Materials Literature
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A facile route has been developed to synthesize nickel hydroxide nanocolumns at 60 °C. The characterized results show that the nanocolumns are formed by stacking of oriented Ni(OH) 2 nanosheets. The porous NiO nanocolumns and nanosheets are obtained by the Ni(OH) 2 nanocolumns annealed at 500 °C for 3 h. The NiO nanoc…
MOTIVATION: The Protein Data Bank (PDB) contains over 43,800 experimentally determined 3D models of macromolecular structures and their complexes. Each 3D model reveals something interesting and important about the given molecule's function and biological significance. Usually the best source of this information is th…
In this Article, we have investigated the self-assembly of a series of amphiphilic hyperbranched star-block copolymers to form multicompartment micelles in acidic aqueous solution (pH 3.0) or in a dimethylformamide/water (pH 3.0) mixture. These hyperbranched star-block copolymers were prepared via oxyanion-initiated p…
Triblock rigid-flexible dendritic block molecules consisting of a rigid aromatic segment as a stem segment, carbohydrate-branched dendrons as a flexible head, and a hydrophobic alkyl chain were synthesized and characterized. The carbohydrate conjugate molecule based on a methyl group as a hydrophobic tail, in the soli…
Within the framework of a generalized Ising model, a one-dimensional magnetic of a finite length with free ends is considered. The correlation length exponent, dynamic critical exponent z of the magnet is calculated taking into account the next nearest neighbor interactions and the external field.
Two synthetic methods of meso-aryl-substituted subporphyrins have been developed by means of the reaction of pyridine-tri-N-pyrrolylborane with a series of aryl aldehydes. One method relies on the condensation under Adler conditions with chloroacetic acid in refluxing 1,2-dichlorobenzene to afford subporphyrins in 1.1…
We have fabricated polymer semiconductor thin-film transistors using an ion gel (ionic liquid plus triblock copolymer) as the gate dielectric layer. The gate capacitance of the ion gel can be as large as 40 μF/cm 2 at 10 Hz and 2 μF/cm 2 at 1 kHz. In addition, the polarization response time of the ion gel is much fast…
Weiche Platindrähte lassen sich durch Verknüpfung amphiphiler Alkinplattformen mit planaren Pt II ‐Terpyridin‐Einheiten herstellen. Das Titelbild zeigt Fasern, die durch Stapeln solcher Komplexe über Pt⋅⋅⋅Pt‐ und π–π‐Wechselwirkungen gebildet werden. Man erhält dunkelgrüne Gele und flüssigkristalline Materialien mit P…
We investigate a single defect coupling to the square of the order parameter in a nearly critical magnet with long-range spatial interactions of the form ${r}^{\ensuremath{-}(d+\ensuremath{\sigma})}$, focusing on magnetic droplets nucleated at the defect while the bulk system is in the paramagnetic phase. To determine…
We study the new characteristic gapless charge ordered state in a spinless fermion system on a triangular lattice under strong inter-site Coulomb interactions. In this state the charges are spontaneously divided into solid and liquid components, and the former solid part aligns in a Wigner crystal manner while the lat…
Abstract Silicon wafers produced from the silicon single crystals are the basic material for the manufacturing of various kinds of electronic devices determining the everyday life of the modern society. Silicon single crystals industrially are mainly grown by two methods ‐ by the Czochralski and by the floating zone t…
The authors of this Communication recently noted that a key word in a sentence in their publication appeared incorrectly. Thus, the penultimate sentence in the penultimate paragraph on page 2369 should read: Hence, it is safe to conclude that the number of nanocrystals (nuclei) formed in the initial nucleation stage i…
Die Autoren bemerkten kürzlich einen sinnverändernden Fehler in dieser Zuschrift. Der vorletzte Satz des vorletzten Abschnitts auf S. 2475 muss lauten: “Hence, it is safe to conclude that the number of nanocrystals (nuclei) formed in the initial nucleation stage increased significantly with decreasing initial oleic ac…
The authors have measured the contribution of CO adsorbed on different bonding sites to the resistivity of epitaxial Cu(100) films. Through an analysis of the correlation between surface resistivity and temperature-programed desorption measurements, CO on terraces is found to affect the resistance much more strongly t…
The cluster {(Mo)Mo5}12Fe(III)30 1 a present in compound 1 (cluster diameter approximately 2.3 nm), which belongs to the family of nanoscale spherical porous {(Mo)Mo5}12{Linker}30 capsules that allow a new type of nanochemistry inside their cavities as well as unprecedented aggregation processes under gaseous, solutio…
Five local clays were characterised by several physicochemical methods to predict their pozzolanic reactivity. The studied samples were treated thermally at 600, 700 and 800°C. The heat-treated samples were characterised by X-ray diffraction. The pozzolanic activity was assessed by chemical (Chappelle test), mechanica…
We report inelastic light scattering experiments on FeCr 2 S 4 , which shows colossal magnetoresistance (CMR) effects around T C ≈170 K. Several distinct features have been observed: (i) anomalies in phonon frequencies and linewidths around T C , (ii) the vanishing of one-magnon excitation close to 0.83 T C , and (iii…
By the reaction of new donor molecules, bis(ethylenedithio)tetrathiafulvalenoquinone(-thioquinone)-1,3-dithiolemethides [BEDT-TTFVO (1) and BEDT-TTFVS (2)] with FeX3 (X = Cl, Br) in CS2/CH3CN, 1:1 salts of 1 or 2 with an FeX4- ion (1.FeX4 and 2.FeX4) were obtained as black needle crystals. Their crystal structures are…
The dependence of the optical properties of [C(12)H(12)N(4)O(2)AgPF(6)](2) (dimer-1) and [C(28)H(28)N(6)O(3)AgPF(6)](2) (dimer-2) on the arrangement of the oxime moieties in the molecule and in bulk crystals was investigated by means of time-dependent density functional theory. Dimer-1 with simple pyridine oxime ligan…
Bovine serum albumin (BSA) was reacted with linear and newly synthesized branched oligothiophene N-hydroxysuccinimidyl ester fluorophores (TSEs) in moderately basic carbonate buffer solution. Optically stable BSA-TSE conjugates were obtained with a degree of labeling depending on experimental conditions. Conjugates wi…