Materials Literature
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Exotic superconducting properties of Sr$_{2}$RuO$_{4}$ have provided strong support for an unconventional pairing symmetry. However, the extensive efforts over the past decade have not yet unambiguously resolved the controversy about the pairing symmetry in this material. While recent phase-sensitive experiments using…
Tissue engineering scaffolds capable of sustained plasmid release can promote gene transfer locally and stimulate new tissue formation. We have investigated the scaffold design parameters that influence the extent and duration of transgene expression and have characterized the distribution of transfected cells. Porous…
Reaction of NaN(3) with the [Cu(II)(tn)](2+) ion (tn = 1,3-diaminopropane) in basic aqueous solution yields the azido-bridged complex of formula [Cu(2)(tn)(2)(N(3))(4)] (1), which is characterized by X-ray crystallography. The structure of 1 is made up of dinuclear neutral complexes, of formula [Cu(2)(tn)(2)(N(3))(4)]…
Slow crack propagation in ductile, and in certain brittle materials, appears to take place via the nucleation of voids ahead of the crack tip due to plastic yields, followed by the coalescence of these voids. Postmortem analysis of the resulting fracture surfaces of ductile and brittle materials on the microm-mm and t…
This is a review article of our work on hysteresis, avalanches, and criticality. We provide an extensive introduction to scaling and renormalization--group ideas, and discuss analytical and numerical results for size distributions, correlation functions, magnetization, avalanche durations and average avalanche shapes,…
The thermal conductivity of individual multiwalled carbon nanotubes (outer diameter of ∼45nm) was obtained by employing the 3-ω method. To this end, the third-harmonic amplitude as a response to the applied alternate current at fundamental frequency (ω) is expressed in terms of thermal conductivity. A microfabricated…
Fully sulfonated poly(styrenesulfonate) brushes were grown from the surface of colloidal silica particles and used to prepare stable trichloroethylene-in-water and heptane-in-water Pickering emulsions. These particles were highly charged and colloidally stable in water but could not be dispersed in trichloroethylene o…
Partial discharges (PD) generate wideband radio frequency interference and, consequently, can be detected using radio receiving equipment. Due to the advances in ultra-high-speed sampling equipment, it is possible to accurately measure the propagation of the PD wavefront as it passes through a 4 element antenna array.…
We show that suitably designed magnetic semiconductor heterostructures consisting of Mn delta (delta)-doped GaAs and p-type AlGaAs layers, in which the locally high concentration of magnetic moments of Mn atoms are controllably overlapped with the two-dimensional hole gas wave function, realized remarkably high ferrom…
We present first-principles density-functional calculations for the electronic properties of nitrogen(N)-doped as well as carbon(C)-doped titanium dioxide (TiO2). We find that the bands originating from N (C) 2p states appear in the band gap of TiO2, but the mixing of N (C) with O2p states is too weak to produce a sig…
Abstract Valence tautomeric complexes combine redox‐active ligands and transition metal ions with two or more accessible oxidation states, exhibiting two nearly degenerated electronic states with localized electronic structures. Charge distribution in such electronic isomers has an appreciable sensitivity to the envir…
Abstract In recent years, research on cylindrical polymer brushes (or molecular bottlebrushes) has received significant attention. In this article, we discuss various strategies for their synthesis and the unique properties arising from their regular multibranched structure. Some recent advances in the application of…
The optical properties of coupled metallic nanorods are studied to investigate the use of coupled plasmonic structures in field-enhanced spectroscopies. Light scattering by coupled nanorods is calculated with the boundary element method, including retardation. The modes of coupled nanorod systems are calculated by the…
Surface-enhanced Raman scattering (SERS) intensities for individual Au nanospheres, nanoshells, and nanosphere and nanoshell dimers coated with nonresonant molecules are measured, where the precise nanoscale geometry of each monomer and dimer is identified through in situ atomic force microscopy. The observed intensit…
Abstract In this work, the effect of ultrasonic irradiation on molecular structure development of metallocene‐catalyzed linear low density polyethylene (mLLDPE) was studied. GPC results show that ultrasonic irradiation have influence on molecular weight and molecular weight distribution of mLLDPE. Molecular weight of…
The effect of water molecules on the conductivity and electrochemical properties of vanadiumpentoxide xerogel was studied in connection with changes of morphology upon thermal annealing atdifferent temperatures. It was demonstrated that the conductivity was increased for the samples heated at150 o C and 270 o C compar…
Abstract Steady‐state electron paramagnetic resonance (EPR) spectroscopy using nitroxide spin probes has been used to investigate the plasticization of poly(vinyl acetate) and poly(ethyl methacrylate) by carbon dioxide. By varying the CO 2 pressure at constant ambient temperature, the glass transition for each polymer…
Local barrier height (LBH) and constant current mode (CCM) images of nonreconstructed (110) single-crystalline titanium dioxide surfaces are determined under ultrahigh vacuum conditions. The barrier height measurements are performed with the tip-oscillation technique in the constant current mode (CCM) of a beetle-type…
Standard applications of density functional theory do not adequately describe the exfoliation energy of graphite. In fact, the local density approximation (LDA) and generalized gradient approximation (GGA) are in qualitative disagreement: the LDA binds at the experimental lattice constant, whereas the GGA does not. Ho…
Concentrated acid solutions have been reported to produce bright light emission during cavitation. Single-bubble sonoluminescence (SBSL) from sulfuric acid (H2SO4) is much brighter than SBSL from water by over three orders of magnitude when both are regassed with Ar. In contrast to water, SBSL spectra of concentrated…