Materials Literature
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Abstract A series of plastic materials from recycled polyethylene (PE) and oyster‐shell powder were prepared to test their fire‐retardant properties with an aim of finding a practical way of waste recycling. Oyster‐shell powder was found to be mainly composed of calcium carbonate and it decomposed to calcium oxide and…
Abstract The permeability of carbon dioxide, oxygen, nitrogen, and air through commercial monolayer and multilayer films, based on polyethylene (PE), biaxially oriented polypropylene (BOPP), and polyamide (PA), used for food packaging is reported. The influence of temperature (from 10 to 60°C) on permeability and DSC…
Abstract Many studies have been carried out to make bottle‐to‐bottle recycling feasible. One of the difficulties found is the decrease in the polymer's molar mass, which damages the injection blow molding process. A method usually employed to increase the molar mass of virgin PET consists of solid‐state polymerization…
The interplay between the solid-state spin-crossover features and the structural properties is analyzed for the $[{\mathrm{Mn}}^{III}{(\mathrm{pyrol})}_{3}\mathrm{tren}]$ complex on the basis of high-pressure and low-temperature single-crystal x-ray-diffraction experiments. In particular, the low-temperature ($30\phan…
In this study, the effect of microstructure on the tensile and fracture properties of injection molded biocomposites consisting of starch-based matrix and short sisal fibers has been investigated. Tensile tests are carried out on samples cut in longitudinal (L) and transverse (T) directions with respect to the melt fl…
We present first-principles total-energy calculations of water adsorption on the $\mathrm{Zn}\mathrm{O}(10\overline{1}0)$ surface. We find that on ideal $\mathrm{Zn}\mathrm{O}(10\overline{1}0)$ surfaces, the fully molecular chemisorption is most energetically favorable at coverage $\ensuremath{\leqslant}0.5\phantom{\r…
Let's twist again: Bei der Transkription der molekularen Chiralität gängiger stereogener Zentren in amplifizierte supramolekulare Chiralität durch invertierte Helicität während des Zusammenlagerns Gel-bildender π-konjugierter Moleküle entstehen longitudinal kondensierte M- und P-Helices. Dieser „Feldwebel-und-Soldaten…
The reaction of the bismuth silanolates [Bi(OSiR2R')3] (R = R' = Me, Et, iPr; R = Me, R' = tBu) with water has been studied. Partial hydrolysis gave polynuclear bismuth-oxo clusters whereas amorphous bismuth-oxo(hydroxy) silanolates were obtained when an excess of water was used in the hydrolysis reaction. The metathe…
This paper reports a detailed and systematic lattice dynamical calculation of the newly discovered intermetallic superconductor $\mathrm{Mg}\mathrm{C}{\mathrm{Ni}}_{3}$ by using a lattice dynamical model theory based on pairwise interactions under the framework of the rigid ion model. The results bring out the anomalo…
Cobalt-containing mesoporous TUD-1 with different Si/Co ratios (100, 50, 20, and 10) was synthesized by the direct hydrothermal treatment method (DHT) using triethanolamine (TEA) as a template. The prepared samples (denoted as Co-TUD-1) were characterized by XRD, UV/Vis spectroscopy, elemental analysis, N2 sorption me…
We show detailed magnetic absorption spectroscopy results of an in situ cleaved high-quality single crystal of magnetite. In addition the experimental setup was carefully optimized to reduce drift, self-absorption, and offset phenomena as far as possible. In strong contradiction to recently published data, our observe…
We measured the ultrafast response of triangular silver nanoparticles upon femtosecond excitation of their plasmon resonance. After a fast electron relaxation, the signature of a bimodal mechanical vibration of the particle is apparent as a spectral modulation. We identify the two lowest frequency, totally symmetric v…
Femtosecond visible photoluminescence is detected from gold nanoparticles using time-resolved fluorescence upconversion spectroscopy. We directly compared this fast luminescence from gold nanospheres $(\ensuremath{\emptyset}25\phantom{\rule{0.3em}{0ex}}\mathrm{nm})$ with that obtained from nanorods ($\ensuremath{\empt…
The oxidation of formic acid and carbon monoxide was studied at a gold electrode by a combination of electrochemistry, in situ surface-enhanced Raman spectroscopy (SERS), differential electrochemical mass spectrometry, and first-principles DFT calculations. Comparison of the SERS results and the (field-dependent) DFT…
We present a detailed numerical study of effective interactions between micrometer-sized silica spheres, induced by highly charged zirconia nanoparticles. It is demonstrated that the effective interactions are consistent with a recently discovered mechanism for colloidal stabilization. In accordance with the experimen…
Structural and upconversion emission properties of ZrO2:Yb3+–Ho3+ nanocrystals were analyzed as function of Yb3+ concentration. Structural characterization shows a crystallite size up to 80 nm and tetragonal and cubic phase as the main crystalline structures. Strong green (540 nm) and weak red (670 nm) and near infrar…
Pr 3 + -doped PbO–GeO2 (PGO) glasses containing silver nanoparticles (NPs) were prepared and their spectroscopic characteristics were studied. The PGO samples and the nucleation of silver NP were obtained melting the starting oxide powders, quenching and annealing. Transmission electron microscopy was used to characte…
In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally admitted that low dimensionality promotes high superconducting transition temperatures…
We report a method for fabricating nanogaps directly with electron beam lithography (EBL). The primary resolution-limit of EBL, electron back-scattering, is reduced dramatically by using a thin-film as a substrate. We show that this resolution enhancement allows one to fabricate metal electrodes with separation from a…
We have studied the photoexcited carrier relaxation dynamics in the Kondo insulator SmB6 and the heavy fermion metal YbAgCu4 as a function of temperature and excitation level. The dynamic response is found to be both strongly temperature dependent and nonlinear. The data are analyzed with a Rothwarf-Taylor bottleneck…