Materials Literature
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A new type of hierarchically porous ZSM-5-type zeolite, Hp-ZSM, with well defined macro-/meso-/microporous structures was facilely synthesized via a simple steam-assisted conversion route in the presence of ethanol. This novel material exhibits a tri-modal porous structure: a macroporous network with macropore sizes o…
In this paper zinc stannate (ZnSnO3) nanoparticles was synthesized by a chemical precipitation method. The synthesized samples were characterized using X-ray powder diffraction (XRD), Differential scanning calorimetry (DSC) and UV-Visible absorption spectroscopy. Sensing material was made as pellet by hydraulic press…
Among different ways to reduce the coke consumption in the blast furnace, not so much attention was paid for decreasing the coke losses through finding suitable application of small size coke called “nut coke”. In meantime modern blast furnaces use nut coke with different amount (10–140 kg/t hot metal) and different g…
The syntheses, characterization and crystal structures of ten complexes of composition [{NiIILLiI(H2O)2}{NiIIL}2](ClO4) (1), [NiIILNaI(ClO4)(CH3OH)] (2), [(NiIIL)2NaI](BPh4)·CH3COCH3 (3), [(NiIIL)2RbI](BPh4)·CH3COCH3 (4), [(NiIIL)2CsI](ClO4)·CH3CN (5), [{NiIILMgII(H2O)3}{NiIIL}2](ClO4)2 (6), [NiIILCaII(NO3)2(H2O)]·1.5…
We report a simple route to form robust, inorganic, semi-permeable compartments composed of montmorillonite, a natural plate-like clay mineral that occurs widely in the environment. Mechanical forces due to shear in a narrow gap assemble clay nanoplates from an aqueous suspension onto air bubbles. Translucent vesicles…
This paper reviews the recent development of the photocatalytic emission control reaction and photooxidation with molecular oxygen, specifically focusing on efforts based on revealing the reaction mechanism by the authors' group. TiO2 acts as an effective catalyst for the photo-assisted selective catalytic reduction o…
The enhancement of the capillarity fabrication of well-ordered two-dimensional (2D) and three-dimensional (3D) opal photonic crystal is described herein. The quality enhancement and the reduction of the fabrication time are improved by using core@soft adhesive shell (Silica@PolyButylAcrylate) particles dispersed in an…
Mn(II) complexes of scorpiand-type azamacrocycles constituted by a tretrazapyridinophane core appended with an ethylamino tail including 2- or 4-quinoline functionalities show very appealing in vitro SOD activity. The observed behaviour is related to structural and electrochemical parameters.
The load dependence of densification during a Vickers indentation test was investigated for three commercial glass compositions, soda-lime silicate glass, aluminoborosilicate glass, and lead borosilicate glass, each of which exhibits markedly different susceptibility to crack initiation. The contribution of densificat…
Here we present DFT calculations based on a periodic mixed gaussians/plane waves approach to study the energetics, structure, bonding of SAMs of simple thiols on Au(111). Several open issues such as structure, bonding and the nature of adsorbate are taken into account. We started with methyl thiols (MeSH) on Au(111) t…
By using a reconstruction program recently developed by the present authors, the parent austenite grain structure is reconstructed from the crystal orientation map of bainite structure. Local austenite orientation can be reconstructed from non-ausformed bainite structure with errors of 1.7° and 1.0° at spatial resolut…
Ca-doped cerium phosphate (CeCaPO(4)) has been newly developed and successfully used as catalyst support with superior ion-exchanged property and oxygen activation ability. Ru(3+) exchanged CeCaPO(4) is identified as an efficient catalyst for aerobic oxidation of alcohols with the highest TOF (∼408 h(-1)) reported so…
Abstract Diamond microinclusions provide the unique opportunity to study the composition of the mineral-forming medium. The paper presents the first data on the composition of cloudy microinclusions in the cores of octahedral diamonds from the Internatsional’naya pipe. These zones are of cuboid shape and have a fibrou…
Mesoporous structure and carbon coating are two important techniques for improving electrode performance for Li ion batteries. The combining of these two techniques in one system offers a new strategy for producing new high-performance electrode materials. Here, we demonstrate a two-step method for preparing carbon co…
Intermolecular connections play a crucial role in biology (recognition, signalling, binding), in physics (material cohesion) and in chemistry ((supra)molecular engineering). While a phenomenological thermodynamic free-energy approach for modelling self-assemblies is now at hand, a more satisfying description based on…
Sn-doped TiO 2 nanoparticles were prepared by the vapor transport method of water molecules and characterized by XRD and XPS analyses. The TEM images indicated that as-prepared samples were highly dispersed nanoparticles with a small and uniform size below 20 nm, as it would effectively control the rate of hydrolysis…
A highly selective ratiometric fluorescent Ag+ chemosensor RAAP which featured Ag+-induced enhancement of fluorescence emission and blue-shift of the UV-vis spectrum (64 nm) was developed. Both of the changes are due to the Ag+-induced conformational changes from a pyrene monomer to a pyrene excimer and the formation…
We investigated the influence of tetrahydrofuran (THF) addition on the structure of poly(1,2-butadiene-b-ethylene oxide) [PB-PEO] micelles in aqueous solution. Our studies showed that while the micelles remained starlike, the micelle core-corona interfacial tension and micelle size decreased upon THF addition. The det…
In this study, we have used cation-passivated codoping of Nb with Ga/In and also of W with Zn/Cd to modulate the band structure of anatase-TiO(2) to extend absorption to longer visible-light wavelengths. We adopted generalized Kohn-Sham theory with the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional for exchange and…
The high strength of 5% chromium steels at elevated temperature is directly related to their complex microstructure generated by specific heat treatments that consist of thoroughly controlled austenitizing, quenching and tempering. Fracture toughness and fatigue crack propagation are studied for various heat treatment…