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Determination of Luminescent Europium β-Diketonates Used as Tracers for Shadowing Pursuits

Shoji Kurata、Haruo Hirano、M. Nagai2002-07-01Journal of Forensic Sciences

Abstract Markers with red luminescence under ultraviolet light were used as tracers for shadowing pursuits in a variety of criminal cases. The luminescent markers consisted of a mixture of 1% europium _-diketonates in Vaseline as the carrier. The visual detection limit under ultraviolet light was 1–100 ppm. Six types…

Medical Imaging Techniques and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Description and crystal structure of vajdakite, [(Mo 6+ O 2 ) 2 (H 2 O) 2 As 3+ 2 O 5 ]· H 2 O—A new mineral from Jáchymov, Czech Republic

Petr Ondruš、Roman Skála、Ivana Cı́sařová 等 6 位作者2002-07-01American Mineralogist

Vajdakite, a new mineral from Jáchymov, NW Bohemia, Czech Republic, forms minute acicular, gray-green crystals associated with arsenolite, scorodite, parascorodite, kanˇkite, annabergite, köttigite, pyrite, marcasite, nickelskutterudite, and löllingite. Microprobe analysis gave (in wt%): As = 27.72, Mo = 35.39, O = 36…

Crystal Structures and PropertiesRadioactive element chemistry and processing

X-ray microanalysis in the environmental scanning electron microscope (ESEM): Small size particles analysis limits

L. Khouchaf、Jan Verstraete2002-07-01Journal de Physique IV (Proceedings)

Dans cette etude nous presenterons les effets de certains parametres tels que la duree d'acquisition et la pression dans la chambre du microscope electronique a balayage environnemental sur les resultats de la microanalyse X. La pression dans la chambre a ete augmentee de 1 Torr (133 Pa) a 15 Torr (1995 Pa). Des mesur…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

The effect of the position of the methyl group on the helical twisting powers of aldol condensation products of methyl cyclohexanones

Johan Lub、Wolter ten Hoeve、W. P. M. Nijssen 等 5 位作者2002-07-01Liquid Crystals

The four aldol condensation products of methylcyclohexanone isomers and 4-(4-hexyloxybenzoyloxy)benzaldehyde have been prepared. These chiral products were either obtained with high enantiomeric excess or the enantiomers were separated by means of chiral HPLC. In all cases only the E-isomer was obtained. UV irradiatio…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Dependence of exchange bias energy on spin projections at (La,Ca)MnO3 ferromagnetic/antiferromagnetic interfaces

C. Christides、N. Moutis、Ph. Komninou 等 5 位作者2002-07-01Journal of Applied Physics

Strained epitaxial bilayers and multilayers consisting of La1−xCaxMnO3 ferromagnetic (FM) layers (x=0.33, 0.4) and La0.33Ca0.67MnO3 antiferromagnetic (AF) layers were grown on (001)LaAlO3 to study the evolution of exchange coupling interactions. The epitaxy was revealed by conventional and high resolution electron mic…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Photoluminescence spectrum of highly excited single CdS nanocrystals studied by a scanning near-field optical microscope

Yoshihiko Kanemitsu、Takeshi Inagaki、M. Ando 等 6 位作者2002-07-01Applied Physics Letters

Many-body effects in strongly photoexcited single CdS nanocrystals embedded in Al2O3 matrices have been studied by a scanning near-field optical microscope at low temperatures. Under weak excitations, we find a sharp photoluminescence (PL) band originating from the exciton recombination. With an increase of the excita…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNear-Field Optical Microscopy

Thermoluminescence Characteristics of Teflon Embedded CaSO4:Dy TLD

Jing Yang、Dongseop Kim、Si Young Chang 等 5 位作者2002-07-01Radiation Protection Dosimetry

The Korea Atomic Energy Research Institute (KAERI) is manufacturing CaSO4:Dy Teflon TL pellets which have more sensitivity and stability than commercial TLD. A method is presented of preparing the CaSO4:Dy phosphor-embedded Teflon powder, which is then compressed to a thin pellet form used as the TLD element. Investig…

Luminescence Properties of Advanced MaterialsRadiation Effects and DosimetryEngineering Applied Research

Upgrading triethanolamine esterquat performance to new levels

F. E. Friedli、H. J. Koehle、M. Fender 等 8 位作者2002-07-01Journal of Surfactants and Detergents

Abstract Triethanolamine (TEA)‐based esterquat has been the primary ingredient in European fabric softeners for several years and is becoming the global molecule of choice. Although it has an excellent environmental profile, TEA esterquat has been plagued by mediocre performance compared to historical molecules such a…

Dyeing and Modifying Textile FibersTextile materials and evaluations

Experimental and Numerical Investigation of the Bridgman Growth of a Transparent Material

James Simpson、Suresh V. Garimella、H. C. de Groh2002-07-01Journal of Thermophysics and Heat Transfer

A combined experimental and numerical study of the horizontal Bridgman growth of pure succinonitrile (SCN) has been performed. The effect of convection on interface propagation and shape is quantified and discussed. Measurements were obtained both under conditions of nogrowth and for a 40 µm/s growth rate. The quantit…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Effect of mixing method on rheological properties of alginate impression materials

K. Inoue、Y. X. Song、Osamu Kamiunten 等 6 位作者2002-07-01Journal of Oral Rehabilitation

The apparent viscosity of alginate impression paste prepared by three mixing methods (hand-mixing technique (HM), semiautomatic instrument (SM) and automatic mixing instrument (AM)), and the gel strength and surface depression of the respective set materials were measured. The materials used were eight commercially av…

