Materials Literature
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A heteropolyoxotungstate, [Cu(en)2]2H8[Gd(PW11O39)2] · (H2en)0.5 · 3H2O (1), has been hydrothermally synthesized and characterized by IR, XPS, TGA and single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P 1, with a = 12.651(2) Å3, b = 20.559(3) Å3, c = 21.729(3) Å3, α = 71.37…
Zinc oxide single-crystal films are prepared by the oxidation of zinc-implanted sapphire at 700 °C for 2 h in oxygen ambient. The cross-section transmission electron microscopy image and the selected-area electron diffraction (SAED) pattern show that ZnO single-crystal films are formed on the surface of the zinc-impla…
ZnO thin films with three different types of surface structures, smooth, large nanowall-networks, and small nanowall-networks, were grown by a vapor phase transport process. The XRD patterns of these samples showed a high c-axis orientation. Photoluminescence spectra of these samples showed that the intensities of ult…
More than 5 million tonnes of metal salts of fatty acids are manufactured and used worldwide every year, to create a range of soft condensed-matter products such as bar soaps, stick deodorants, personal care creams, toothpastes, and lubricant greases. These molecules, popularly known as soaps, are capable of forming a…
In this work, the interactions between beta-peptides are investigated for helix-forming peptides using molecular simulation. The role of electrostatic interactions in the self-assembly of these peptides is studied by calculating the dipole moment of various 14-helical beta-peptides using molecular dynamics simulations…
A fully printed Veselago-Pendry lens (isotropic n=-1, epsilon(r)=-1, mu(r)=-1) is presented which is based on transmission-line metamaterials. The lens is constructed in a parallel-plate environment at 1.569 GHz and without any embedded sources and achieves a resolution better than the diffraction limit (full width ha…
Zirconium oxide doped with scandium oxide is one of the most promising materials for electrolytes of solid oxide fuel cells because of its high ionic conductivity. In this study, temperature dependence of mechanical property, especially strength, of 9 mol% scandia doped zirconia polycrystalline samples with 0 to 30 wt…
In this paper a micromechanics-based design is proposed for the development of a material with enhanced ductility and flexural strength combined with low production cost. The composite performance is described by 11 micromechanical properties of the system consisting of cement matrix, fibres and fibre-matrix interface…
Semiconducting carbon nanotubes (CNTs) are attractive as channel material for field-effect transistors due to their high carrier mobility. In this paper we show that a local CNT gate can provide a significant improvement in the subthreshold slope of a CNT transistor compared to back gate switching and provide gate del…
The fabrication and structure characterization of ordered nanowire-nanotube hybrid arrays embedded in porous anodic aluminum oxide (AAO) membranes are reported. Arrays of TiO(2) nanotubes were first deposited into the pores of AAO membranes by a sol-gel technique. Co nanowires were then electrochemically deposited int…
In this work we present the investigation of the influence of electronic and structural variations induced by varying the N,N'-bridge on the magnetic properties of Cu(II)- bis(oxamato) complexes. For this study the complexes [Cu(opba)] (2-) ( 1, opba = o-phenylene- bis(oxamato)), [Cu(nabo)] (2-) ( 2, nabo = 2,3-naphth…
Nanodiamonds synthesized by detonation have been found not to immobilize the ring form of pUC19 plasmid DNA. Linear pUC19 molecules with blunt ends, prepared by restriction of the initial ring form of pUC19 DNA, and linear 0.25-10 kb DNA fragments are adsorbed on nanodiamonds. The amount of adsorbed linear DNA molecul…
We investigated the pressure dependence of the Raman frequencies and intensities of the D and G bands of double-wall carbon nanotubes under strong uniaxial conditions. Using moissanite anvils, we observed for the first time the evolution of the D band under extreme stress/pressure conditions. We find that the differen…
A simple technique to transfer aligned multi-walled carbon nanotubes (MWCNTs) is demonstrated in this work. With polydimethylsiloxane (PDMS) as the transfer medium, as-grown or patterned MWCNT arrays are directly transferred onto a wide variety of Pt-coated substrates such as glossy paper, cloth, polymers, glass slide…
Crystal structures of new trinuclear complexes [Ni 3(mu-OAc F) 4(mu-AA) 2(tmen) 2], [Ni 3(mu-OAc F) 4(mu-BA) 2(tmen) 2], and [Co 3(mu-OAc F) 4(mu-BA) 2(tmen) 2] have been determined (OAc F = CF 3COO (-), AA = acetohydroxamate anion, BA = benzohydroxamate anion, tmen = N, N, N', N'-tetramethylethylenediamine). In each…
The diffraction theory of Kirchhoff is reinterpreted and a new form of a surface diffraction integral is developed by using the axioms of the modified theory of physical optics, which leads to the exact scattered fields by conducting bodies. The new integral is arranged according to the interpretation of Young, and th…
Ultrafine cobalt ferrite nanoparticles were prepared by forced hydrolysis in diethyleneglycol and, after centrifugation, dispersed in the same solvent to form a sol in which a layered hydroxyacetate nickel salt was precipitated. The as-obtained composite was moderately calcined in air to form nanoparticles constituted…
Grubbs olefin metathesis catalyst was immobilized as a ruthenium-supported ionic liquid catalyst (Ru-SILC) in pores of amorphous alumina with the aid of ionic liquid [hmim]PF6. This Ru-SILC was effective for various olefin metathesis reactions such as intra- or intermolecular macrocyclization and dimerization, and use…
Large-area, over several square centimeters, mesoporous array of magnetic nanostructure with perpendicular anisotropy is prepared by depositing Co/Pt multilayers (MLs) on a mesopore array of anodized alumina (AAO) fabricated on Si wafers. The MLs are mainly deposited on the top of AAO walls and perimeters of the pores…
Control of the morphology of gold nanoparticles has received considerable attention because the physical and chemical properties of gold depend significantly on its size and shape. A novel route for obtaining 2-D gold nanostructures has been developed in which chloroaurate ions (AuCl (4)(-)) are reduced at the 2-D int…