Materials Literature
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Abstract The demand for improved properties of common polymers keeps increasing, and several new approaches have been investigated. In the study reported here, composites with a polymer matrix comprising a blend of high‐density polyethylene with ethylene–vinyl acetate copolymer (EVA), and with polyhedral oligomeric si…
BACKGROUND: Enteric coating prevents oral dose forms from being digested in the stomach, which is required for drugs that are acid unstable, have an irritant effect on the stomach, or are designed to act in the small intestine. AIM: The objective of this study was to develop a novel gastroresistant delayed-release tab…
We describe neutron-scattering experiments performed to investigate the magnetic order and dynamics of half-doped ${\text{La}}_{1.5}{\text{Sr}}_{0.5}{\text{CoO}}_{4}$. This layered perovskite exhibits a near-ideal checkerboard pattern of ${\text{Co}}^{2+}/{\text{Co}}^{3+}$ charge order at temperatures below $\ensurema…
Silver galvanic displacement on silicon has been employed to produce large-area reproducible substrates, with morphology similar to that of the natural desert rose but on the micrometer scale. The process is based on an extremely simple wet chemistry approach using only AgF and KF, as silver and fluoride sources. A ke…
We report direct observation of the lowest two states of the band-edge exciton fine structure in the photoluminescence from single CdSe/ZnS core/shell nanocrystals at cryogenic temperatures. The temperature dependence of this spectral fingerprint reveals exciton spin relaxation rates as low as 10 micros(-1). The fine…
Superhydrophobic nanosheet assemblies of polymerized n-octadecylsiloxane (PODS) were obtained on glass using n-octadecyltricholorsilane (OTS) as a starting material and acetone as the extracting agent. The coating layers were characterized by infrared spectroscopy, X-ray diffractometry, X-ray photoelectron spectroscop…
Abstract The growth of a new nonlinear optical material L‐valine by solvent evaporation method is reported here. To grow good quality crystals pH value of growth solution has been optimized and solubility of L‐valine in different solvents and different pH values was determined. The grown crystals were characterized by…
The thickness and origin of the free charge layer which forms at the LaAlO_{3}/SrTiO_{3} interface is still uncertain. By inserting Mn dopants at different distances from the interface we can locate the position of carriers within the SrTiO3 surface layers. We show that the majority of the carriers in fully-oxygenated…
The ligands−assisted rational design of a Eu 3+ -containing organic−inorganic hybrid (di-ureasil) displaying the highest emission quantum yield (0.60 ± 0.06) reported so far is introduced. Two new lanthanide complexes were synthesized in which the metal (Eu 3+ or Gd 3+ ) first coordination sphere is formed by three β-…
In this paper we studied the metal-enhanced emission from long-lifetime lanthanide dyes that were encapsulated in the silver nanoshells. The metal nanoshells were synthesized with the silica spherical cores of 50 nm diameters and the silver shells of 5 - 60 nm. The optical properties of luminescent metal shells were p…
Micrometer-sized, monodisperse dimple and hemispherical polystyrene (PS) particles were successfully prepared by heating (55-70 degrees C) of spherical PS particles dispersed in methanol/water media (40/60 to 80/20, w/w) in the presence of decane droplets, and subsequent cooling down to room temperature. Decane was ab…
An efficient and metal-free oxidative method was reported for synthesis of triply linked diporphyrins with 2.5 equiv of phenyliodine bis(trifluoroacetate) (PIFA). This reaction showed high selectivity for Zn(II) porphyrins and had been successfully applied in the synthesis of a novel triply-singly interlacedly linked…
The main limitation of contemporary anticancer chemotherapy remains to be the insufficient specificity of the drugs for tumor tissue, which decreases the maximum tolerated dose due to severe side effects. Micellar drug delivery systems based on amphiphilic block copolymers with a very narrow size distribution (10 to 1…
The possible existence of a new kind of ferroelectric order and the need to explore domain arrangement in ferroelectric nanostructures has stimulated an increasing activity on the growth of ferroelectric nanowires. In the present study, single crystal BaTiO 3 nanowires with tetragonal structure were obtained by an ori…
A metallodendron functionalized with dicyclohexyldiphosphino palladium complex was synthesized. The metallodendron was grafted onto core-shell superparamagnetic nanoparticles (gamma-Fe(2)O(3)/polymer, 200-500 nm) to give optimal catalytic reactivity in cross-coupling reactions. The grafted nanoparticles were used as r…
A composite methodology using laser ablation followed by a solution refluxing process was demonstrated to prepare GaOOH and (β-, γ-) Ga2O3 nanowires, where GaOOH and γ-Ga2O3 nanowires were prepared for the first time. The CTAB surfactant and PVP polymer facilitated the nucleation and growth of GaOOH nanorods, and play…
The effect of partial autolysis during storage of shrimp biowaste on the quality of the extracted chitin and chitosan has been investigated. Shrimp waste materials were stored in a 30 o C incubator for 1-4 days. The quality of the chitin and chitosan extracted from these materials was assessed by ash and protein analy…
Poly[2-(methacryloyloxy)ethyl phosphorylcholine] -modified gold surfaces, which have been newly prepared by a 'grafting to' method using a series of monosulfanyl-terminated PMPC, are characterized by protein adsorption experiments based on surface plasmon resonance spectroscopy and ellipsometry measurements. The exten…
We report the investigation of electron transport through a four-terminal graphene-superconductor hybrid system. Because of the quantum interference of the reflected holes from two graphene-superconductor interfaces with a phase difference theta, it is found that the specular Andreev reflection vanishes at theta=0 whi…
We have investigated the role of formate (HCOO), carbonate (CO 3 ), and carboxyl (HOCO) species as possible intermediates in the OH ads + CO gas → CO 2,gas + 0.5H 2,gas reaction on Au(111) using synchrotron-based core level photoemission, near-edge X-ray absorption fine structure (NEXAFS), and infrared absorption spec…