Materials Literature
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Neutral Zn(II) [2×2] grids (M(4)L(4)) and a hexagon structure (M(6)L(6)) were, for the first time, synthesized using bis(dipyrrin)s and confirmed by X-ray diffraction analysis. The channel structures in the solid state result from several intermolecular noncovalent interactions.
Compositions based on REZn 1/2 Ti 1/2 O 3 –CaTiO 3 (RE=La and Nd), suitable for microwave (MW) applications have been developed by systematically doping the perovskite B site with Ta 2 O 5 , Al 2 O 3 , and MgO in order to tune the temperature coefficient of the resonant frequency (τ f ) and improve the MW quality fact…
Surface plasmon polaritons, as a surface electromagnetic wave, have plenty of features in the near-field zone. We find that not only localized SSPs but also magnetic plasmon resonance play a vital role in plasmonic electromagnetically induced transparency (EIT). Their interaction is investigated in detail by analyzing…
Abstract In this paper high efficiency (up to 15.8%) Mo/Cu(In,Ga)Se2/CdS/i‐ZnO solar cells terminated with an electrodeposited ZnO:Cl window layer are reported. The optoelectronic properties of these cells are comparable to reference cells terminated with standard sputtered ZnO:Al. The use of an electrochemical step,…
Two heteroarylene-vinylene donor−acceptor polymers, P(2,6-Py-V-EDOT) and P(2,5-Py-V-EDOT), containing vinylene-spaced simple donor (EDOT) and acceptor (pyridine) moieties, are presented. The central pyridine ring of the repeating unit is either 2,6- or 2,5-substituted, leading to different structural and electronic pr…
This paper presents the effects of postdeposition annealing temperatures (400, 600, 800, and 1000°C) in oxygen ambient on the metal-organic decomposed CeO2films spin coated on an n-type GaN substrate. The compositions, structures, and morphologies of these samples are revealed by X-ray diffraction (XRD), field-emissio…
Three novel pentamethine cyanine dyes with 3,5-dimethylpyridinium-1-yl and 4-benzylpyridinium-1-yl substituents in γ position of the methine chain were synthesized via a three-step procedure. The visible spectral behavior of these pentamethine cyanine dyes was examined in DMSO. Elemental analysis, IR, 1H-NMR, 13C-NMR,…
The extent of substituent influence on the vertical electron affinities (EAs) and ionization energies (IEs) of 43 substituted tria-, penta-, and heptafulvenes was examined computationally at the OVGF/6-311G(d)//B3LYP/6-311G(d) level of theory and compared with those of tetracyanoquinodimethane (TCNQ) and tetrathiafulv…
To assess effects of carbon nanoparticle (CNP) exposure on renal epithelial cells, fullerenes (C(60)), single-walled carbon nanotubes (SWNT), and multi-walled carbon nanotubes (MWNT) were incubated with a confluent renal epithelial line for 48 h. At low concentrations, CNP-treated cells exhibited significant decreases…
We report an experimental investigation of equilibrium shapes of epitaxial Au nanocrystals (NCs) supported on rutile ${\text{TiO}}_{2}(110)$ and the role of interfacial triple line energy (TLE). The study was enabled by aberration corrected electron microscopy; the significantly improved image resolution allows us to…
A study was performed to investigate the phylogenetic relationship among AAAH members and to statistically evaluate sequence conservation and functional divergence. In total, 161 genes were identified from 103 species. Phylogenetic analysis showed that well-conserved subfamilies exist. Exon-intron structure analysis s…
A novel fabrication process for the efficient incorporation of single-walled carbon nanotubes (SWCNT) into ZnO layers was developed, and this technique was used for constructing organic solar cells having a ZnO-based inverted structure with embedded SWCNTs. By SWCNT, significant enhancement in photovoltaic performance…
We investigate a two-orbital Anderson lattice model with Ising orbital intersite exchange interactions by means of dynamical mean field theory combined with the static mean field approximation of the intersite orbital interactions. Focusing on Ce-based heavy-fermion compounds, we examine the orbital crossover between…
The incoherent emission of periodically structured Light Emitting Diodes (LEDs) can be computed at relatively low computational cost by applying the reciprocity method. We show that by another application of the reciprocity principle, the structure of the LED can be optimized to obtain a high emission. We demonstrate…
Abstract Electric‐field‐induced hierarchical, multiscale patterning of incompletely cross‐linked viscoelastic polydimethylsiloxane (PDMS) films is achieved by spatiotemporal variation of the field, which produces a multiplicity of complex mesopatterns from the same electrode. Experiments and simulations are employed t…
Cationic phosphine-terminated rhenium(III) chalcogenide clusters—[Re 6 Se 8 (Et 3 P) 5 I]I, [Re 6 S 8 (Et 3 P) 5 Br]Br, [Re 6 Se 8 (Bu 3 P) 5 I]I, and [Re 6 S 8 (Bu 3 P) 5 Br]Br—were synthesized and encapsulated in silica nanospheres in a one-pot, base-catalyzed hydrolysis in acetonitrile. The cluster-doped silica nan…
We discuss the rigorous characterization of the electron density Laplacian of crystals in terms of its topological properties: critical points (CPs), zero flux surfaces, and accumulation and depletion basins. Comparison with the atomic shell structure is exploited to characterize the numerous core critical points so t…
A tandem polymerization strategy has been applied to the synthesis of novel core−shell soft nanoparticles having tunable thermosensitivity. These nanoparticles have amphiphilic dendritic core−shell structures, containing dendritic polyethylene (PE) as the hydrophobic core and a layer of poly(oligo((ethylene glycol) me…
One clinical precedent for the use of nanosized imaging agents is the localization of the tumor draining sentinel lymph nodes. In this application, radiocolloids such as (99m)Tc-NanoColl are currently used to plan the surgical procedure and to provide acoustic guidance during the intervention. Additional injections of…
Novel hybrid polymer hydrogels were prepared in a facile manner by simple mixing of a water-soluble copolymer having trimethoxysilyl side chains with silica nanoparticles used as multiple crosslinkers.