Materials Literature
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The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxidation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 p…
Elastin synthesis and physiologic compliance are significant challenges in blood vessel tissue engineering. Here, we report that a biocompatible elastomeric scaffold can support the co-expression of elastin and collagen, which likely yielded the physiologic compliance in the constructs. A biodegradable elastomer, poly…
We report on charge separation between type II aligned CdTe and CdSe nanocrystals. Two types of electrostatically bound nanocrystal structures have been studied: first, clusters of nanocrystals hold together by Ca(II) ions in aqueous solution and, second, thin film structures of nanocrystals created with layer-by-laye…
The electronic structure of cuprite $({\mathrm{Cu}}_{2}\mathrm{O})$ has been studied by high-resolution x-ray photoemission (XPS), x-ray absorption (XAS), and resonant x-ray emission spectroscopies (XES) supported by band structure calculations using a hybrid exchange approximation to density functional theory. A pron…
Amorphous Si1−xCx/SiC multilayer films were prepared by alternating deposition of Si-rich Si1−xCx and near-stoichiometric SiC layers by using magnetron sputtering. The as-deposited films were annealed at different temperatures (Ta) from 800 to 1100 °C. The influence of Ta and Si content in the Si-rich layer on the lay…
Abstract The impact of the preparation and thermal history on the dynamic glass transition in thin films of poly(methyl methacrylate) and poly(vinyl acetate) is systematically investigated by means of broadband dielectric spectroscopy. Metastable states of glassy dynamics are detected, exhibiting shifts in the mean‐re…
We study boron-doped single-walled carbon nanotubes by using first-principles methods based on the density functional theory. The total energy, band structure, and density of states are calculated. From the formation energy of boron-doped nanotubes with different diameters, it is found that a narrower tube needs a sma…
Abstract The synthesis and properties of two closely related boron dipyrromethene (BODIPY) derived dyads, incorporating redox‐active quinone units appended at the meso position, are described. For one dyad, the quinone unit is attached directly to the BODIPY core, whereas a phenylene spacer separates the two units in…
Magnetic functionalization of the ordered mesoporous SBA-15 (SiO 2 ) aggregate blocks and rice grain-like particles were realized by using a sol−gel method, resulting in the formation of Fe x O y @SBA-15 composite materials. The X-ray diffraction (XRD), N 2 adsorption/desorption, and transmission electron microscopy (…
Two sandwich-type complexes Na9n(Cu(im)4(H2O)2)1.5n(Cu(im)4(H2O))n[{Cu(im)4}{Na(H2O)2}3{Cu3(im)2(H2O)}(XW9O33)2]2n .(xH2O)n (im=imidazole, X=Bi (1), Sb(2), x=42.5 (1), 40 (2)) have been synthesized and structurally characterized. Basic frameworks of 1 and 2 are built from sandwich-type [{Na(H2O) 2} 3{Cu3(im)2(H2O)}(XW…
Abstract The embedding of nanoscopic metal structures into polymeric matrices represents a convenient way to stabilise a controlled dispersion of protected nanoparticles whilst taking advantage of their physical characteristics. Supercritical carbon dioxide (scCO 2 ) has been used to produce silver nanoparticles in op…
The structure and oxidation state of self-assembled nanostructures formed by oxidation of aniline with ammonium persulfate in the presence of alanine have been investigated by solid-state 13 C and 15 N NMR, FTIR, GPC, elemental, UV−vis, and SEM methods. These techniques have been applied to samples obtained 1 and 20 h…
BACKGROUND: It is expected that prolonged circulation of anticancer drugs will increase their anticancer activity while decreasing their toxic side effects. The purpose of this study was to prepare 5-fluorouracil (5-FU) loaded block copolymers, with poly(gamma-benzyl-L-glutamate) (PBLG) as the hydrophobic block and po…
Uniaxial plastic deformation of polycrystalline Cu with grain sizes in the range of 5--20 nm was studied by using molecular dynamics computer simulations. We developed a quantitative analysis of plasticity by using localized slip vectors to separate the contributions of dislocation activity from grain boundary sliding…
The dynamics of water confined in silica matrices MCM-41 C10 and C18, with pore diameter of 21 and 36 A, respectively, is examined by broadband dielectric spectroscopy (10(-2)-10(9) Hz) and differential scanning calorimetry for a wide temperature interval (110-340 K). The dynamics from capillary condensed hydration wa…
Many types of clay tend to absorb organics via electron transferring interactions between the clay and the organics. This may be utilized to design clay incorporated polymer composites with better interfacial properties. In the present paper, 2,5-bis(2-benzoxazolyl) thiophene (BBT), capable of donating electrons, is s…
Electrospun fibers that are protein resistant and functionalized with bioactive signals were produced by solution electrospinning amphiphilic block copolymers. Poly (ethylene glycol)-block-poly(D,L-lactide) (PEG-b-PDLLA) was synthesized in two steps, with a PEG segment of 10 kDa, while the PDLLA block ranged from 20 t…
The importance of anisotropy in the optical response of metal nanoparticles of different end shapes is studied theoretically. The number, behavior, and localization of the plasmon modes in terms of the shape and elongation is revised in detail for silver, gold, and copper nanoparticles. It is found that the position o…
Abstract Carbohydrate‐sensitive polymer multilayers are assembled onto flat substrates and colloidal CaCO 3 particles via reversible covalent ester formation between the polysaccharide mannan and phenylboronic acid moieties grafted onto poly(acrylic acid) (PAA). The resulting multilayer films are sensitive to several…
Nonmetallic left-handed material by assembly of low-dimensional quantum structures is theoretically proposed. Specifically, we predict relatively wideband, tunable left-handed material by employing structures comprised of semiconductor quantum wells and quantum dots. Well established epitaxial growth of semiconductor…