Materials Literature
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Enantiopure undecagold clusters protected by chiral atropisomeric diphosphine ligands (P^P) have been synthesized by the stoichiometric reduction of the corresponding (P^P)(AuCl)(2) complexes with NaBH(4). The molecular mono-disperse [Au(11)(P^P)(4)Cl(2)]Cl species have been thoroughly characterized using an array of…
A sensitive, selective, reversible, and easy performance way of detecting electron donating volatile amines such as abused drug methamphetamine (MAPA) has been developed.
Low-temperature proton conduction in nanocrystalline ceramics of Gd-doped ceria with an average grain size of ca. 15 nm was investigated as a function of dopant concentration over the temperature range of 30 ≤ θ/°C ≤ 200. The proton conductivity, σH+, was independent of the dopant concentration while the oxygen-ion co…
By using Ce(SO4)2·4H2O as an oxidant and sodium bis(2-ethylhexyl) sulfosuccinate (AOT) as a surfactant, unique poly(3,4-ethylenedioxythiophene) (PEDOT) nanorods with a couple of cuspate tips were successfully prepared by reverse interfacial polymerization. The morphology of these PEDOT nanorods was very regular and we…
Janus colloids have inspired growing interests due to their diverse potential applications. Herein, we present a facile approach to fabricate Janus submicron sized colloids by the selective etching of anisotropic colloids. Size ratio, microstructure and composition are tunable. The method can be scaled up, which is th…
Various nanoparticles are used to fabricate innovative systems for drug encapsulation and cancer therapy. In this paper, the hierarchical core-shell nanostructures composed of gold nanoparticles and poly(dimethylsiloxane)-poly(ethylene glycol) (PDMS-PEG) block copolymers are fabricated via a hydrosilylation reaction.…
Cage-type mesoporous Pt with tunable large mesopores possessing smooth and rough pore surfaces were prepared selectively by the deposition of Pt in the absence and presence of a block copolymer in a hard-template, respectively.
The last decade has witnessed many advances in the coordination chemistry of tetrathiafulvalene (TTF). Various ligands, in which a metal-binding functionality is attached to the TTF unit, have been synthesized and used for the preparation of metal complexes. This Perspective summarizes the main types of TTF-containing…
„Wasserstoff in der Fahrzeugtechnik“ bietet einen allgemeinen Überblick über die verschiedenen Aspekte von Eigenschaften, Erzeugung, Speicherung und Anwendung von Wasserstoff. Schwerpunkte liegen auf
Fourier Transform Near Infrared Raman Spectroscopy has been used to monitor the molecular changes of collagen in a tendon subjected to strain. In the Raman spectrum of the unstrained tendon, some protein bands, mainly assigned to collagen, can be observed: amide I (1666 cm-1) and III (1266 and 1248 cm-1) vibrational m…
We demonstrate ultrafast transistor-based photodetectors made from single- and few-layer graphene. The photoresponse does not degrade for optical intensity modulations up to 40 GHz, and further analysis suggests that the intrinsic bandwidth may exceed 500 GHz.
The prevention of external corrosion on underground structures is accomplished using a dual system of coatings and CP. To define corrosion, pipelines will be considered synonymous with all underground structures. All metallic corrosion is electrochemical in nature and is the result of direct electrical current flow.
Highly and homogeneously crosslinked poly(beta-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-acti…
Porous organic materials can be synthesized via free-radical polymerization of crosslinkable olefinic monomers within the interstices of porous templates. The synthesis process has been employed to generate ordered mesoporous structures through use of a mesoporous silica template, KIT-6. The mesoporous silica features…
One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and…
published
The emission spectra of the tripositive lanthanide ion Eu(3+) have often been employed to probe its environment in the solid state, and the intensity ratio of magnetic dipole ((5)D(0)-->(7)F(1)) and forced electric dipole ((5)D(0)-->(7)F(2)) transitions has been used to estimate the "degree of asymmetry" of a crystal…
A specific ion-pair approach can be involved in precise control of the size of gold nanodots. The dendrimers with terminal amine and hydroxyl groups were a hydrophilic and hydrophobic microcavity-template, respectively, for trapping gold salts. The facile strategy can significantly enhance the quantum yield of gold na…
This study was intended to characterize the mechanical properties of nanoclay filled epoxy adhesive single lap joints under both static (tensile) and dynamic (impact) loadings. The nanoclay contents were 1, 3 and 5 wt% of epoxy resin (Araldite LY5052). The nanoclay particles were dispersed in the epoxy resin by a stir…
Scattering of electromagnetic radiation by a charged homogeneous spherical particle/body is treated. Theoretical solution represents a generalization of the Mie's scattering theory for electrically neutral sphere. It is shown that classical and quantum physics approaches may lead to difierent conclusions, as documente…