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TOPICAL REVIEW: Metallo-supramolecular modules as a paradigm for materials science

Dirk G Kurth2008-01-01Science and Technology of Advanced Materials

Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical,…

Superconductivity in transparent zinc-doped In2O3 films having low carrier density

Kazumasa Makise, Nobuhito Kokubo, Satoshi Takada, Takashi Yamaguti, Syunsuke Ogura, Kazumasa Yamada, Bunjyu Shinozaki, Koki Yano, Kazuyoshi Inoue and Hiroaki Nakamura2008-01-01Science and Technology of Advanced Materials

Thin polycrystalline zinc-doped indium oxide (In2O3–ZnO) films were prepared by post-annealing amorphous films with various weight concentrations x of ZnO in the range 0≤x ≤0.06. We have studied the dependences of the resistivity ρ and Hall coefficient on temperature T and magnetic field H in the range 0.5≤T ≤300 K, H…

Enhanced bioactivity of ZnO nanoparticles—an antimicrobial study

Nagarajan Padmavathy and Rajagopalan Vijayaraghavan2008-01-01Science and Technology of Advanced Materials

In this study, we investigate the antibacterial activity of ZnO nanoparticles with various particle sizes. ZnO was prepared by the base hydrolysis of zinc acetate in a 2-propanol medium and also by a precipitation method using Zn(NO3)2 and NaOH. The products were characterized by x-ray diffraction (XRD) analysis, tran…

BiFeO3-doped (Na0.5K0.5)NbO3 lead-free piezoelectric ceramics

Xueyi Sun et al2008-01-01Science and Technology of Advanced Materials

Lead-free piezoelectric ceramics (1−x)(Na0.5K0.5)NbO3-xBiFeO3 (x=0~0.07) were synthesized by the solid-state reaction. Differential scanning calorimetry (DSC) measurements revealed that an increase in the amount of BiFeO3 dopant resulted in a decrease in the orthorhombic-tetragonal and tetragonal-cubic phase transitio…

Review - Synthesis and superconducting properties of CaC6

Nicolas Emery, Claire Herold, Jean-François Mareche and Philippe Lagrange2008-01-01Science and Technology of Advanced Materials

Among the superconducting graphite intercalation compounds, CaC6 exhibits the highest critical temperature Tc=11.5 K. Bulk samples of CaC6 are obtained by immersing highly oriented pyrographite pieces in a well-chosen liquid Li–Ca alloy for 10 days at 350 °C. The crystal structure of CaC6 belongs to the { m R}ar{3}{ m…

Anisotropic elasticity of magnetically ordered agarose gel

Isao Yamamoto et al2008-01-01Science and Technology of Advanced Materials

The physical properties of agarose gel prepared under strong magnetic fields were investigated. The storage modulus was measured by the reflection method with an ultrasonic pulse. The measurement results of the gel's elasticity indicate that agarose gel has anisotropic properties. The elasticity and its anisotropy dep…

TOPICAL REVIEW: Optics of high-performance electron microscopes

H H Rose2008-01-01Science and Technology of Advanced Materials

During recent years, the theory of charged particle optics together with advances in fabrication tolerances and experimental techniques has lead to very significant advances in high-performance electron microscopes. Here, we will describe which theoretical tools, inventions and designs have driven this development. We…

Formation of Al3Ti/Mg composite by powder metallurgy of Mg–Al–Ti system

Zi R Yang et al2008-01-01Science and Technology of Advanced Materials

An in situ titanium trialuminide (Al3Ti)-particle-reinforced magnesium matrix composite has been successfully fabricated by the powder metallurgy of a Mg–Al–Ti system. The reaction processes and formation mechanism for synthesizing the composite were studied by differential scanning calorimetry (DSC), x-ray diffractom…

Soft x-ray photoelectron spectroscopy study of type-I clathrates

Jun Tang, Zhaofei Li, Jing Ju, Ryotaro Kumashiro, Marcos A. Avila, Kouichirou Suekuni, Toshiro Takabatake, FangZhun Guo, Keisuke Kobayashi, Koji Akai and Katsumi Tanigaki2008-01-01Science and Technology of Advanced Materials

Extensive soft x-ray photoelectron spectroscopy studies are performed on Ba8 Ga16 Ge30 (BGG) and Sr8Ga16Ge30 (SGG) single crystals ranging from Fermi to core levels, at a high-energy facility. Valence band x-ray photoelectron spectroscopy (XPS) experiments with theoretical calculations revealed that the valence band i…

