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Triazine‐Based Polymers as Nanostructured Supports for the Liquid‐Phase Oxidation of Alcohols

Carine E. Chan‐Thaw、Alberto Villa、Laura Prati 等 4 位作者2010-11-18Chemistry - A European Journal

A covalent triazine framework (CTF) was used as support for palladium nanoparticles (NPs) and Pd/CTF was applied as the catalyst in the selective oxidation of benzyl alcohol. N groups in the CTF appeared more efficient than those created on carbon nanotubes (CNTs) by NH(3) /high-temperature treatment in stabilizing Pd…

Metal-Organic Frameworks: Synthesis and ApplicationsFuel Cells and Related MaterialsCovalent Organic Framework Applications

Consistent model of magnetism in ferropnictides

A. L. Wysocki、K. D. Belashchenko、V. P. Antropov2010-11-18arXiv

The discovery of superconductivity in LaFeAsO introduced the ferropnictides as a major new class of superconducting compounds with critical temperatures second only to cuprates. The presence of magnetic iron makes ferropnictides radically different from cuprates. Antiferromagnetism of the parent compounds strongly sug…

Materials ScienceSuperconductivity

Tin telluride: A weakly co-elastic metal

Ekhard K. H. Salje、D. J. Safarik、K. A. Modic 等 16 位作者2010-11-18Physical Review B

We report resonant ultrasound spectroscopy (RUS), dilatometry/magnetostriction, magnetotransport, magnetization, specific-heat, and $^{119}\text{S}\text{n}$ M\"ossbauer spectroscopy measurements on SnTe and ${\text{Sn}}_{0.995}{\text{Cr}}_{0.005}\text{Te}$. Hall measurements at $T=77\text{ }\text{K}$ indicate that our…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesAdvanced Semiconductor Detectors and Materials

Magnetic reversal processes and critical thickness in FePt/α-Fe/FePt trilayers

N. L. Guo、G. P. Zhao、H. W. Zhang 等 4 位作者2010-11-18arXiv

Magnetic reversal processes of a FePt/α-Fe/FePt trilayer system with in-plane easy axes have been investigated within a micromagnetic approach. It is found that the magnetic reversal process consists of three steps: nucleation of a prototype of domain wall in the soft phase, the evolution as well as the motion of the…

Materials Science

Nature’s Design of Hierarchical Superhydrophobic Surfaces of a Water Strider for Low Adhesion and Low-Energy Dissipation

Yewang Su、Baohua Ji、Yonggang Huang 等 4 位作者2010-11-18Langmuir

The mechanics of wet adhesion between a water strider's legs and a water surface was studied. First, we showed that the nanoscale to microscale hierarchical surface structure on striders' legs is crucial to the stable water-repellent properties of the legs. The smallest structure is made for the sake of a stable Cassi…

Surface Modification and SuperhydrophobicityHeat Transfer and OptimizationAdhesion, Friction, and Surface Interactions

Woven Fabric Engineering

Polona Dobnik Dubrovski2010-11-18Sciyo eBooks

The main goal in preparing this book was to publish contemporary concepts, new discoveries and innovative ideas in the field of woven fabric engineering, predominantly for the technical applications, as well as in the field of production engineering and to stress some problems connected with the use of woven fabrics i…

Textile materials and evaluations

Controlled Buckling and Crumpling of Nanoparticle-Coated Droplets

Sujit S. Datta、Ho Cheung Shum、David A. Weitz2010-11-18Langmuir

We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the continuous phase. By adding a fixed amount of unsaturated continuous phase, the volume…

Surface Modification and SuperhydrophobicityAdvanced Materials and MechanicsPickering emulsions and particle stabilization

Repulsive Casimir forces with finite-thickness slabs

R. Zhao、Th. Koschny、E. N. Economou 等 4 位作者2010-11-18arXiv

We use the extended Lifshitz theory to study the behaviors of the Casimir forces between finite-thickness effective medium slabs. We first study the interaction between a semi-infinite Drude metal and a finite-thickness magnetic slab with or without substrate. For no substrate, the large distance $d$ dependence of the…

Mesoscale and Nanoscale PhysicsMaterials Sciencephysics.opticsquant-ph

Self-immolative linkers in polymeric delivery systems

Christopher A. Blencowe、Andrew T. Russell、Francesca Greco 等 5 位作者2010-11-18Polymer Chemistry

There has been significant interest in the methodologies of controlled release for a diverse range of applications spanning drug delivery, biological and chemical sensors, and diagnostics. The advancement in novel substrate-polymer coupling moieties has led to the discovery of self-immolative linkers. This new class o…

RNA Interference and Gene DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Quantum criticality of vanadium chains with strong relativistic spin-orbit interaction

Gia-Wei Chern、Natalia B. Perkins、G. I. Japaridze2010-11-18Physical Review B

We study quantum phase transitions induced by the on-site spin-orbit interaction $\ensuremath{\lambda}\mathbf{L}\ensuremath{\cdot}\mathbf{S}$ in a toy model of vanadium chains. In the $\ensuremath{\lambda}\ensuremath{\rightarrow}0$ limit, the decoupled spin and orbital sectors are described by a Haldane and an Ising c…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Scattering of band carriers by neutral and charged impurities

l. I. Bolko2010-11-18arXiv

Mobility of band carriers scattered on donors, partially ionized, partially neutral, is considered in general and calculated for crystals belonging to AIII-BV group. As neutral impurity we have constructed the hydrogen-like model. It is shown that dependence of mobility on temperature is determined by relation between…

Materials Science

First-principles calculation of H vibrational excitations at a dislocation core of Pd

Hadley M. Lawler、Dallas R. Trinkle2010-11-18Physical Review B

Palladium is an ideal system for understanding the behavior of hydrogen in metals. In Pd, H is located both in octahedral sites and in dislocation cores, which act as nanoscale H traps and form Cottrell atmospheres. Adjacent to a dislocation core, H experiences the largest possible distortion in $\ensuremath{\alpha}\t…

Advanced Chemical Physics StudiesMetal and Thin Film MechanicsHydrogen Storage and Materials

Possibility of exchange switching ferromagnet - antiferromagnet junctions

Yu. V. Gulyaev、P. E. Zilberman、E. M. Epshtein2010-11-18arXiv

Current flowing is studied in magnetic junctions consisting of a ferromagnetic metal (FM), antiferromagnetic conductor (AFM) and a nonmagnetic metal closing the electric circuit. The FM layer with high anisotropy and pinned spins of the magnetic atoms in the lattice acts as a spin injector relative to the AFM layer. T…

Materials Science

A Comparative Study of Two Folate-Conjugated Gold Nanoparticles for Cancer Nanotechnology Applications

G. Ali Mansoori、Kenneth S. Brandenburg、Ali Shakeri‐Zadeh2010-11-18Cancers

We report a comparative study of synthesis, characteristics and in vitro tests of two folate-conjugated gold nanoparticles (AuNP) differing in linkers and AuNP sizes for selective targeting of folate-receptor positive cancerous cells. The linkers chosen were 4-aminothiophenol (4Atp) and 6-mercapto-1-hexanol (MH) with…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

First-Principles Study on the Origin of the Different Selectivities for Methanol Steam Reforming on Cu(111) and Pd(111)

Xiang‐Kui Gu、Wei‐Xue Li2010-11-18The Journal of Physical Chemistry C

Methanol steam reforming (MSR) is an important industrial process for hydrogen production, and fundamental understanding of the reaction mechanism is crucial to improve the catalytic activity and selectivity. In the present work, we present a comparative mechanistic study of the MSR reaction on two key model systems,…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Exotic materials for bio-organic electronics

Mihai Irimia‐Vladu、Niyazi Serdar Sariçiftçi、Siegfried Bauer2010-11-18Journal of Materials Chemistry

“Exotic” materials have become the focus of recent developments in organic electronics that envision biocompatibility, biodegradability, and sustainability for low-cost, large-volume electronic components. In this brief review, we discuss firstly the use of paper, leather, silk, hard gelatine, and bio-degradable plast…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Excited State Processes in Linear π-System-Based Organogels

Sukumaran Santhosh Babu、Kalathil K. Kartha、Ayyappanpillai Ajayaghosh2010-11-18The Journal of Physical Chemistry Letters

This article describes the recent progress made to the understanding of the excited state interactions in organogels derived from linear π-conjugated molecules. The soft organogel scaffolds of such systems create an excellent ambience for the self-organization of the molecules allowing the modulation of their excited…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Crystal Structures and Exotic Behavior of Magnesium under Pressure

Peifang Li、Guoying Gao、Yanchao Wang 等 4 位作者2010-11-18The Journal of Physical Chemistry C

The high-pressure structures of magnesium (Mg) have been extensively explored through our newly developed particle swarm optimization algorithm on crystal structural prediction. Two structures with face-centered cubic (fcc) and simple hexagonal (sh) symmetries are discovered to be stable at 456−756 GPa and above 756 G…

Metal and Thin Film MechanicsMagnesium Alloys: Properties and ApplicationsBoron and Carbon Nanomaterials Research

Long‐Term Antimicrobial Effect of Silicon Nanowires Decorated with Silver Nanoparticles

Min Lv、Shao Su、Yao He 等 8 位作者2010-11-18Advanced Materials

Silicon nanowires (SiNWs), as a novel one-dimensional semiconducting nanomaterial, are attracting increasing interest in recent years. The synthesis of SiNWs with in situ grown silver nanoparticles (AgNPs) (SiNWs@AgNPs) is reported and the highly effective and long-term antibacterial activity of this novel nanostructu…

Quantum Dots Synthesis And PropertiesNanowire Synthesis and ApplicationsGraphene and Nanomaterials Applications

Functional Hollow Carbon Nanospheres by Latex Templating

Robin J. White、Klaus Tauer、Markus Antonietti 等 4 位作者2010-11-18Journal of the American Chemical Society

A facile and sustainable synthesis of hollow carbonaceous nanospheres is presented, offering a scalable and multifunctional route to the generation of useful nanocontainers, which critically possess the stability not offered by polymeric equivalents and functionality not afforded by other nanocarbons. Carbonization te…

Carbon Nanotubes in CompositesGraphene research and applicationsSynthesis and Properties of Aromatic Compounds