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Effect of a Hydrodynamic Flow on the Orientation Profiles of a Nematic Liquid Crystal Around a Spherical Particle

Makoto Yoneya、Jun‐ichi Fukuda、Hiroshi Yokoyama 等 4 位作者2005-06-01Molecular Crystals and Liquid Crystals

We study the effect of a hydrodynamic flow on the orientational configuration of a nematic liquid crystal around a spherical particle imposing rigid normal anchoring. We discuss the cases of large Ericksen numbers (characterizing the ratio of viscous force to the elastic force), where strong elastic deformation by the…

Liquid Crystal Research AdvancementsOrbital Angular Momentum in OpticsAdvanced Materials and Mechanics

Titanium-Passivated Tinplate for Canning Foods

Rafael Catalá、C. Alonso、Rafael Gavara 等 7 位作者2005-06-01Food Science and Technology International

Chromium-based treatments are currently used for the passivation of tinplate, which produces a protective surface layer consisting of a mixture of metal chromium and chromium oxide. This passivation film is effective against the formation of tin oxides and corrosion by food media, and offers a good substrate for the a…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisPigment Synthesis and Properties

Late Mesozoic—Cenozoic clay mineral successions of southern Iran and their palaeoclimatic implications

Farhad Khormali、A. Abtahi、Hamidreza Owliaie2005-06-01Clay Minerals

Abstract Clay minerals of calcareous sedimentary rocks of southern Iran, part of the old Tethys area, were investigated in order to determine their origin and distribution, and to reconstruct the palaeoclimate of the area. Chemical analysis, X-ray diffraction, transmission electron microscopy, scanning electron micros…

Clay minerals and soil interactionsIron oxide chemistry and applicationsTherapeutic Uses of Natural Elements

Thermal stability of soy-based polyurethanes

Luciane Lemos Monteavaro、Izabel C. Riegel‐Vidotti、César Liberato Petzhold 等 4 位作者2005-06-01Polímeros

New types of polyurethanes were prepared by reacting diisocyanates and formiated soy polyols with different OH functionalities. Thermal properties and degradation kinetics were investigated by TGA. All prepared PU's showed at least two-weight loss steps, the first one, around 210 °C. Thermal stability of these PUs dep…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingThermal and Kinetic Analysis

The Effect of Compatibilizer and Coupling Agent on the Properties of Paper Sludge Filled Polypropylene (PP)/Ethylene Propylene Diene Terpolymer (EPDM) Composites

Salmah H. Ismail、A. Abu Bakar2005-06-01Polymer-Plastics Technology and Engineering

Paper sludge-polypropylene (PP)–ethylene propylene diene terpolymer (EPDM) composites were developed in this study. The paper sludge was used as a filler in PP/EPDM blends, and maleic anhydride-grafted PP (MAPP) and LICA were used as a compatibilizer and a coupling agent, respectively. The mechanical properties, therm…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Interaction between Particles in a Nematic Liquid Crystal: Numerical Study Using the Landau-de Gennes Continuum Theory

Jun‐ichi Fukuda、Hiroshi Yokoyama、Makoto Yoneya 等 4 位作者2005-06-01Molecular Crystals and Liquid Crystals

We study numerically the interaction between particles in a nematic liquid crystal mediated by its elastic distortions with the aid of the Landau-de Gennes continuum theory. We consider the cases where two particles impose rigid normal anchoring on their surfaces and are accompanied by a hyperbolic hedgehog defect. As…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsNonlinear Dynamics and Pattern Formation

Study of Molecular Structures and Properties of Europium(III) Complexes with Phosphine Oxides by NMR Analysis

Hiroki Iwanaga、Akio Amano、Masayuki Oguchi2005-06-01Japanese Journal of Applied Physics

The 31 P-NMR spectra of europium complexes with β-diketones and phosphine oxides in CDCl 3 , DMSO- d 6 , toluene- d 8 with dissolved fluorinated polymers, and fluorinated solvent were investigated as well as the temperature dependence of these spectra. When a mixture of europium complex 1 and 1.0 molar equivalent of t…

Advanced MRI Techniques and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

New Hydroxylated Cationic Gemini Surfactants as Effective Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Medium

Vikas Sharma、Mahendra S. Borse、Smita Jauhari 等 5 位作者2005-06-01Tenside Surfactants Detergents

Abstract Inhibitory action of hydroxylated cationic gemini surfactants on corrosion of mild steel [MS] in 1 M hydrochloric acid medium is studied by gravimetric, electrochemical polarization and electrochemical impedance spectroscopic (EIS) techniques. The results obtained reveal that these compounds are very efficien…

Corrosion Behavior and InhibitionSurfactants and Colloidal SystemsConcrete Corrosion and Durability

Lipase‐catalyzed ring‐opening polymerization of 6(S)‐methyl‐morpholine‐2,5‐dione

Yakai Feng、Doris Klee、Hartwig Höcker2005-06-01Journal of Polymer Science Part A Polymer Chemistry

Abstract Lipase‐catalyzed ring‐opening bulk polymerizations of 6( S )‐methyl‐morpholine‐2,5‐dione (MMD) were investigated. Selected commercial lipases were screened as catalysts for MMD polymerization at 100 °C. Polymerizations catalyzed with 10 wt % porcine pancreatic lipase type II crude (PPL), lipase from Pseudomon…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesCyclopropane Reaction Mechanisms

AN INVESTIGATION ON THE PRESENCE OF NiAl2O4 IN A STABLE Ni ON ALUMINA CATALYST FOR DRY REFORMING

Alberto M. Becerra、A. CASTRO-LUNA2005-06-01Journal of the Chilean Chemical Society