TOPICAL REVIEW: Spin current, spin accumulation and spin Hall effect

Saburo Takahashi and Sadamichi Maekawa2008-01-01Science and Technology of Advanced Materials

Nonlocal spin transport in nanostructured devices with ferromagnetic injector (F1) and detector (F2) electrodes connected to a normal conductor (N) is studied. We reveal how the spin transport depends on interface resistance, electrode resistance, spin polarization and spin diffusion length, and obtain the conditions…

TOPICAL REVIEW Progress in cold roll bonding of metals

Long Li, Kotobu Nagai and Fuxing Yin2008-01-01Science and Technology of Advanced Materials

Layered composite materials have become an increasingly interesting topic in industrial development. Cold roll bonding (CRB), as a solid phase method of bonding same or different metals by rolling at room temperature, has been widely used in manufacturing large layered composite sheets and foils. In this paper, we pro…

Electrodeposition of nanostructured coatings and their characterization-a review

Injeti Gurrappa and Leo Binder2008-01-01Science and Technology of Advanced Materials

Nanostructured materials have gained importance in recent years due to their significantly enhanced properties. In particular, electrochemistry has a special role in producing a variety of nanostructured materials. In the current review, we discuss the superiority of electrochemical deposition techniques in synthesizi…

Impurity band Mott insulators: a new route to high Tc superconductivity

Ganapathy Baskaran2008-01-01Science and Technology of Advanced Materials

Last century witnessed the birth of semiconductor electronics and nanotechnology. The physics behind these revolutionary developments is certain quantum mechanical behaviour of 'impurity state electrons' in crystalline 'band insulators', such as Si, Ge, GaAs and GaN, arising from intentionally added (doped) impurities…

Inhibition of Alzheimer amyloid β aggregation by polyvalent trehalose

Yoshiko Miura et al2008-01-01Science and Technology of Advanced Materials

A glycopolymer carrying trehalose was found to suppress the formation of amyloid fibrils from the amyloid β peptide (1–42) (Aβ), as evaluated by thioflavin T assay and atomic force microscopy. Glycopolymers carrying sugar alcohols also changed the aggregation properties of Aβ, and the inhibitory effect depended on the…

Superhydrophobic cotton fabrics prepared by sol–gel coating of TiO2 and surface hydrophobization

Chao-Hua Xue et al2008-01-01Science and Technology of Advanced Materials

By coating fibers with titania sol to generate a dual-size surface roughness, followed by hydrophobization with stearic acid, 1H,1H,2H,2H-perfluorodecyltrichlorosilane or their combination, hydrophilic cotton fabrics were made superhydrophobic. The surface wettability and topology of cotton fabrics were studied by con…

Spin drift and spin diffusion currents in semiconductors

M Idrish Miah2008-01-01Science and Technology of Advanced Materials

On the basis of a spin drift-diffusion model, we show how the spin current is composed and find that spin drift and spin diffusion contribute additively to the spin current, where the spin diffusion current decreases with electric field while the spin drift current increases, demonstrating that the extension of the sp…

Control of nonmagnetic particles using a magnetic field

Kazuhiko Iwai, Akbar Eskandarpour, Manabu Usui and Kento Sugiura2008-01-01Science and Technology of Advanced Materials

A force and/or torque are induced in a material under the imposition of a magnetic field. Their magnitudes are different from those acting on the surrounding materials because of the difference in their physical properties. Therefore, a magnetic field is a powerful tool for controlling a second phase in a mother phase…

Microwave magnetoresistance in Ge:Mn nanowires and nanofilms

Roman Morgunov et al2008-01-01Science and Technology of Advanced Materials

The Lorentzian and spin-scattering components of magnetoresistance were found and distinguished in Ge:Mn thin films. The suppression of microwave magnetoresistance by the limitation of the dimensionality of Ge nanowires doped with Mn has been revealed. Spin-wave resonance in the long-ordered magnetic state and ferroma…

11B nuclear magnetic resonance in boron-doped diamond

Miwa Murakami, Tadashi Shimizu, Masataka Tansho and Yoshihiko Takano2008-01-01Science and Technology of Advanced Materials

This review summarizes recent results obtained by 11B solid-state nuclear magnetic resonance (NMR) on boron-doped diamond, grown by the high-pressure high-temperature (HPHT) or chemical vapor deposition techniques. Simple single-pulse experiments as well as advanced two-dimensional NMR experiments were applied to the…