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A new Schiff base as a bridge in binuclear cobalt(III) dioximate

O. Ciobanică、Paulina Bourosh、Vasile Lozan 等 5 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Ni(CN) 2 -CN-] n with trans-positioned bridging cyanide ligands in both cation and anion. The water molecules of crystallization are located between the chains and link them by hydrogen bonds. In the crystal structure of 4 the chains are built up of [Ni(cyclam)] 2+ cations linked by cyanide anions solely; as a consequ…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Refinement of structural parameters of PbTiO3by convergent-beam electron diffraction

Roland Schierholz、Kenji Tsuda、Hartmut Fuess2010-08-29Acta Crystallographica Section A Foundations of Crystallography

The purpose of the present work is to reveal around Kikuchi lines the temperature diffuse scattering maximums which, to our knowledge, have not been observed before. As specimen for investigations were single crystalline silicon films prepared by chemical etching of bulk crystals. The transmission electron diffraction…

X-ray Diffraction in CrystallographyFerroelectric and Piezoelectric MaterialsElectronic and Structural Properties of Oxides

Understanding the structures of complex cubic intermetallic phases

Julia Dshemuchadse、Daniel Y. Jung、W. Steurer2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Although Complex Metallic Alloy phases (CMAs) are known since the beginning of the last century, they have long been considered as rare and special cases of intermetallic compounds.Recent phase diagram studies using state of the art techniques have shown that CMAs occur frequently not only in multinary but also in bin…

Intermetallics and Advanced Alloy PropertiesMetallurgical and Alloy Processes

Monitoring the preparation of protein derivative crystalsviaRaman microscopy

Alessandro Vergara2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Raman microscopy is having increasing applications into molecular biology. Primary structure features can be analyzed, such as Se-Met labeled protein crystals to be used for MAD crystallography Secondary structure modification can be clearly identified according to relationships between amide band frequencies and Rama…

Enzyme Structure and Function

Crystallographic orientation relationship between bastnaesite, fluocerite and cerianite in a single crystal from the Pikes Peak pegmatites

Mathis M. Müller、Hans‐Joachim Kleebe2010-08-29Acta Crystallographica Section A Foundations of Crystallography

A fluocerite (Ce,La)F3 single crystal intergrown with bastnaesite (Ce,La)[CO3]F from the Pikes Peak area in Colorado, USA was prepared for the investigation of the crystallographic orientation relationship between the two mineral phases via transmission electron microscopy.The epitactical overgrowth of bastnaesite on…

Geological and Geochemical AnalysisCrystal Structures and PropertiesMineralogy and Gemology Studies

Mullite-type (Bi1−xSrx)2Al4O9−x/2: HT-XRPD, TEM and XPS investigations

Thorsten M. Gesing、Marco Schowalter、Claudia Weidenthaler 等 6 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

It is well known that metal dusting is an undesirable corrosion phenomenon that can be observed in a wide range of chemically and petrochemically working industries.Due to strongly carburizing atmospheres, it leads to a decomposition of materials into metal particles and carbon.The aim of this work is to clarify open…

Nuclear materials and radiation effectsFerroelectric and Piezoelectric MaterialsX-ray Diffraction in Crystallography

Elastic and non-elastic response of shape memory alloys to stress fields

Wolfgang W. Schmahl、S. Gollerthan、Marcus L. Young 等 10 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

It is convenient to consider a change in the structure of crystalline material as a reason for remarkable modifications in its physical properties: a structural phase transition often results in the anomalous behaviour of macroscopic parameters in condensed matter. However, is it always true that a detected change in…

Shape Memory Alloy Transformations

Complexation properties of completely reducedmeso-octamethylporphyrinogens (calix[4]pyrroles)

H. Stoeckli‐Evans、Guillaume Journot、Frédéric Bruyneel 等 4 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Odorants are low-boiling compounds such as esters, ketones or ethers [1].Their structures in the gas phase may be studied by microwave spectroscopy [2].Odorants are active in condensed phase, and hence their solid-state structures are of interest, too.In addition to in situ crystallization [3], one can imagine two alt…

Porphyrin and Phthalocyanine ChemistryDNA and Nucleic Acid ChemistryMolecular Sensors and Ion Detection

Upside-down protein crystallization

Naomi E. Chayen、Sahir Khurshid2010-08-29Acta Crystallographica Section A Foundations of Crystallography

TiO 2 (rutile modification), space group (136) P4 2 /mnm, carried out in the vicinity of the Ti-K absorption edge. The influence of oxygen vacancies on the anomalous scattering signal (see e.g. [2]) has been studied on a series of 10 x 10 x 1 mm 3 single crystal wafers of different vacancy concentrations obtained by a…

Enzyme Structure and FunctionMass Spectrometry Techniques and Applications

Structural trends in the (emim)m[An(Mo8O26)] (emim = 1-ethyl-3-methylimidazolium;m= 2, 3;n= 1, 2;A= K, Rb, Cs) group of compounds

Anna Pakhomova、Sergey V. Krivovichev2010-08-29Acta Crystallographica Section A Foundations of Crystallography

A fluocerite (Ce,La)F3 single crystal intergrown with bastnaesite (Ce,La)[CO3]F from the Pikes Peak area in Colorado, USA was prepared for the investigation of the crystallographic orientation relationship between the two mineral phases via transmission electron microscopy. The epitactical overgrowth of bastnaesite on…

Polyoxometalates: Synthesis and ApplicationsOrganometallic Compounds Synthesis and CharacterizationMetal-Organic Frameworks: Synthesis and Applications

Metastable Bi2O3polymorphs obtained by high pressure and high temperature

T. Locherer、Stefan Ghedia、Anatoliy Senyshyn 等 6 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

preferred orientation of the ferroelectric domains accompanied by a macroscopic polarization. In PZT highest piezoelectric response is found at the morphotropic phase boundary (MPB), separating a rhombohedral structure, in which the polarization is along the [111] c direction, from a tetragonal structure, in which the…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Electronic carbon-nanotube-based materials for protein crystallization

Naomi E. Chayen、Lata Govada、Piyapong Asanithi 等 10 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Page s294 s294TiO 2 (rutile modification), space group (136) P4 2 /mnm, carried out in the vicinity of the Ti-K absorption edge.The influence of oxygen vacancies on the anomalous scattering signal (see e.g.[2]) has been studied on a series of 10 x 10 x 1 mm 3 single crystal wafers of different vacancy concentrations o…

Mechanical and Optical ResonatorsCarbon Nanotubes in CompositesCalcium Carbonate Crystallization and Inhibition

RAPIDO - a web server for the rapid alignment of protein structures in the presence of domain motions

Fabio Dall’Antonia、Roberto Mosca、T. Schneider2010-08-29Acta Crystallographica Section A Foundations of Crystallography

For many years computer processors have been getting faster, which has meant that by upgrading hardware, software would run faster without any modifications. This is now beginning to change. Processor speeds are reaching a plateau, so manufacturers have instead begun to increase the computation power available by addi…

Protein Structure and DynamicsEnzyme Structure and FunctionGenomics and Phylogenetic Studies

The crystal structure of a mixed-metal basic trifluoroacetate of aluminium and zinc: [AlZn(μ4-O(O2CCF3)3]4

Georgi Z. Genchev、Walter Frank2010-08-29Acta Crystallographica Section A Foundations of Crystallography

M 4 X 4 molecular cages where M is a metal and X is an element of group 15, 16 or 17 are quite common All these cages have the cube geometry as found in the well known Fe 4 S 4 ferredoxins Here we report on the synthesis and the crystal structure of [AlZn( 4 -O)(O 2 CCF 3 ) 3 ] 4 (1). This exceptional compound was dis…

Silicone and Siloxane ChemistryMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related Compounds

Simulation of modulated reflections

Jeffrey J. Lovelace、Martyn Winn、Gloria E. O. Borgstahl2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Multifunctional ferromagnetic shape memory Heusler Ni-Mn-Ga alloys are frequently characterized by structural modulation in martensitic phases.In particular, modulated martensitic phases, showing the higher magnetic field induced strain performance, are the most promising candidates for technological applications.Depe…

Crystallization and Solubility StudiesProtein Structure and DynamicsEnzyme Structure and Function

Experimental and DFT studies on a pyrimidine-thione derivative

Muharrem Di̇nçer、Namık Özdemir、İrfan Koca 等 4 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Page s131 on protein size, secondary structure and overall conformation will be presented. The characterization of the solution structure and oligomerization state of the Arabidopsis gamma subunit is novel and important contribution to studies on Gproteins providing insights also for the mammalian proteins [1]

Nonlinear Optical Materials Research

Diffuse neutron scattering in high-temperature phase of relaxor PbMg1/3Nb2/3O3

R. G. Burkovsky、S. B. Vakhrushev、Kazuma Hirota 等 4 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Page s214 s214follows that the width of the diffraction maximum in reciprocal space is proportional to the square root of the dislocation density, however the shape of the maximum strongly depends on the correlation of dislocation positions.The results were compared with dislocation curves obtained from the standard a…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisThermoelastic and Magnetoelastic Phenomena

Al/Si-ordering phenomena in sanidine megacrystals from the Eifel

Kathrin Demtröder、Sara Dehn、Michael Gopon 等 4 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

residual ash is enriched in silica and applied as a good adsorbent material for heavy metals The capture of carbon dioxide and other smoke gases from the biomass burning can be vitally achieved through hot manganese oxide at 200-250 o C. The gases change the mineralogical composition of the applied manganese oxides or…

Phase-change materials and chalcogenidesQuasicrystal Structures and PropertiesSolidification and crystal growth phenomena

Dual polarization interferometry in macromolecular crystallisation diagnostics

Emmanuel Saridakis、Attia Boudjemline、Marcus J. Swann 等 5 位作者2010-08-29Acta Crystallographica Section A Foundations of Crystallography

Dual Polarization Interferometry (DPI) is a waveguide based interferometer technique, which is well established for the characterisation of surface layers. This method allows the correlation of changes in refractive index to the thickness and density of surface layers immediately above a waveguide surface. It has ther…

Advanced Scientific Research Methodsthermodynamics and calorimetric analysesEnzyme Structure and Function