Materials Literature
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Water-dispersible polypyrrole nanospheres with diameters of less than 100 nm were synthesized in high yield without any templates, surfactants, or functional dopants by the introduction of 2,4-diaminodiphenylamine as an initiator into a reaction mixture of pyrrole monomer, oxidant, and acid. The initiator plays a crit…
A bundle of many fibers with stochastically distributed breaking thresholds is considered as a model of composite materials. The fibers are assumed to share the load equally, and to obey Hookean elasticity up to the breaking point. The bundle is slightly overloaded, which leads to complete failure. We study the proper…
The spectral--kinetic characteristics of a ZnO:Ga single crystal upon excitation in the vacuum UV region have been studied. At a temperature of 8 K, the exciton luminescence line peaking at 3.356 eV has an extremely small half-width (7.2 meV) and a short decay time (360 ps). In the visible range, a wide luminescence b…
As a model of composite material, the fiber bundle model has been chosen -where a bundle of fibers is subjected to external load and fibers have distributed thresholds. For different loading conditions, such a system shows few precursors which indicate that the complete failure is imminent. When external load is incre…
This paper deals with the mathematical definition of a general vector hysteresis operator in 3-D, as an extension of previous papers where the theory has been limited to the 2-D case. Although the paper is mainly focused on magnetic hysteresis, the definitions and the results reported can be applied to any general phy…
A computational methodology based on Metropolis Monte Carlo (MC) and the weighted histogram analysis method (WHAM) has been developed to calculate the absolute binding free energy between functionalized nanocarriers (NC) and endothelial cell (EC) surfaces. The calculated NC binding free energy landscapes yield binding…
We investigate ground and excited state transport through small (d≈70 nm) graphene quantum dots. The successive spin filling of orbital states is detected by measuring the difference between ground-state energies as a function of a magnetic field. For a magnetic field in-plane of the quantum dot the Zeeman splitting o…
The magnetocaloric effect (MCE) of A-site ordered PrBaMn2O6 manganite has been studied by direct methods and by the specific heat measurements. Direct measurements of the MCE in low magnetic fields were performed using recently proposed modulation technique and by classic direct method in high fields. Direct and inver…
The aim of this study was to explore the utilization of industrial bio-residues as a source of raw material for the industrial production of cellulose nanowhiskers. The used residue, obtained from a bioethanol pilot plant, was first purified using chemical extraction and bleaching, and then separated to nanowhiskers b…
Despite the wide use of silver nanoparticles (nano Ag), its toxicity still remains poorly understood. In this report, nano Ag induced an increase in platelet aggregation and procoagulant activation which are the key contributors to thrombotic diseases. In freshly isolated human platelets, nano Ag induced platelet aggr…
Topological phase transitions between a conventional insulator and a state of matter with topological properties have been proposed and observed in mercury telluride - cadmium telluride quantum wells. We show that a topological state can be induced in such a device, initially in the trivial phase, by irradiation with…
Uniaxial hot pressing has been used to obtain ceramics based on zinc oxide, and their optical, x-ray-structure, luminescence, and scintillation characteristics have been studied. It is shown that, by changing the concentration of the dopant (Ga) and the codopant (N), it is possible to change the intensities of the edg…
Ceramics ZnO:Zn of 20mm diameter and 1.6mm thickness with an optical transparency up to 0.33 in the visible region have been prepared by hot pressing technique. Scintillating and luminescent characteristics such as emission spectra, decay time, yield, and TSL glow curve have been measured under X-ray excitation. Two e…
The pyramid-to-dome transition in Ge$_{x}$Si$_{1-x}$ on Si(100) initiated by step bunching on pyramidal quantum dots is atomistically simulated using a novel multi-state lattice model incorporating effective surface reconstructions. Results are explained by a simple theory based on a shallow island approximation. Unde…
We report a method to pattern monolayer graphene nanoconstriction field effect transistors (NCFETs) with critical dimensions below 10 nm. NCFET fabrication is enabled by the use of feedback controlled electromigration (FCE) to form a constriction in a gold etch mask that is first patterned using conventional lithograp…
Abstract Lanthanide nanoparticles (NPs), characterized by their large Stokes’ shifts, narrow emission bands and high photochemical stability, are promising candidates for optical probes in biological research. As a typical red emission material, Eu3+‐doped YVO4 is investigated in pursuit of an integral methodology for…
The importance of nonclassical, multistage crystallization pathways is increasingly evident from theoretical studies on colloidal systems and experimental investigations of proteins and biomineral phases. Although theoretical predictions suggest that proteins follow these pathways as a result of fluctuations that crea…
Graphene has attracted a great deal of scientific interest in latter years owing to its unique properties, with many prospective applications being actively investigated at present. However, the actual implementation of graphene in technological uses will depend critically on the development of appropriate methodologi…
Magic-number theories, developed to explain the anomalous stability of clusters in the gas phase, are being successfully applied to explain the stability of families of condensed phase Au clusters. To test the generalizability of these theories, we have synthesized a family of magic-numbered Ag clusters. Silver cluste…
Atomically thin WO 3 is fabricated using a three-step process, involving wet-chemical synthesis of hydrated-WO 3, mechanical exfoliation of fundamental layers and dehydration by annealing at 300 °C. Atomic force microscopy reveals that the minimum resolvable thickness of the hydrated flakes to be ∼1.4 nm, which corres…