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Influence of reaction conditions on the formation of nanotubes/nanoparticles of polyaniline in the presence of 1‐amino‐2‐naphthol‐4‐sulfonic acid and applications as electrostatic charge dissipation material

Hema Bhandari、Vineet Bansal、Veena Choudhary 等 4 位作者2009-03-02Polymer International

Abstract BACKGROUND: Poly(1‐amino‐2‐naphthol‐4‐sulfonic acid) and its copolymers with aniline are a new class of conducting polymers which can acquire intrinsic protonic doping ability, leading to the formation of highly soluble self‐doped homopolymers and copolymers. Free OH and NH 2 groups in the polymer chain can…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Laser-embossing nanoparticles into a polymeric film

André G. Skirtach、Dirk G. Kurth、Helmuth Möhwald2009-03-02Applied Physics Letters

Embossing or embedding of nanoparticles into a polymeric film is realized by an electromagnetic field. Upon laser light illumination nanoparticles absorb energy, convert it to heat, and sink into a locally softened polymer film as probed by atomic force microscope. The polymeric matrix forms a characteristic rim and s…

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Stamping of Titanium Sheets

J. Adamus2009-03-02Key engineering materials

In this paper, some technological problems (e.g. low drawability, high susceptibility to galling, spring-back) occurring in the sheet-titanium forming process are discussed. A numerical simulation of the stamping process was carried out with the Adina System v.8.3 based on the finite element method. The effects of fri…

Metal Forming Simulation TechniquesMetallurgy and Material FormingTitanium Alloys Microstructure and Properties

Room-Temperature Ferromagnetic Ga1−xMnxAs (x ≤ 0.05) Nanowires: Dependence of Electronic Structures and Magnetic Properties on Mn Content

Han Sung Kim、Yong Jae Cho、Kang Jun Kong 等 12 位作者2009-03-02Chemistry of Materials

Ga 1− x Mn x As nanowires were synthesized with finely controlled Mn contents ( x = 0, 0.01, 0.02, 0.03, and 0.05) by the vapor transport method. They consisted of single-crystalline GaAs nanocrystals (avg. diameter = 60 nm) grown along the [111] direction. The Mn doping decreases the lattice constant, most significan…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Biaxial ZnO−ZnS Nanoribbon Heterostructures

Michael W. Murphy、P. S. Grace Kim、Xingtai Zhou 等 7 位作者2009-03-02The Journal of Physical Chemistry C

Biaxial ZnO−ZnS heterostructure nanoribbons (NRs) have been synthesized using the vapor−liquid−solid technique by the thermal evaporation of ZnS powder in the presence of a Au nanoparticles catalyst, a limited supply of oxygen and an inert carrier gas under controlled temperature and pressure. High resolution transmis…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications

Synthesis of Folic Acid Functionalized PLLA‐b‐PPEGMA Nanoparticles for Cancer Cell Targeting

Feixiong Hu、K. G. Neoh、E. T. Kang2009-03-02Macromolecular Rapid Communications

Poly(L-lactic acid)-block-poly(poly(ethylene glycol) monomethacrylate) (PLLA-b-PPEGMA) has been prepared by the ring-opening polymerization of lactide with a double-headed initiator, 2-hydroxyethyl 2'-methyl-2'-bromopropionate (HMBP), followed by atom transfer radical polymerization (ATRP) of poly(ethylene glycol) mon…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Cure reaction of multi‐walled carbon nanotubes/diglycidyl ether of bisphenol A/2‐ethyl‐4‐methylimidazole (MWCNTs/DGEBA/EMI‐2,4) nanocomposites: effect of carboxylic functionalization of MWCNTs

Tianle Zhou、Xin Wang、Tianchi Wang2009-03-02Polymer International

Abstract BACKGROUND: The aim of this work was to study, using differential scanning calorimetry, the effect of carboxylic functionalization of multi‐walled carbon nanotubes (MWCNTs) on the cure reaction of MWCNTs/diglycidyl ether of bisphenol A/2‐ethyl‐4‐methylimidazole (MWCNTs/DGEBA/EMI‐2,4) nanocomposites. This is i…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Selective Nanopatterning Using Citrate-Stabilized Au Nanoparticles and Cystein-Modified Amphiphilic Protein

Päivi Laaksonen、Jani Kivioja、Arja Paananen 等 7 位作者2009-03-02Langmuir

We present an approach where biomolecular self-assembly is used in combination with lithography to produce patterns of metallic nanoparticles on a silicon substrate. This is achieved through a two-step method, resulting in attachment of nanoparticles on desired sites on the sample surfaces, which allowed a detailed ch…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Electronic Structure Modulations of Radially Deformed Single Wall Carbon Nanotubes under Transverse External Electric Fields

Yaroslav V. Shtogun、Lilia M. Woods2009-03-02The Journal of Physical Chemistry C

The electronic structure of radially deformed single walled carbon nanotubes under transverse external electric fields is studied by self-consistent density functional theory methods. The energy band structure modifications are analyzed, revealing that the admixture of the different states and increased σ−π hybridizat…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

A model for carbon nanotube interconnects

Y. Xu、Ashok Srivastava2009-03-02International Journal of Circuit Theory and Applications

Abstract In this paper, a semi‐classical one‐dimensional (1D) electron fluid model is built that is based on a classical two‐dimensional electron fluid theory taking into account electron–electron repulsive forces, which are significant in 1D system. We have used 1D fluid model to characterize the carbon nanotube (CNT…

