Materials Literature
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We report on a novel, efficient, and one-step approach to prepare single-layer reduced graphene oxide (RGO) suspensions and films using hydroxylamine hydrochloride. The effective chemical reduction of GO was evidenced by a significant increase in the C/O ratio and five orders of magnitude decrease in the GO resistance…
New phases of Zn–Co-layered double hydroxides (Zn–Co-LDHs) were synthesized for the first time via a co-precipitation reaction using hydrogen peroxide as an oxidant. According to powder X-ray diffraction and field emission-scanning electron microscopy, both nitrate- and sulfate-forms of the Zn–Co-LDHs crystallized wit…
The equilibrium dynamics of a spherical particle immersed in a complex Maxwell fluid is analyzed in terms of velocity autocorrelation function (VACF), mean-square displacement (MSD), and power spectral density (PSD). We elucidate the role of hydrodynamic memory and its interplay with medium viscoelasticity for a free…
The slippage effect at the interface between a confined fluid and the surface around it has a potential application in microfluidic and nanofluidic devices. To investigate the slippage effect of fluid on superhydrophobic surfaces, a series of rheological experiments are carried out for superhydrophobic surfaces coated…
High-yield three dimensional (3D) graphene networks were prepared on Ni foams by ambient pressure chemical vapour deposition (APCVD). The layer number of graphene can be tuned by changing the gas flow ratio and growth time. The assembled films from the vacuum filtration of the 3D graphene possessed excellent electrica…
This paper presents the design, simulation and measurement of a dual-band terahertz metamaterial absorber with polarization-insensitivity and wide incident angle. The unit cell of the metamaterial consists of top resonator structures and low metallic ground plane, separated by an isolation material spacer to realize b…
A series of amide and ester derivatives of 1,3,6,8-tetraphenylpyrene (TPPy) were prepared, and their solid-state luminescence, molecular packing, and piezochromic responses were studied in order to improve and refine the design concept of piezochromic luminescent materials based on the use of multiple hydrogen bonds a…
Graphene sheets have been functionalized with a PAMAM dendron, finding that graphene can be efficiently functionalized all over the surface, or only at the edges, depending on the reactions used in the functionalization process.
Mg2Si0.5−xSn0.5Sbx(x = 0–0.023) thermoelectric solid solutions have been successfully synthesized by a facile and cost-effective B2O3 flux method in air. X-ray diffraction analysis and scanning electron microscopy observations confirm that the single-phased Mg2Si0.5−xSn0.5Sbx compounds have been obtained. The peak pow…
Core-shell TiO(2)@ZnO nanorods (NRs) have been fabricated by a simple two step method: growth of ZnO NRs' array by an aqueous chemical technique and then coating of the NRs with a solution of titanium isopropoxide [Ti(OC(3)H(7))(4)] followed by a heating step to form the shell. The core-shell nanocomposites are compos…
In this paper we report the first use of Al(III) salalen complexes for the ring opening polymerisation of rac-lactide. Polylactides with narrow polydispersities (PDIs range from 1.04-1.65) and moderate degrees of stereoselectivity were formed. Eight salalen Al(III) complexes have been prepared and fully characterised…
By tuning the polymer-filler interaction, filler size and filler loading, we use a coarse-grained model-based molecular dynamics simulation to study the polymer-filler interfacial structural (the orientations at the bond, segment and chain length scales, chain size and conformation), dynamic and stress-strain properti…
Silica (SiO2) is one of the most frequently used inorganic materials. This review covers the research progress in the synthesis of one-dimensional silica nanotubes as well as the newest aspects of silica nanotubes in applications where their structural attributes are exploited. The synthetic methods for well-defined s…
Compounds of CuxBi2Te3 (0 ≤ x ≤ 0.1) were studied to measure the effect of Cu intercalation on their thermoelectric properties. HR-TEM images of freshly fractured surfaces of Cu0.07Bi2Te3 showed that Cu nanoparticles formed in the van der Waals gaps between Te layers in Bi2Te3. Such nanoparticles acted as electron don…
A one-pot synthesis of non-noble transition metal-based core-shell nanoparticles (NPs) has been developed under ambient conditions. The obtained Cu@M (M = Co, Fe, Ni) NPs exhibit superior catalytic activity for hydrolytic dehydrogenation of NH(3)BH(3), compared to the alloy and monometallic counterparts.
Fullerene-functionalized graphene shows a hierarchical structure, and is promising for many potential applications. In this paper, a new method is presented to synthesize such a novel nanostructure. Graphite flakes were intercalated to graphite oxide, and then functionalized with zero-dimensional fullerene nanocrystal…
Polymer composites is a typical material consisting of a matrix reinforced with fiber/filler and the general nature of construction of the material itself provides innumerable sites for the initiation of a defect or for the growth of delamination. The life expectancy of composite structure requires a clear understandi…
In recent years, skin and soft-tissue infections (SSTIs), particularly due to multidrug-resistant pathogens are increasingly being encountered in clinical settings. Due to the development of antibiotic resistance and the outbreak of infectious diseases caused by resistant pathogenic bacteria, the pharmaceutical compan…
Fully siliceous layer-by-layer assembled thin films, using polyhedral oligomeric silsesquioxanes (POSS) as building blocks, were successfully deposited on various substrates, including cotton fabric. Water-soluble OctaAmmonium POSS ((+)POSS) and OctaTMA POSS ((-)POSS) were used as cationic and anionic components for t…
The reported size distribution of silver nanoparticles (AgNPs) is strongly affected by the underlying measurement method, agglomeration state, and dispersion conditions. A selection of AgNP materials with vendor-reported diameters ranging from 1 nm to 100 nm, various size distributions, and biocompatible capping agent…