Materials Literature
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The supramolecular structures of dendrimer-bile salt complexes have been investigated by multidimensional and multinuclear NMR techniques, such as (1)H NMR, COSY, TOCSY, NOESY, and DOSY. 2D-NOESY analysis indicated the localization of bile salt in the interior pockets of dendrimers. The orientation of the guest in the…
We show that recent developments in the application of metadynamics methods to direct simulations of crystallization make it possible to predict the orientation of crystals grown on self-assembled monolayers. In contrast to previous studies, the method allows for dynamic treatment of the organic component and the incl…
The conductivity behavior of MWCNT networks within the volume of polymer nanocomposite samples is analyzed with nanometer resolution in all three dimensions. It is demonstrated that close to but above the percolation threshold for electrical conduction most of the MWCNTs do not contribute to the conductive network wit…
α,ω-Dihydroxy-telechelic poly(trimethylenecarbonate), HO-PTMC-OH, is synthesized from the controlled "immortal" ring-opening polymerization (ROP) of trimethylene carbonate under mild conditions (bulk, 60 °C), using ZnEt(2) or, more efficiently, [(BDI)Zn(N(SiMe(3) )(2) )] (BDI = CH(CMeNC(6) H(3) -2,6-iPr(2) )(2) ) as c…
Hydrogen can be easily produced from the catalytic hydrolysis of sodium borohydride (NaBH 4 ), with sodium metaborate (NaBO 2 ) being the co-product. If NaBO 2 can be economically recycled in the process, NaBH 4 could be considered as a promising hydrogen carrier in fuel cells because of its high hydrogen content. In…
Past and recent x-ray and absorption data on chromonic liquid crystals are analyzed in a consistent manner to reveal both the cross-sectional areas and stacking free energy changes for a number of systems. Two tentative conclusions result from this study. First, the locations of the charged groups on the dye molecule…
A series of 2-(imidazole-2-yl)phenol ligands L1-L6 with the general composition 4-R(4)-5-R(3)-6-R(2)-2-(4,5-R(1),R(1)-1H-imidazole-2-yl)phenol (L1: R(1) = C(2)H(5), R(2) = R(3) = R(4) = H; L2: R(1) = C(6)H(5), R(2) = R(3) = R(4) = H; L3: R(1) = C(6)H(5), R(3) = OCH(3), R(2) = R(4) = H; L4: R(1) = C(6)H(5), R(4) = OCH(…
Although β-Ga 2 O 3 thin films and nanowires (NWs) show promise as very stable and reliable active components for high temperature gas sensors, their use at room temperatures is limited due to poor electrical conductivity. To address this problem, we grew Sn-doped β-Ga 2 O 3 nanowires by the vapor−liquid−solid (VLS) a…
This paper reports on the synthesis of birefringent vaterite microspheres with narrow size distribution using a seeded growth method. In a post-treatment the microspheres were stabilized and functionalized through coating with a combination of organosilica and silica. The coating vastly enhanced the stability of the v…
Liquid crystals are a successful example of how the control of self-assembly via chemical design leads to novel applications. Direct patterning of a continuous metal-free mesogenic phthalocyanine film (discotick liquid crystals) is shown by the spatial control of columns orientation by unconventional lithography. Thes…
Phase contrast and epifluorescence microscopy were utilized to monitor morphological changes in human astrocytoma cells during a time-course exposure to single-walled carbon nanotube (SWCNT) conjugates with different surfactants and to investigate sub-cellular distribution of the nanotube conjugates, respectively. Exp…
Whereas the Daltonian atom-to-atom ratios in ordinary molecules are well understood via the traditional theory of valence, the naturally occurring stoichiometries in intermetallic compounds ${A}_{p}{B}_{q}$, as revealed by phase-diagram compilations, are often surprising. Even equal-valence elements $A$ and $B$ give r…
Adipose-derived stem cells (ASCs) may provide a clinical option for rebuilding damaged superficial lamina propria of the vocal fold. We investigated the effects of five hydrogels (hyaluronic acid [HA], collagen, fibrin, and cogels of fibrin-collagen and fibrin-HA) on the differentiation of ASCs, with the long-term goa…
The electronic structure and oxidation state of atomic Au adsorbed on a perfect CeO(2)(111) surface have been investigated in detail by means of periodic density functional theory-based calculations, using the LDA+U and GGA+U potentials for a broad range of U values, complemented with calculations employing the HSE06…
At the core of amyloid fibrils is the cross-beta spine, a long tape of beta-sheets formed by the constituent proteins. Recent high-resolution x-ray studies show that the unit of this filamentous structure is a beta-sheet bilayer with side chains within the bilayer forming a tightly interdigitating "steric zipper" inte…
Pure BiFeO3 (BFO), Nd-doped BFO (BNF) and Nd and Mo co-doped BFO (BNFM) multiferroic thin films were prepared by pulsed laser deposition on Pt/Ti/SiO2/Si substrates. Among these films, the BNFM film exhibited the lowest dielectric loss and leakage current density, a well-saturated P–E loop, excellent charge-retaining…
We investigated the influence of processing conditions, nanocrystal/substrate interactions and solvent evaporation rate on the ordering of strongly interacting nanocrystals by synergistically combining electron microscopy and synchrotron-based small-angle X-ray scattering analysis. Spin-cast PbSe nanocrystal films exh…
We report on the fabrication of electrochemical double layer capacitor (EDLC) electrodes with aligned carbon nanotubes (CNTs) grown directly on conductive substrates using an air assisted chemical vapor deposition technique. The fabricated EDLCs showed very small equivalent series resistances (approximately few hundre…
Our aim was to develop a biodegradable fibrous dressing to act as a tissue guide for in situ wound repair while releasing Ibuprofen to reduce inflammation in wounds and reduce pain for patients on dressing changes. Dissolving the acid form of Ibuprofen (from 1% to 10% by weight) in the same solvent as 75% polylactide,…
The research is aimed to investigate the mechanical behaviors of epoxy-based nanocomposites reinforced with spherical nanoparticles. Five different contents of silica nanoparticles — 5, 10, 15, 20, and 40 wt% — were introduced in the samples. Through a sol—gel technique, the silica particles with a diameter of 25 nm w…