Carbon Nanotubes in CompositesGraphene research and applicationsLow-power high-performance VLSI design

SNH Approach in the Synthesis of Nitronyl Nitroxides

Олег Н. Чупахин、Irina A. Utepova、Михаил В. Вараксин 等 7 位作者2009-03-02The Journal of Organic Chemistry

We show that the S(N)(H) approach opens up new possibilities in the synthesis of hetaryl-substituted nitronyl nitroxides. The reaction of 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl lithium salt with pyridine-, pyrimidine-, pyrazine-, isoquinoline-, phthalazine-, quinoxaline-, and 1,2,4-triazine-N-oxid…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Hydrophobic Effects in the Critical Destabilization and Release Dynamics of Degradable Multilayer Films

Reneé C. Smith、Amy Leung、Byeong‐Su Kim 等 4 位作者2009-03-02Chemistry of Materials

Recent research has highlighted the ability of hydrolytically degradable electrostatic layer-by-layer films to act as versatile drug delivery systems capable of multi-agent release. A key element of these films is the potential to gain precise control of release by evoking a surface-erosion mechanism. Here we sought t…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Low Viscosity Poly(trimethylene carbonate) for Localized Drug Delivery: Rheological Properties and in vivo Degradation

Laurianne Timbart、M. Yat Tse、Stephen C. Pang 等 5 位作者2009-03-02Macromolecular Bioscience

The purpose of this study is to examine the potential of low-molecular-weight poly(trimethylene carbonate) for localized delivery for acid-sensitive drugs. Poly(trimethylene carbonate) of various molecular weights is prepared by ring-opening polymerization initiated by octan-1-ol and co-initiated/catalyzed by tin 2-et…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Control of Nucleation Rate for Tetragonal Hen-Egg White Lysozyme Crystals by Application of an Electric Field with Variable Frequencies

Hiroshi Koizumi、Kozo Fujiwara、Satoshi Uda2009-03-02Crystal Growth & Design

Control of the nucleation rate is important for the growth of high quality protein crystals; therefore, the development of improved growth methods is required. Crystal growth with an external electric field is an attractive method for control of the nucleation rate. However, mainly a decrease in nucleation rate was ob…

Enzyme Structure and FunctionCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Triangular Single-Crystalline Nanorings of PbS Formed at the Air/Water Interface

Guoqing Xin、Hui-Ping Ding、Yangang Yang 等 8 位作者2009-03-02Crystal Growth & Design

Triangular single-crystalline nanorings of PbS were prepared at the air/water interface and characterized by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), scanning electron microscopy (SEM), atomic force microscopy (AFM), and UV−vis spectroscopy. The nanorings were transformed from triangular Pb…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesSpectroscopy and Quantum Chemical Studies

Hierarchical PbTiO3 Nanostructures Grown on SrTiO3 Substrates

Per Martin Rørvik、Tor Grande、Mari‐Ann Einarsrud2009-03-02Crystal Growth & Design

A synthesis route, based on a hydrothermal treatment of an amorphous PbTiO 3 precursor at 180 °C, has been developed to grow hierarchical PbTiO 3 nanostructures on single-crystal SrTiO 3 substrates. Initially, highly oriented PbTiO 3 platelets grew parallel to the ⟨100⟩ substrate orientations. PbTiO 3 nanorods with sq…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Schottky barrier formation at metal electrodes and semiconducting carbon nanotubes

Yu He、Jinyu Zhang、Shimin Hou 等 5 位作者2009-03-02Applied Physics Letters

Schottky barrier (SB) formation at the contact interface between metal and semiconducting carbon nanotubes (CNTs) is of great importance in determining the transport characteristics of a CNT field effect transistor. In this paper, we studied the SB height (SBH) between different metals and CNT contacts using first-pri…

Carbon Nanotubes in CompositesGraphene research and applicationsSemiconductor materials and interfaces

Forced-Induced Desorption of a Polymer Chain Adsorbed on an Attractive Surface: Theory and Computer Experiment

S. Bhattacharya、V. G. Rostiashvili、A. Milchev 等 4 位作者2009-03-02Macromolecules

We consider the properties of a self-avoiding polymer chain adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a grand canonical ensemble (GCE) approach. We derive theoretical expressions for…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesAdvanced Physical and Chemical Molecular Interactions

A Single Molecular System Gating Electron Transfer by Ring Inversion of a Methylpyridylpyrimidine Ligand on Copper

K. Nomoto、Shoko Kume、Hiroshi Nishihara2009-03-02Journal of the American Chemical Society

We have succeeded in constructing an electron-transfer gating system involving a copper complex, 1.BF(4), that is regulated by the rotational motion of a pyridylpyrimidine ligand. 4-Methyl-2-(2'-pyridyl)pyrimidine confined between two bulky groups underwent a dynamic process derived from pyrimidine-ring coordination i…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

Effect of Filler Treatment on Crystallization, Morphology and Mechanical Properties of Polypropylene/Calcium Carbonate Composites

Ming‐Rui Meng、Qiang Dou2009-03-02Journal of Macromolecular Science Part B

Ming-Rui Mengab & Qiang Doua a Department of Polymer Science, College of Materials Science and Engineering , Nanjing University of Technology , Nanjing, China b Plastic Plant, Sinopec Yangzi Petrochemical Company Ltd , Nanjing, China Pimelic acid (PA) was used as a new surface modifier for CaCO3. The effects of PA tre…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties