Materials Literature
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The thermal conductivity along the out-of-plane direction in polyimide (PI) blend films containing ZnO nano-pyramidal particles (ZnO-NPs) was investigated. PI blend films composed of a sulfur- and a fluorine-containing PI were prepared viaspin-coating and thermal curing of precursor solutions containing ZnO-NPs. Micro…
BACKGROUND: Nanomaterials such as SiO2 nanoparticles (SiO2NP) are finding increasing applications in the biomedical and biotechnological fields such as disease diagnostics, imaging, drug delivery, food, cosmetics and biosensors development. Thus, a mechanistic and systematic evaluation of the potential biological and…
The application of new methods and techniques to fields such as biology and medicine is becoming more and more demanding since the request of detailed information down to single molecules is a scientific necessity and a technical realistic possibility. In this effort a key role is played by emerging fabrication techni…
We report a systematic study of the surface modification of gold and silver nanoparticles with DL-penicillamine (PEN) and N-acetyl-DL-penicillamine (NAP), motivated by the possibility of inducing pH-controlled reversible nanoparticle assembly. The interaction of PEN and NAP with the metal nanoparticle surface was stud…
In this work, BiPO4:Eu of three different polymorphs was prepared using a room-temperature reaction followed by a heat treatment. The formation mechanism, morphologies, structures, and luminescence properties of these three polymorphs were investigated in detail. It is found that a hexagonal phase (HP) was formed at r…
Homoleptic tetrakis[2,3,9,10,16,17,23,24-octa(butyloxy)phthalocyaninato] dysprosium-cadmium quadruple-decker complex 1 was isolated in relatively good yield of 43% from a simple one-pot reaction. This compound represents the first sandwich-type tetrakis(phthalocyaninato) rare earth-cadmium quadruple-decker SMM that ha…
We construct a conformally invariant random family of closed curves in the plane by welding of random homeomorphisms of the unit circle. The homeomorphism is constructed using the exponential of βX, where X is the restriction of the 2-dimensional free field on the circle and the parameter β is in the “high temperature…
Electrochemical impedance spectroscopy (EIS) in the l00 kHz-10 mHz frequency range was employed as the main electrochemical technique to study the corrosion protection behaviour of zinc rich epoxy paint in 3% NaCl solution. The EIS results obtained at the open-circuit corrosion potential have been interpreted using a…
Ruddlesden-Popper phases of the general stoichiometry Lnn+1NinO3n+1 are potential solid oxide fuel cell cathodes displaying attractive electronic and ionic conductivities. To ensure long term performance, understanding of the materials degradation mechanisms occurring during operation is vital. One of the key processe…
Cyano-bridged single-chain magnets of the type L4FeReCl4(CN)2, where L = diethylformamide (DEF) (1), dibutylformamide (DBF) (2), dimethylformamide (DMF) (3), dimethylbutyramide (DMB) (4), dimethylpropionamide (DMP) (5), and diethylacetamide (DEA) (6), have been synthesized to enable a systematic study of the influence…
Colloidal Er(3+)/Yb(3+), Tm(3+)/Yb(3+) and Ho(3+)/Yb(3+) doped CaF(2) nanoparticles have been prepared by a one-pot hydrothermal procedure and their upconversion properties have been investigated.
In recent years, interfacial properties have been tailored with nanostructured polymer assemblies to generate materials with specific properties and functions for application in diverse fields, including biomaterials, drug delivery, catalysis, sensing, optics and corrosion. This perspective begins with a brief introdu…
Solid catalysts containing supported nanoparticles of metals such as Au and Pt are very efficient in the oxidation of alcohols obtained from biorenewable sources under mild conditions. However, these reactions sometimes appear to be inhibited by the products formed during oxidation. In this work, the inhibition of gly…
Hydrated vanadium pentoxide (V2O5·0.44H2O, HVO) nanobelts were synthesized by a simply high-yield (e.g. up to ∼99%) hydrothermal approach. The length of these nanobelts was up to several hundred micrometers while the diameter was only ∼20 nm and the thickness was ∼10 nm. Binder-free bulky papers were prepared by using…
Cation exchange, recently explored for synthesizing core/shell quantum dots (QDs), causes continuous core size change during shell formation. By carefully varying parent PbS QD size and cation exchange conditions, we have synthesized PbS/CdS core/shell QDs with a similar PbS core size of ∼4.5 nm yet a different CdS sh…
Substantial efforts have been devoted to design, synthesize, and integrate various semiconductor nanostructures for photovoltaic (PV) solar cells. In this article, we will review the recent progress in this exciting area and cover the material chemistry and physics related to all-inorganic nanostructure solar cells, h…
We demonstrate a novel architecture of solar cell by incorporating graphene thin film in a quantum dot sensitized solar cell. Quantum dot sensitized nanorods with a graphene layer exhibited a 54.7% improvement comparing a quantum dot sensitized ZnO nanorods without graphene layer. A fill factor as high as ∼62% was als…
A low temperature electroactive shape-memory material, PU–SWCNT hybrid, was prepared by blending the low molecular weight soft segment polyurethane (PU) with the high conductivity single-walled carbon nanotubes (SWCNTs). The melting points of PU–SWCNT hybrids were changed clearly with the amount of SWCNTs, which were…
New non-conjugated random copolymers containing pendent electron-donating 9-(4-vinylphenyl)carbazole (VPK) and electron-accepting 2-phenyl-5-(4-vinylphenyl)-1,3,4-oxadiazole (OXD) or 2-(4-vinylbiphenyl)-5-(4-phenyl)-1,3,4-oxadiazole (BOXD) were successfully synthesized by nitroxide-mediated free radical polymerization…
SrTiO3 nanocubes were synthesized in aqueous solution with Bis (ammonium lactate) titanium dihydroxide (TALH) as the Ti source under hydrazine-assisted hydrothermal condition. The SrTiO3 nanocubes grew from the Ti-based sol through a dissolution-precipitation process and large cubic particles formed through the orient…