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Effect of lateral substitution on supramolecular liquid crystal associates induced by hydrogen-bonding interactions between 4-(4′-pyridylazo-3-methylphenyl)-4′′-alkoxy benzoates and 4-substituted benzoic acids

Magdi M. Naoum、Abdelgawad A. Fahmi、Sayed Z. Mohammady 等 4 位作者2010-04-22Liquid Crystals

Five laterally methyl-substituted pyridine-based derivatives of the title compounds (I 8–I 16), with molecular formula 4-CnH2n+1O-C6H4COOC6H3(3-CH3)-N=N-C5H4N were prepared and their molecular formulae elucidated via elemental analyses, infrared, nuclear magnetic resonance and mass spectra. The number of carbon atoms…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Ceramics Science and Technology

作者信息未提供2010-04-22OpenAlex

Although ceramics have been known to mankind literally for millennia, research has never ceased. Apart from the classic uses as a bulk material in pottery, construction, and decoration, the latter half of the twentieth century saw an explosive growth of application fields, such as electrical and thermal insulators, we…

Advanced ceramic materials synthesis

An All‐Vanadium(III) Hexametalate Lindqvist Structure and Its Chromium and Iron Analogues

L.J. Batchelor、Rachel Shaw、S. Markey 等 5 位作者2010-04-22Chemistry - A European Journal

Lindqvist structures: We report the isolation of the all-vanadium(III) analogue (see figure) of the fully reduced (all-vanadium(IV)) hexavanadate structure from formal substitution of the {VIIICl}2+ and {VIVO}2+ fragments. The chemistry can be extended to the analogous CrIII and FeIII cluster anions. Magnetic data for…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Poly(2-thiophen-3-yl-malonic acid), a Polythiophene with Two Carboxylic Acids Per Repeating Unit

Oscar Bertrán、Elaine Armelín、Francesc Estrany 等 6 位作者2010-04-22The Journal of Physical Chemistry B

A new substituted polythiophene derivative bearing malonic acid, poly(2-thiophen-3-yl-malonic acid), has been prepared and characterized using a strategy that combines both experimental and theoretical methodologies. The chemical structure of this material has been investigated using FTIR and (1)H NMR, and its molecul…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsSynthesis and properties of polymers

Controlling the Morphology of BaCO3Aggregates by Carboxymethyl Cellulose through Polymer Induced Needle-Stacking Self-Assembly

Wei Li、Shengtong Sun、Qisi Yu 等 4 位作者2010-04-22Crystal Growth & Design

Inspired by mineralization in biological organisms, fabrication of higher ordered inorganic crystals induced by polymer chains has received much attention. In our present work, we made use of a widely used industrial material, carboxymethyl cellulose (CMC), to mediate the nucleation and growth of barium carbonate (BaC…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionCephalopods and Marine Biology

Evidence of Dynamic Pentagon−Heptagon Pairs in Single-Wall Carbon Nanotubes using Surface-Enhanced Raman Scattering

Toshihiko Fujimori、Koki Urita、Tomonori Ohba 等 5 位作者2010-04-22Journal of the American Chemical Society

Surface-enhanced Raman scattering (SERS) was applied to detecting pentagon-heptagon pairs, the so-called Stone-Wales defect, in single-wall carbon nanotubes (SWCNTs). When a probing laser light was scanned over a SWCNT-dispersed silver surface, two distinct SERS spectra were obtained: (1) temporally stable spectra sim…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsIon-surface interactions and analysis

Electrosynthesis of well-organized nanoporous poly(3,4-ethylenedioxythiophene) by nanosphere lithography

Luís Santos、Pascal Martin、Jalal Ghilane 等 7 位作者2010-04-22Electrochemistry Communications

The electrodeposition of poly(3,4-ethylenedioxythiophene) (PEDOT) films from aqueous surfactant solution through a two-dimensional poly(styrene) (PS) template onto indium tin oxide (ITO) substrate has been investigated. The polymer grows in the interstitial spaces of the self-assembled PS spheres which were subsequent…

Conducting polymers and applicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Achieving A‐Site Termination on La0.18Sr0.82Al0.59Ta0.41O3 Substrates

Joseph H. Ngai、Todd C. Schwendemann、Anna E. Walker 等 7 位作者2010-04-22Advanced Materials

Interfaces between transition metal oxide compounds provide a setting where correlated behavior can emerge. Essential to interface studies are substrates that have a single atomic plane termination. By tuning the vapor pressure of La above the surface of La0.18Sr0.82Al0.59Ta0.41O3 (LSAT) during annealing, single-unit-…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Valence-Band Structure of the Ferromagnetic Semiconductor GaMnAs Studied by Spin-Dependent Resonant Tunneling Spectroscopy

Shinobu Ohya、Iriya Muneta、Pham Nam Hai 等 4 位作者2010-04-22Physical Review Letters

The valence-band structure and the Fermi level (E(F)) position of ferromagnetic-semiconductor GaMnAs are quantitatively investigated by electrically detecting the resonant tunneling levels of a GaMnAs quantum well (QW) in double-barrier heterostructures. The resonant level from the heavy-hole first state is clearly ob…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

NEXAFS Depth Profiling of Surface Segregation in Block Copolymer Thin Films

Sitaraman Krishnan、Marvin Y. Paik、Christopher K. Ober 等 8 位作者2010-04-22Macromolecules

NEXAFS spectroscopy was used to probe the surface composition and under-water surface reconstruction of thin films of comb-like diblock copolymers with cylindrical and spherical microphases. The polymers consisted of a polystyrene block, and a second block prepared from a styrenic monomer grafted with fluoroalkyl-tagg…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Effect of Degree of Branching on the Thermoresponsive Phase Transition Behaviors of Hyperbranched Multiarm Copolymers: Comparison of Systems with LCST Transition Based on Coil-to-Globule Transition or Hydrophilic−Hydrophobic Balance

Haixing Cheng、Shaoai Xie、Yongfeng Zhou 等 7 位作者2010-04-22The Journal of Physical Chemistry B

This work reports for the first time the influence of degree of branching (DB) on the thermoresponsive phase transition behaviors of hyperbranched multiarm copolymers. Two series of PEHO-star-PEOs (series A) and PEHO-star-PDMAEMAs (series B) with the hydrophobic DB-variable PEHO core and different kinds of linear arms…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Self-Ordered Anodic Alumina with Continuously Tunable Pore Intervals from 410 to 530 nm

Sun Chuanmin、Jia Luo、Longmin Wu 等 4 位作者2010-04-22ACS Applied Materials & Interfaces

We report a "mild anodization" (MA) process using aluminum oxalate (Alox) as an additive to suppress breakdown of porous anodic alumina (PAA) in the electrolyte of phosphoric acid at high potentials and comparatively high temperatures. It is shown for the first time that continuously tunable pore intervals (D(int)) fr…

Semiconductor materials and devicesConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Carrier Distribution and Dynamics of Nanocrystal Solids Doped with Artificial Atoms

Dong‐Kyun Ko、Jeffrey J. Urban、Christopher B. Murray2010-04-22Nano Letters

Single component and multicomponent nanocrystal (NC) solids represent an exciting new form of condensed matter, as they can potentially capture not only the quantum features of the individual building blocks but also novel collective properties through coupling of NC components. Unlike bulk semiconductors, however, th…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Combination Radiofrequency Ablation and Intravenous Radiolabeled Liposomal Doxorubicin: Imaging and Quantification of Increased Drug Delivery to Tumors

Hayden Head、Gerald D. Dodd、Ande Bao 等 10 位作者2010-04-22Radiology

PURPOSE: To identify, with noninvasive imaging, the zone of radiopharmaceutical uptake after combination therapy with radiofrequency (RF) ablation and intravenous administration of technetium 99m ((99m)Tc) liposomal doxorubicin in a small-animal tumor model, and to quantify and correlate the uptake by using imaging an…

Nanoparticle-Based Drug DeliveryHepatocellular Carcinoma Treatment and PrognosisNanoplatforms for cancer theranostics

Morphology and viscoelasticity of PP/TiO2 nanocomposites prepared by in situ sol–gel method

Walid Bahloul、Véronique Bounor‐Legaré、Laurent David 等 4 位作者2010-04-22Journal of Polymer Science Part B Polymer Physics

Abstract PP/TiO 2 nanocomposites were prepared from an original method based on the hydrolysis‐condensation (sol–gel method) reactions of titanium alkoxide inorganic precursor premixed with polypropylene (PP) under molten conditions. Nanocomposites with a mean diameter of primary particles lower than 5 nm were then pr…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Coomassie Brilliant Dyes as Surface-Enhanced Raman Scattering Probes for Protein−Ligand Recognitions

Xiao X. Han、Lei Chen、Jie Guo 等 5 位作者2010-04-22Analytical Chemistry

Coomassie brilliant dyes have high affinity to proteins and high Raman activity, and on the basis of which, we have employed brilliant blue R-250 (BBR) and brilliant blue G-250 (BBG) as surface-enhanced Raman scattering (SERS) labels to probe protein-ligand recognitions. This method differs from previously proposed me…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

1D Cu(OH)2 Nanomaterial Synthesis Templated in Water Microdroplets

Gilles R. Bourret、R. Bruce Lennox2010-04-22Journal of the American Chemical Society

For many applications, micro- and nanostructured materials show a strong correlation between their geometry and their function. We report here the interfacial precipitation of a copper/alkylamine complex to form Cu(OH)(2) nanofibers in a two-phase system (H(2)O/CH(2)Cl(2)). Their aggregation results in porous microbea…

ZnO doping and propertiesCopper-based nanomaterials and applicationsPickering emulsions and particle stabilization

Simulated glass transition in free‐standing thin polystyrene films

A. R. C. Baljon、S. Williams、Н. К. Балабаев 等 6 位作者2010-04-22Journal of Polymer Science Part B Polymer Physics

Abstract In this article, we investigate the glass transition in polystyrene melts and free‐standing ultra‐thin films by means of large‐scale computer simulations. The transition temperatures are obtained from static (density) and dynamic (diffusion and orientational relaxation) measurements. As it turns out, the glas…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Effect of Crystallographic Texture on Magnetic Characteristics of Cobalt Nanowires

K. Maaz、Shafqat Karim、Muhammad Usman 等 7 位作者2010-04-22Nanoscale Research Letters

Cobalt nanowires with controlled diameters have been synthesized using electrochemical deposition in etched ion-track polycarbonate membranes. Structural characterization of these nanowires with diameter 70, 90, 120 nm and length 30 μm was performed by scanning electron microscopy, high-resolution transmission electro…

Nanopore and Nanochannel Transport StudiesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Evidence of Fermi level control in a half-metallic Heusler compoundCo2MnSiby Al-doping: Comparison of measurements with first-principles calculations

Yuya Sakuraba、Kōki Takanashi、Yohei Kota 等 7 位作者2010-04-22Physical Review B

The Fermi level $({E}_{\text{F}})$ control of half-metallic Heusler alloy ${\text{Co}}_{2}\text{MnSi}$ by Al-doping was challenged in magnetic tunnel junctions with a ${\text{Co}}_{2}{\text{MnAl}}_{x}{\text{Si}}_{1\ensuremath{-}x}$ (CMAS) electrode. The observed bias voltage dependence on tunneling conductance ($G\tex…

Semiconductor materials and interfacesMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties