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Preparation and Studies of Cerium Dioxide(CeO2) Nanoparticles by Microwave-assisted Solution Method

E. T. Deva Kumar、P. Selvarajan、Balasubramanian Kandasubramanian2010-07-25Recent Research in Science and Technology

In this paper, synthesis and characterization of cerium dioxide (CeO 2 ) or ceria nanoparticles are presented. Nanoparticles of cerium dioxide were synthesized by solution method using a microwave oven. The precursor used to prepare the nanoparticles of CeO 2 was ammonium ceric nitrate. The precursor was dissolved in…

Advanced Nanomaterials in CatalysisElectrochemical sensors and biosensors

Molecular Identification of N-Acetylaspartylglutamate Synthase and β-Citrylglutamate Synthase

François Collard、Vincent Stroobant、Pedro Lamosa 等 9 位作者2010-07-25Journal of Biological Chemistry

The purpose of the present work was to determine the identity of the enzymes that synthesize N-acetylaspartylglutamate (NAAG), the most abundant dipeptide present in vertebrate central nervous system (CNS), and β-citrylglutamate, a structural analogue of NAAG present in testis and immature brain. Previous evidence sug…

RNA and protein synthesis mechanismsProtein Structure and DynamicsEnzyme Structure and Function

Background-free quasi-steady-state photoinduced absorption spectroscopy by dual optical modulation

Houssem Kallel、Gianluca Latini、Francis Paquin 等 6 位作者2010-07-25arXiv

We present a simple and inexpensive means to measure background-free photoinduced absorption spectra by implementing a dual optical modulation scheme. Our objective is to measure quasi-steady-state absorption spectra of long-lived photoexcitations, such as polarons and triplet excitons in organic semiconductors, when…

physics.opticsMaterials Science

Stochastic Generation of Particle Structures with Controlled Degree of Heterogeneity

Iwan Schenker、Frank T. Filser、Ludwig J. Gauckler2010-07-25arXiv

The recently developed void expansion method (VEM) allows for an efficient generation of porous packings of spherical particles over a wide range of volume fractions. The method is based on a random placement of the structural particles under addition of much smaller "void-particles" whose radii are repeatedly increas…

Materials ScienceSoft Condensed Matter

Möbius Aromatic Palladium(II) Complexes of a β-Tetraphenyl meso-Hexakis(pentafluorophenyl) Substituted Hexaphyrin(1.1.1.1.1.1)

Taro Koide、Atsuhiro Osuka2010-07-24Bulletin of the Chemical Society of Japan

Abstract Two isomeric PdII complexes, 4 and 5, of a β-tetraphenyl meso-hexakis(pentafluorophenyl) substituted [28]hexaphyrin were isolated, both of which exhibited distinct diatropic ring currents and electronic absorption spectra characteristic of aromatic porphyrinoids. These complexes have been designated Möbius ar…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Glutathione Nanosphere: Self-Assembly of Conformation-Regulated Trigonal-Glutathiones in Water

Kazunori Matsuura、Keisuke Fujino、Takeshi Teramoto 等 5 位作者2010-07-24Bulletin of the Chemical Society of Japan

Abstract A novel trigonal conjugate of glutathiones with a 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene core was synthesized and its self-assembling behavior was investigated in water. Three glutathione units were regulated to orient on the same side of the benzene ring, through steric repulsions between ethyl groups…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsSulfur Compounds in Biology

Functional Roles of the Conserved Glu304 Loop of Bacillus subtilis Glutamine Synthetase

Lewis V. Wray、Susan H. Fisher2010-07-24Journal of Bacteriology

The enzymatic activity of Bacillus subtilis glutamine synthetase (GS), which catalyzes the synthesis of glutamine from ammonium and glutamate, is regulated by glutamine feedback inhibition. The feedback-inhibited form of B. subtilis GS regulates the DNA-binding activities of the TnrA and GlnR nitrogen transcriptional…

Enzyme Structure and FunctionBacterial Genetics and BiotechnologyAmino Acid Enzymes and Metabolism

Colonial planktonic Eunotia (Bacillariophyceae) from Brazilian Amazon: Taxonomy and biogeographical considerations on the E. asterionelloides species complex

Carlos E. Wetzel、Luc Éctor、Lucien Hoffmann 等 4 位作者2010-07-24Nova Hedwigia

Colonial planktonic diatoms representative of the genus Eunotia Ehrenberg are common in phytoplankton assemblages from oligotrophic pristine rivers and streams in the Amazon hydrographical basin. A taxonomic account on E. asterionelloides and related species revealed the presence of four unknown taxa, which are formal…

Aquatic Ecosystems and Phytoplankton DynamicsFish biology, ecology, and behaviorDiatoms and Algae Research

Inhibition of cold rolled steel corrosion in sulphuric acid solution by 2-mercapto-1-methylimidazole: Time and temperature effects treatments

O. Benali、Mokhtar Ouazene2010-07-24Arabian Journal of Chemistry

2-Mercapto-1-methylimidazole (MMI) has been evaluated as a corrosion inhibitor for cold rolled steel in aerated 2 M H2SO4 by gravimetric method. The effect of MMI on the corrosion rate was determined at various immersions time and concentrations. The effect of the temperature on the corrosion behaviour with addition o…

Concrete Corrosion and DurabilityCorrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metals

Synthesis of Siloxene Derivatives with Organic Groups

Yusuke Sugiyama、Hirotaka Okamoto、Hideyuki Nakano2010-07-24Chemistry Letters

Abstract Reaction of calcium disilicide (CaSi2) and hydrogen chloride solution with various alcohols yields siloxene derivatives terminated with functional groups that are determined by the alcohol used as the solvent in the reaction. The functional groups terminated on silicon determine the basal spacing of the silox…

Molecular Junctions and NanostructuresDiamond and Carbon-based Materials ResearchCarbon Nanotubes in Composites

Overview of Potential and Existing Applications of Shape Memory Alloys in Bridges

Junhui Dong、C.S. Cai、Ayman M. Okeil2010-07-24Journal of Bridge Engineering

Bridges are the backbones of transportation lines for modern cities. Damage to bridges could disrupt the flow of traffic and be disastrous for the communities they serve, especially when reconstruction and recovery activities are needed, such as after strong earthquakes and hurricanes. Recent earthquake and hurricane…

Structural Engineering and Vibration AnalysisShape Memory Alloy TransformationsMasonry and Concrete Structural Analysis

The influence of natural organic matter on the toxicity of multiwalled carbon nanotubes

Aaron J. Edgington、Aaron P. Roberts、Leigh M. Taylor 等 8 位作者2010-07-24Environmental Toxicology and Chemistry

Engineered carbon nanostructures, such as multiwalled carbon nanotubes (MWNTs), are inherently hydrophobic and are not readily stable in aqueous media. However, the aqueous stability and bioavailability of these nanotubes may be influenced by the water quality parameters such as ionic strength, pH, and natural organic…

Nanoparticles: synthesis and applicationsElectrochemical Analysis and ApplicationsEnvironmental Toxicology and Ecotoxicology

Spatial Point Analysis of Quantum Dot Nucleation Sites on InAs Wetting Layer

Tomoya Konishi、Shiro Tsukamoto2010-07-24arXiv

We perform spatial point analysis of InAs quantum dot nucleation sites and surface reconstruction domain pattern on an InAs wetting layer, giving insights for quantum dot nucleation mechanism. An InAs wetting layer grown to 1.5 monolayers in thickness on a GaAs(001) substrate has been observed at 300 degC by using in…

Materials Science

Melting of superheated crystals initiates on vacancies

L. W. Wang、Q. Wang、K. Q. Lu2010-07-24arXiv

In a large variety of ideal crystals we found that when rapidly migrating atoms squash or annihilate a neighbouring vacancy and produce a disordered cluster, the heat of migration stored in the system exceeds the enthalpy increase required for the coordinating atoms of the vacancy to form a liquid phase, i.e. the liqu…

Materials ScienceSoft Condensed Matter

Novel In Vivo -Degradable Cellulose-Chitin Copolymer from Metabolically Engineered Gluconacetobacter xylinus

Vikas Yadav、Bruce J. Paniliatis、Hai Shi 等 6 位作者2010-07-24Applied and Environmental Microbiology

Despite excellent biocompatibility and mechanical properties, the poor in vitro and in vivo degradability of cellulose has limited its biomedical and biomass conversion applications. To address this issue, we report a metabolic engineering-based approach to the rational redesign of cellular metabolites to introduce N-…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesEnzyme Production and Characterization

DNA Translocation through Graphene Nanopores

Christopher A. Merchant、Ken Healy、Meni Wanunu 等 11 位作者2010-07-23Nano Letters

We report on DNA translocations through nanopores created in graphene membranes. Devices consist of 1-5 nm thick graphene membranes with electron-beam sculpted nanopores from 5 to 10 nm in diameter. Due to the thin nature of the graphene membranes, we observe larger blocked currents than for traditional solid-state na…

Advanced biosensing and bioanalysis techniquesNanopore and Nanochannel Transport StudiesGraphene research and applications

Hysteresis Phenomenon Implementation in FIT: Validation With Measurements

Julien Korecki、Abdelkader Bénabou、Yvonnick Le Menach 等 5 位作者2010-07-23IEEE Transactions on Magnetics

The presented work is about the implementation of a vector hysteresis model in a Finite Integration Technique (FIT) calculation code. This is achieved in the magnetostatic case using the vector potential formulation and with the external electric circuit coupling. The used behavior law model is the vectorized Jiles-At…

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsNon-Destructive Testing Techniques

The effect of yarn twist direction on the formability of woven fabrics

A. Alamdar‐Yazdi、Seyed Mansour Bidoki2010-07-23Journal of the Textile Institute

This experimental work examines the influence of the yarn twist on the formability of a woven fabric. Consideration is given to the phenomenon of bedding between warp and weft yarns, as affected by the local helix angles of bent yarns. A total of 28 plain weave woven fabrics (four groups, each with seven samples) were…

Textile materials and evaluationsMechanical Behavior of CompositesStructural Analysis and Optimization

Development of Resin Adsorbents for Blood Purification at Nankai University in China

Yongjian Wang、Yaoting Yu2010-07-23Artificial Cells Blood Substitutes and Biotechnology

Various types of porous resin adsorbents based on polystyrene, agarose, and cellulose as matrixes coupling with DNA, amino acids and other biological active molecules as ligands were extensively studied in China. Molecular recognition between the ligand and pathogenic molecule was investigated. Several commercialized…

HIV/AIDS drug development and treatmentProtein purification and stabilityDendrimers and Hyperbranched Polymers