Comprehensive temperature-programmed reduction, X-ray diffraction and diffuse reflectance spectroscopy studies were conducted on a stable nickel (10.5%) catalyst obtained through conventional impregnation of a sol-gel made support of g-Al2O3, to elucidate the interactions between nickel oxide and support. The results…

Catalytic Processes in Materials ScienceMetallurgical Processes and Thermodynamics

Application of Photoalignment Technology to Liquid-Crystal-on-Silicon Microdisplays

Baolong Zhang、Kuenkuen Li、Vladimir G. Chigrinov 等 5 位作者2005-06-01Japanese Journal of Applied Physics

We applied photoalignment technology to liquid-crystal-on-silicon microdisplays and characterized their performance. A three-step photoexposure method was developed to solve problems with alignment disturbances on reflective silicon panels. The azimuthal and polar anchoring energies of photoalignment layers produced b…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Fine ZnO patterning with controlled sidewall-etch front slope

Jae Wan Kwon、Eun Sok Kim2005-06-01Journal of Microelectromechanical Systems

This paper describes a wet-etching technique that solves the major difficulty of fine patterning a c-axis oriented polycrystalline ZnO film. The technique uses aqueous NH/sub 4/Cl with electrolytically added copper ions and convection flow, and for the first time, allows the ZnO film to be etched 1) with controlled et…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsPlasma Diagnostics and Applications

Fabrication of regular silicon microstructures by photo‐electrochemical etching of silicon

Giuseppe Barillaro、Paolo Bruschi、A. Diligenti 等 4 位作者2005-06-01Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

In this paper photo-electrochemical etching of silicon in HF-based solutions is employed as a versatile technique for fabrication of original silicon microstructures, alternative to commonly used methods. Photo-electrochemical etching, a well known technique for regular macropore formation, has been exploited to produ…

Silicon Nanostructures and PhotoluminescenceAnodic Oxide Films and NanostructuresSmart Materials for Construction

A measurements-based discharge location algorithm for plain disc winding power transformers

Zhongdong Wang、Sujeewa Hettiwatte、P.A. Crossley2005-06-01IEEE Transactions on Dielectrics and Electrical Insulation

A measurements-based electrical method for locating partial discharges (PD) in transformers is described in the paper. This location method relies on the series resonance frequencies of the signals produced at the transformer terminals by a discharge on the winding. Based on the equivalent circuit of plain disc type w…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationMagneto-Optical Properties and Applications

PHYSICAL, CHEMICAL AND MICROBIAL CHANGES IN SHREDDED SWEET POTATOES+

R.Y. McCONNELL、Vinh Truong、William M. Walter 等 4 位作者2005-06-01Journal of Food Processing and Preservation

With the increasing demand for freshly cut vegetables, a substantial potential exists in developing minimally processed sweet potato products. This study was undertaken to determine the effects of semipermeable polymeric materials and modified atmosphere packaging (MAP) on quality changes and microbial growth in shred…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingFood Waste Reduction and Sustainability

A Novel Process for Low‐Density Alumina Foams

K. Prabhakaran、N.M. Gokhale、S. C. Sharma 等 4 位作者2005-06-01Journal of the American Ceramic Society

A novel process for low‐density alumina foams has been studied. Aqueous acidic sucrose solution containing aluminum nitrate when concentrated by heating formed a viscous resin. The resin mixed well with aqueous alumina slurry and the resulting powder‐filled resin underwent foaming on heating in a Teflon mold. The gree…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisCatalysis and Hydrodesulfurization Studies

Perturbing the Hydrophobic Pocket of Mandelate Racemase To Probe Phenyl Motion during Catalysis

Ferhan Siddiqi、Jennifer R. Bourque、Haiyan Jiang 等 7 位作者2005-06-01Biochemistry

Mandelate racemase (MR, EC 5.1.2.2) from Pseudomonas putida catalyzes the Mg(2+)-dependent 1,1-proton transfer that interconverts the enantiomers of mandelate. Crystal structures of MR reveal that the phenyl group of all ground-state ligands is located within a hydrophobic cavity, remote from the site of proton abstra…

Protein Structure and DynamicsEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Self-Assembled Networks of Ribbons in Molecular Hydrogels of Cationic Deoxycholic Acid Analogues

Pierre Térech、Neralagatta M. Sangeetha、Bruno Demé 等 4 位作者2005-06-01The Journal of Physical Chemistry B

Aqueous gels derived from three cationic 24-nor 3,12-dihydroxy cholane (DC) derivatives with N-methyl-2-pyrrolidinone (NMP), N-methylmorpholine (NMM), and 1,4-diazabicyclo[2.2.2]octane (DABCO) at the side chain positions have been exhaustively characterized by small-angle neutron-scattering experiments. Although the m…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

SO2 on TiO2(110) and Ti2O3(1012) Nonpolar Surfaces: A DFT Study

Maurizio Casarin、Francesca Ferrigato、Chiara Maccato 等 4 位作者2005-06-01The Journal of Physical Chemistry B

Density functional molecular cluster calculations have been used to investigate the interaction of SO(2) with defect-free TiO(2)(110) and Ti(2)O(3)(102) surfaces. Adsorbate geometries and chemisorption enthalpies have been computed and discussed. Several local minima have been found for TiO(2)(110), but only one seems…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Analysis and Design of Superconducting Left-Handed Transmission Lines

H. Salehi、A. Hamed Majedi、Raafat R. Mansour2005-06-01IEEE Transactions on Applied Superconductivity

In this paper, for the first time, we study the properties of a superconductive-based left-handed transmission line (SLHTL). The effect of the kinetic inductance on the propagation constant of the left-handed transmission line is analyzed. It is shown that increasing the kinetic inductance decreases both the bragg fre…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsMicrowave Engineering and Waveguides