Surface Modification and SuperhydrophobicityTextile materials and evaluationsMaterial Properties and Processing

Homopolymers and copolymers of N-4-phenylbenzamido-L-lysine and N-trifluoroacetyl-L-lysine: Synthesis and liquid-crystalline properties

Céline Guillermain、Bernard Gallot2002-07-01Macromolecular Chemistry and Physics

In order to obtain comb-like poly-L-lysines bearing a biphenyl mesogen at the end of every repeating unit we have synthesised Nε-4-phenylbenzamido-L-lysine (Kφφ) and the corresponding N-carboxy anydride (Kφφ-NCA). We have homopolymerised the Kφφ-NCA and block-copolymerised it with the NCA of Nε-trifluoroacetyl-L-lysin…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Effect of interstitial hydrogen on structural and electronic properties of BaTiO3

Arvids Stashans、Johnny Chimborazo2002-07-01Philosophical Magazine B

We investigate the geometry and electronic structure of an interstitial H atom in the BaTiO3 crystal considering both cubic and tetragonal crystallographic lattices. A quantum-chemical method based on the Hartree-Fock formalism is used throughout the study. Interstitial H is found to bind to one of the O atoms, formin…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Novel hexasubstituted triphenylene discotic liquid crystals having three different types of peripheral substituent

Sandeep Kumar、Jaishri J. Naidu2002-07-01Liquid Crystals

The synthesis and mesomorphic properties of a variety of novel hexasubstituted triphenylene derivatives having three different types of peripheral substitutions are described. Monobromination of 2,3,6,7-tetrakis(pentyloxy)triphenylene 4, prepared by Suzuki coupling of 2-iodo-3′,4,4′,5-tetrakis(pentyloxy)biphenyl 2 and…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

Fatigue crack nuclei in austempered ductile cast iron

T.J. Marrow、Hakan Çetinel、M. Al-Zalmah 等 6 位作者2002-07-01Fatigue & Fracture of Engineering Materials & Structures

ABSTRACT Short fatigue crack nuclei in austempered ductile cast iron have been studied using optical microscopy, scanning electron microscopy, atomic force microscopy and X‐ray microtomography and by electron backscatter diffraction analysis. Fatigue cracks nucleate at graphite nodules and shrinkage microporosity. The…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Melting Temperature of Mixed Oxide Fuels for Fast Reactors

Koichi Konno、Takashi Hirosawa2002-07-01Journal of Nuclear Science and Technology

Alternation of the melting temperature of irradiated mixed oxide (MOX) fuel in fast reactors with progress of burnup was determined in relation to the actinide fractions contained and of the oxygen-to-metal (O/M) ratio. Based on ideal solution models of UO2-PuO2 and UO2-PuO2-Am2O3 systems and on correlations obtained…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

An intermediate monoclinic phase and electromechanical interactions in xPbTiO3-(1−x)Pb(Zn1/3Nb2/3)O3 crystals

V. Yu. Topolov、A. V. Turik2002-07-01Physics of the Solid State

The elastic matching of phases in the vicinity of the morphotropic phase boundary in x PbTiO 3 -(1− x )Pb(Zn 1/3 Nb 2/3 )O 3 crystals is investigated in an external electric field with strength E ‖ [001]. The field dependences of the unit cell parameters of the monoclinic phase are determined experimentally in the ran…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Growth-Sector Boundaries and Growth-Rate Dispersion in Potassium Alum Crystals

H. Klapper、Robert A. Becker、D. Schmiemann 等 4 位作者2002-07-01Crystal Research and Technology

Crystals of potassium alum, pure and slightly doped with Cr3+, were grown from aqueous solution by slow temperature lowering. In addition, short re-dissolution periods were introduced in order to provoke growth defects and changes of growth rates. Crystal slices of about 1 mm thickness were studied by conventional LAN…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaCrystallization and Solubility Studies

Factors contributing to decreased protein stability when aspartic acid residues are in β‐sheet regions

P. Raj Pokkuluri、M. Gu、Xiaoyin Cai 等 6 位作者2002-07-01Protein Science

Asp residues are significantly under represented in beta-sheet regions of proteins, especially in the middle of beta-strands, as found by a number of studies using statistical, modeling, or experimental methods. To further understand the reasons for this under representation of Asp, we prepared and analyzed mutants of…

Protein Structure and DynamicsProtein purification and stabilityEnzyme Structure and Function

125I-Labeled PLA/PEO Block Copolymer: Biodistribution Studies in Rats

Kateřina Nováková、Milan Lázníček、František Rypáček 等 4 位作者2002-07-01Journal of Bioactive and Compatible Polymers

Block copolymers have a potential utility as drug carriers. In order to study their in vivo fate, the biodegradable block copolymer poly(D,L- lactide ethylene oxide) (PLA/PEO) (Mw 5000/5000) with a p-methoxyphenyl moiety was radio labeled with 125 I. The copolymer was [ 125 I] iodinated in the organic medium by a chlo…

Nanoparticle-Based Drug DeliveryLanthanide and Transition Metal ComplexesRadiopharmaceutical Chemistry and Applications

Amine carboxylates as vapour phase corrosion inhibitors

Eino Vuorinen、William Skinner2002-07-01British Corrosion Journal

Fifty three products, mostly carboxylate salts of amines, were evaluated as vapour phase corrosion inhibitors for mild steel. Fifteen compounds showed effectiveness in excess of 90%. Morpholine was the most effective amine and caprylic acid the most effective acid constituent. The effectiveness of ammonium monocarboxy…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability