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Lead germanium oxide

Yan Xu、Liying Cheng、Guangpeng Zhou 等 4 位作者2006-05-17Acta Crystallographica Section E Structure Reports Online

The crystal structure of the title compound, PbGeO3, shows a three-dimensional framework assembled by Pb6 and Ge6 structural building units. The Pb atom is coordinated by five O atoms in square-pyramidal coordination, while the Ge atom is tetra­hedrally coordinated by four O atoms.

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Dendron-like Growth of Silver Nanoparticles Using a Water-Soluble Oligopeptide

Santanu Bhattacharya、Apurba K. Das、Arindam Banerjee 等 4 位作者2006-05-17The Journal of Physical Chemistry B

A dendron-like nanostructure of silver was grown in solution using a water-soluble tetrapeptide Tyr-Aib-Tyr-Val (Aib, alpha-amino isobutyric acid), silver nitrate, and methanol. These structures are composed of silver nanoparticles having a bimodal size distribution with the median diameters around 2.0 and 19.5 nm, re…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

Motif-based Hessian matrix forab initiogeometry optimization of nanostructures

Zhengji Zhao、Lin‐Wang Wang、Juan Meza2006-05-17Physical Review B

A simple method to estimate the atomic degree Hessian matrix of a nanosystem is presented. The estimated Hessian matrix, based on the motif decomposition of the nanosystem, can be used to accelerate ab initio atomic relaxations with speedups of 2--4 depending on the size of the system. In addition, the programing impl…

Nanoparticle-Based Drug DeliveryGraphene research and applicationsX-ray Diffraction in Crystallography

Preparation and characterisation of tantalum carbide as an optional crucible material for bulk aluminium nitride crystal growth via physical vapour transport

C. Hartmann、J. Wollweber、M. Albrecht 等 4 位作者2006-05-17Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract This paper reports experimental measured and calculated phase distributions of carburised Ta sheets. Electron back scatter diffraction (EBSD) maps of carburised Ta samples have shown the progress of carburisation in respect of the annealing procedure. The initial stage is characterised by grain boundary and s…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsSemiconductor materials and devices

Polymer-dispersed liquid-crystal voltage sensor

Elizabeth Scherschener、César D. Perciante、Enrique A. Dalchiele 等 6 位作者2006-05-17Applied Optics

We present a novel electric-field and voltage sensor based on the electro-optical properties of polymer-dispersed liquid-crystals (PDLCs). In principle, the transmittance of PDLCs is a nonlinear function of the applied electrical field. To measure an AC field we superposed to it a known DC field. This allowed us to ac…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsMagneto-Optical Properties and Applications

Lateral and normal forces between patterned substrates induced by nematic fluctuations

Fahimeh Karimi Pour Haddadan、S. Dietrich2006-05-17Physical Review E

We consider a nematic liquid crystal confined by two parallel flat substrates whose anchoring conditions vary periodically in one lateral direction. Within the Gaussian approximation, we study the effective forces between the patterned substrates induced by the thermal fluctuations of the nematic director. The shear f…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsAdhesion, Friction, and Surface Interactions

Structure and Catalytic Mechanism of a Novel N-Succinyl-l-ornithine Transcarbamylase in Arginine Biosynthesis of Bacteroides fragilis

Dashuang Shi、Hiroki Morizono、Juan Cabrera‐Luque 等 8 位作者2006-05-17Journal of Biological Chemistry

A Bacteroides fragilis gene (argF'(bf)), the disruption of which renders the bacterium auxotrophic for arginine, was expressed and its recombinant protein purified and studied. The novel protein catalyzes the carbamylation of N-succinyl-L-ornithine but not L-ornithine or N-acetyl-L-ornithine, forming N-succinyl-L-citr…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Xanthene-Based Ligand with Two Adjacent β-Diiminato Binding Sites

Maurice Frederic Pilz、Christian Limberg、B. Ziemer2006-05-17The Journal of Organic Chemistry

A novel potential ligand has been designed where two beta-dialdimine units are linked by a xanthene backbone (H2Xanthdim). The synthesis proceeds via a double vinamidinium salt and the products of its hydrolysis (containing eneamine/malonaldehyde units), which were converted into H2Xanthdim via a reaction with 2,3-dim…

Enzyme Catalysis and ImmobilizationPorphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry Methods

Biodegradable Amphiphilic Triblock Copolymer Bearing Pendant Glucose Residues: Preparation and Specific Interaction with Concanavalin A Molecules

Changhai Lü、Xuesi Chen、Zhigang Xie 等 7 位作者2006-05-17Biomacromolecules

A novel biodegradable amphiphilic block copolymer PLGG-PEG-PLGG bearing pendant glucose residues is successfully prepared by the coupling reaction of 3-(2-aminoethylthio)propyl-alpha-D-glucopyranoside with the pendant carboxyl groups of PLGG-PEG-PLGG in the presence of N,N'-carbonyldiimidazole. The polymer PLGG-PEG-PL…

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Conformational and visometric behavior of quaternized polysulfone in dilute solution

Silvia Ioan、Anca Filimon、Ecaterina Avram2006-05-17Polymer Engineering and Science

Abstract Some properties of polysulfone, chlorometylated polysulfone and quaternized polysulfone were studied by viscometry, interferometry and dialysis equilibrium. Modification of intrinsic viscosity, preferential and total adsorbtion coefficients explained the changes of the hydrodynamic dimensions with solvent qua…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

Liquid Crystal and Crystal Structure of Octahomotetraoxacalix[4]arenes

Shigeo Kohmoto、Yasunobu Someya、Hyuma Masu 等 5 位作者2006-05-17The Journal of Organic Chemistry

Octahomotetraoxacalix[4]arenes bearing long alkyl chains on their lower rim were prepared. Ester 4a existed in a 1,2-alternate conformation in its crystal structure, which was examined by single-crystal X-ray diffraction analysis. To prepare liquid crystalline materials possessing calixarene moieties by self-assemblin…

Liquid Crystal Research AdvancementsSupramolecular Chemistry and ComplexesMolecular spectroscopy and chirality

Reaction of Silanes in Supercritical CO2 with TiO2 and Al2O3

Wei Gu、Carl P. Tripp2006-05-17Langmuir

Infrared spectroscopy was used to investigate the reaction of silanes with TiO2 and Al2O3 using supercritical CO2 (Sc-CO2) as a solvent. It was found that contact of Sc-CO2 with TiO2 leads to partial removal of the water layer and to the formation of carbonate, bicarbonate, and carboxylate species on the surface. Alth…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Simple approach to estimating the van der Waals interaction between carbon nanotubes

Chenghua Sun、Gao Qing Lu、Hui–Ming Cheng2006-05-17Physical Review B

The van der Waals (vdW) interactions between carbon nanotubes (CNTs) were studied based on the continuum Lennard-Jones model. It was found that all the vdW potentials between two arbitrary CNTs fall on the same curve when plotted in terms of certain reduced parameters, the well depth, and the equilibrium vdW gap. Base…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Experimental Studies on Active Shape Control of Composite Structures using SMA Actuators

Seung‐Man Yang、Jin-Ho Roh、Jae‐Hung Han 等 4 位作者2006-05-17Journal of Intelligent Material Systems and Structures

In this article, the experimental modeling and active shape control of hybrid composite structures actuated by shape memory alloy (SMA) wires are presented and discussed. The thermomechanical properties of the SMA wires are experimentally measured. SMA actuators with residual strains are prepared by loading-unloading…

Shape Memory Alloy TransformationsAeroelasticity and Vibration ControlStructural Engineering and Vibration Analysis

Early stages of precipitation and microstructure control in Mg–rare earth alloys

C. Antion、P. Donnadieu、C. Tassin 等 4 位作者2006-05-17The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Hardening precipitation frequently occurs in Mg–rare earth (RE) alloys after heat treatment in the 150–200°C range. Early stages of precipitation have been studied in detail by transmission electron microscopy in two Mg–RE alloys (Mg–Y–Gd and Mg–Y–Nd). Two types of structures may be involved in the precipitation seque…

Magnesium Alloys: Properties and ApplicationsTitanium Alloys Microstructure and PropertiesMXene and MAX Phase Materials

Light-induced rotation of dye-doped liquid crystal droplets

Carlo Manzo、Domenico Paparo、Lorenzo Marrucci 等 4 位作者2006-05-17Physical Review E

We investigate both theoretically and experimentally the rotational dynamics of micrometric droplets of dye-doped and pure liquid crystal induced by circularly and elliptically polarized laser light. The droplets are dispersed in water and trapped in the focus of the laser beam. Since the optical torque acting on the…

Liquid Crystal Research AdvancementsOrbital Angular Momentum in OpticsNonlinear Dynamics and Pattern Formation

Time-Resolved Infrared Spectroscopy as an In Situ Tool To Study the Kinetics During Self-Assembly of Mesostructured Films

Plinio Innocenzi、Tongjit Kidchob、Johnny Mio Bertolo 等 6 位作者2006-05-17The Journal of Physical Chemistry B

Rapid scan time-resolved infrared spectroscopy has been used to investigate in situ the kinetics of the chemical processes involved in the formation of self-assembled mesostructured films. The experiments have been done in transmission mode on films cast on a diamond disk using an infrared microscope. Two specific mat…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisAerogels and thermal insulation

Handbook of Optoelectronics (Two-Volume Set)

J.P. Dakin、Robert G. W. Brown2006-05-17OpenAlex

A field as diverse as optoelectronics needs a reference that is equally versatile. From basic physics and light sources to devices and state-of-the-art applications, the Handbook of Optoelectronics provides comprehensive, self-contained coverage of fundamental concepts and practical applications across the entire spec…

Semiconductor Lasers and Optical DevicesOptical and Acousto-Optic TechnologiesAdvanced Materials and Semiconductor Technologies

New clay‐reinforced nanocomposites based on a polycarbonate/polycaprolactone blend

I. González、J. I. Eguiazábal、J. Nazábal2006-05-17Polymer Engineering and Science

Abstract New clay‐reinforced polymer nanocomposites based on poly(carbonate of bisphenol A) (PC)/poly(caprolactone) (PCL) blends have been obtained by mixing PC with minor amounts of PCL in which a widely dispersed organically modified montmorillonite (OMMT) was present. Upon the addition of PCL/OMMT, the T g of the m…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Observation of Brewster’s effect for transverse-electric electromagnetic waves in metamaterials: Experiment and theory

Yasuhiro Tamayama、Toshihiro Nakanishi、Kazuhiko Sugiyama 等 4 位作者2006-05-17Physical Review B

We have experimentally realized Brewster's effect for transverse-electric waves with metamaterials. In dielectric media, Brewster's no-reflection effect arises only for transverse-magnetic waves. However, it has been theoretically predicted that Brewster's effect arises for TE waves under the condition that the relati…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies