a giant magnetoelectric effect below the temperature of magnetic ordering ${T}_{N}=33\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The analysis of the t…
We have developed multifunctional fluorescent surface enhanced Raman spectroscopic tagging material (F-SERS dots) composed of silver nanoparticle-embedded silica spheres with fluorescent organic dye and specific Raman labels for multiplex targeting, tracking, and imaging of cellular/molecular events in the living orga…
In this paper, the mechanical properties, especially the shape memory properties, of shape memory fibres (SMFs) prepared by the melt spinning method and the wet spinning method were studied. It was observed that the melt-spun SMFs had higher tenacity, breaking elongation and shape memory effect compared with those of…