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Spontaneous Discrimination of Polycyclic Aromatic Hydrocarbon (PAH) Enantiomers on a Metal Surface

Gonzalo Otero、Giulio Biddau、Taisuke Ozaki 等 7 位作者2010-11-23Chemistry - A European Journal

Surface control: Vacuum deposition of a planarized PAH (C60H30) on a Pt(111) surface induces chirality caused by the different landing side of the molecule, as shown by in situ STM images. The surface determines the landing side of individual molecules, which present different structural geometries that are shifted by…

Graphene research and applicationsMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Rapid Densification of Yttria‐Stabilized Tetragonal Zirconia by Electric Current‐Activated/Assisted Sintering Technique

Tatsuo Kumagai2010-11-23Journal of the American Ceramic Society

The high‐speed densification behavior of nanocrystalline 3 mol% yttria‐stabilized tetragonal zirconia polycrystal compacts during electric current‐activated/assisted sintering (ECAS) in the initial sintering stage (relative density: ρ≤0.92) was investigated. Fully dense bulk samples with an average grain size of about…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisAdvanced materials and composites

MOCVD Cobalt Oxide Deposition from Inclusion Complexes: Decomposition Mechanism, Structure, and Properties

N. D. Papadopoulos、Haido S. Karayianni、P.E. Tsakiridis 等 6 位作者2010-11-23Journal of The Electrochemical Society

MOCVD Cobalt Oxide Deposition from Inclusion Complexes: Decomposition Mechanism, Structure, and Properties, Papadopoulos, N. D., Karayianni, H. S., Tsakiridis, P. E., Perraki, M., Sarantopoulou, E., Hristoforou, E.

ZnO doping and propertiesSemiconductor materials and devicesCopper-based nanomaterials and applications

Ligand-Induced Formation of a Transient Tryptophan Synthase Complex with αββ Subunit Stoichiometry

Alexander Ehrmann、Klaus Richter、Florian Büsch 等 6 位作者2010-11-23Biochemistry

The prototypical tryptophan synthases form a stable heterotetrameric αββα complex in which the constituting TrpA and TrpB1 subunits activate each other in a bidirectional manner. The hyperthermophilic archaeon Sulfolobus solfataricus does not contain a TrpB1 protein but instead two members of the phylogenetically dist…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

Growth, Characterization, and Polarity Identification of (0001) Zn[sub 1−x]Mg[sub x]O Epitaxial Films on Lattice-Matched β-LiGaO[sub 2] (001) Substrates

Wan-Hsien Lin、Mitch M. C. Chou、Jih‐Jen Wu2010-11-23Journal of The Electrochemical Society

Small lattice-mismatched (001) substrates have been used for the epitaxial growth of (0001) films using the metallorganic chemical vapor deposition method. Structure characterizations by employing X-ray diffraction and transmission electron microscope demonstrate that no MgO or Mg cluster exists throughout the films.…

ZnO doping and propertiesSemiconductor materials and devicesGa2O3 and related materials

Synthesis, structures, and magnetic properties of two pyrazolato-bridged trinuclear copper(II) complexes

Feng‐Mei Nie、Zhi-Yun Dong、Fei Lu 等 4 位作者2010-11-23Journal of Coordination Chemistry

One nonlinear and one linear trinuclear copper(II) complex [Cu3(dien)2(pdc)2CH3OH]2 · 6CH3OH (1) and [Cu3(pdc)2(CH3OH)6(H2O)4] (2) were prepared and characterized structurally, where dien is diethylenetriamine and pdc3− the trianion of 3,5-pyrazoledicarboxylic acid. Both complexes consist of 3,5-pyrazoledicarboxylato-…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

General properties of surface modes in binary metal-dielectric metamaterials

SungHyun Nam、Erick Ulin-Avila、Guy Bartal 等 4 位作者2010-11-23Optics Express

We present general properties of surface modes in binary metal-dielectric metamaterials. We show mechanism for surface mode formation and analyze their existence conditions for semi-infinite metamaterials in the frame of couple mode theory.

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Going beyond the mean field approximation in classical density functional theory and application to one attractive core-softened model fluid

Shiqi Zhou2010-11-23Journal of Statistical Mechanics Theory and Experiment

A novel scheme is advanced for an excess Helmholtz free energy density functional. The present scheme is isomorphic to one frequently used mean field approximation (MFA) methodology, but goes beyond the latter in that the present scheme contains a bulk second-order direct correlation function (DCF) which can be obtain…

Phase Equilibria and ThermodynamicsHigh-pressure geophysics and materialsMaterial Dynamics and Properties

Matrix metalloproteinase sensing via porous silicon microcavity devices functionalized with human antibodies

Marta Martin、Chakib Taleb Bendiab、Laurent Massif 等 7 位作者2010-11-23Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract Porous silicon microcavity (PSiMc) structures were used as support material for specific sensing of matrix metalloproteinases (MMPs). For lower concentrations of MMP‐8, the structures were tested with two types of functionalization methods. Silanization of the oxidized porous silicon structures, followed by g…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnalytical Chemistry and Sensors

Room temperature amorphous to nanocrystalline transformation in ultra-thin films under tensile stress: anin situTEM study

Mohan Prasad Manoharan、Sandeep Kumar、Aman Haque 等 5 位作者2010-11-23Nanotechnology

The amorphous to crystalline phase transformation process is typically known to take place at very high temperatures and facilitated by very high compressive stresses. In this study, we demonstrate crystallization of amorphous ultra-thin platinum films at room temperature under tensile stresses. Using a micro-electro-…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsIon-surface interactions and analysis

Synthesis and characterization of thermoplastic composites filled with γ‐boehmite for fire resistance

Guillaume Droval、Ibon Aranberri、J. Ballestero 等 5 位作者2010-11-23Fire and Materials

Abstract This paper explores the use of boehmite as a fire retardant in low‐density polyethylene and polyamide 6. The structure and morphology of the filler are characterized by X‐ray diffraction and scanning electron microscopy. The water content of our boehmite is estimated about 30% by thermogravimetric analysis. T…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Silk fibroin has a protective effect against high glucose induced apoptosis in HIT‐T15 cells

Jun Hong Park、YoonYi Nam、So‐Young Park 等 8 位作者2010-11-23Journal of Biochemical and Molecular Toxicology

High glucose levels induce cell death in many cell types, including pancreatic β-cells. Although protective agents against glucotoxicity have been searched for extensively, so far none have been found. In this report, we tested silk fibroin (SF) as a candidate material for antiglucotoxicity in the pancreatic β-cell (H…

Pancreatic function and diabetesSilk-based biomaterials and applicationsSignaling Pathways in Disease

Mechanistic Studies of the Autoactivation of PAK2

Jue Wang、Jiawei Wu、Zhi‐Xin Wang2010-11-23Journal of Biological Chemistry

Protein kinase activation, via autophosphorylation of the activation loop, is a common regulatory mechanism in phosphorylation-dependent signaling cascades. Despite the prevalence of this reaction and its importance in biological regulation, the molecular mechanisms of autophosphorylation are poorly understood. In thi…

Protein Structure and DynamicsProtein Kinase Regulation and GTPase SignalingEnzyme Structure and Function

Dynamic modeling of a SOFC/MGT hybrid power system based on modified OIF Elman neural network

Xiaojuan Wu、Qi Huang、Zhu Xin-jian2010-11-23International Journal of Energy Research

Solid oxide fuel cell (SOFC) integrated into micro gas turbine (MGT) cycle is a promising power-generation technology. This article proposes a modified output–input feedback (OIF) Elman neural network model to describe the nonlinear temperature and power dynamic properties of the SOFC/MGT hybrid system. A physics-base…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsPower Systems and Renewable Energy

Tower systems for linearly repetitive Delone sets

José Aliste‐Prieto、Daniel Coronel2010-11-23Ergodic Theory and Dynamical Systems

Abstract In this paper we study linearly repetitive Delone sets and prove, following the work of Bellissard, Benedetti and Gambaudo, that the hull of a linearly repetitive Delone set admits a properly nested sequence of box decompositions (tower system) with strictly positive and uniformly bounded (in size and norm) t…

Mathematical Dynamics and FractalsQuasicrystal Structures and PropertiesCellular Automata and Applications

Polytellurophenes with Properties Controlled by Tellurium‐Coordination

Ashlee A. Jahnke、Graeme W. Howe、Dwight S. Seferos2010-11-23Angewandte Chemie

Koordinierte Kontrolle: Wegen ihrer äußerst schwierigen Synthese sind Polytellurophene praktisch unerforscht. Ein neues dihalogeniertes Bitellurophen-Monomer wurde synthetisiert, und seine Polymerisation unter Palladium-katalysierten Bedingungen wurde optimiert. Die entstehenden Polytellurophene sind stabile Verbindun…

Organic Electronics and PhotovoltaicsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Optically Stimulated Luminescence in Fluoride–Phosphate Glass for Radiation Dosimetry

Christopher A. G. Kalnins、Heike Ebendorff‐Heidepriem、Nigel A. Spooner 等 4 位作者2010-11-23Journal of the American Ceramic Society

Optically stimulated luminescence (OSL) was studied in undoped and rare‐earth doped fluoride–phosphate glass. Following exposure to 90 Sr/ 90 Y β‐radiation, the samples demonstrated strong OSL in the 350–600 nm wavelength range. Here, we explore the effects of fabrication conditions and rare‐earth dopants on the OSL.…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Magnetoelastic Materials as Novel Bioactive Coatings for the Control of Cell Adhesion

Eli Vlaisavljevich、Logan P. Janka、Keat Ghee Ong 等 4 位作者2010-11-23IEEE Transactions on Biomedical Engineering

Interfacial fibrosis is known to dramatically decrease the lifespan, stability, and function of biomedical implants and bone-anchored prosthetics. Bioactive coatings aimed at mitigating fibrous adhesions are one of the approaches to alleviate the problem. In this paper, we are developing a bioactive coating based upon…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyMagnesium Alloys: Properties and Applications

PARTICULARITIES OF THE ELECTRICAL PROPERTIES OF CuInAsSe3 AT HIGH PRESSURES AND LOW TEMPERATURES

N. V. Melnikova、О. Л. Хейфец、А. Н. Бабушкин 等 4 位作者2010-11-23Sensor Electronics and Microsystem Technologies

The results of the experimental studies of effect of high pressures (12–45 GPa) and low temperatures (10–300 K) on the electrical properties of the semiconductor CuInAsSe3 are presented. The temperature and pressure ranges of noticeable changes in a behaviour of the electrical properties are established. At atmospheri…

Chalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Modeling the Interactions of the Nucleotide Excision Repair UvrA2 Dimer with DNA

Tsvetan G. Gantchev、Darel J. Hunting2010-11-23Biochemistry

The UvrA protein initiates the DNA damage recognition process by the bacterial nucleotide excision repair (NER) system. Recently, crystallographic structures of holo-UvrA(2) dimers from two different microorganisms have been released (Protein Data Bank entries 2r6f , 2vf7 , and 2vf8 ). However, the details of the DNA…

Bacterial Genetics and BiotechnologyDNA Repair MechanismsEnzyme Structure and Function