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Separation of C5-Hydrocarbons on Microporous Materials: Complementary Performance of MOFs and Zeolites

M. Maes、Luc Alaerts、Frederik Vermoortele 等 8 位作者2010-02-01Journal of the American Chemical Society

This work studies the liquid-phase separation of the aliphatic C(5)-diolefins, mono-olefins, and paraffins, a typical feed produced by a steam cracker, with a focus on the seldomly studied separation of the C(5)-diolefin isomers isoprene, trans-piperylene, and cis-piperylene. Three adsorbents are compared: the metal-o…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Nonlinear oscillation of a dielectric elastomer balloon

Jian Zhu、Shengqiang Cai、Zhigang Suo2010-02-01Polymer International

Abstract Much of the existing literature on dielectric elastomers has focused on quasi‐static deformation. However, in some potential applications, the elastomer deforms at high frequencies and undergoes nonlinear oscillation. While nonlinear oscillation has been studied in many areas of science and engineering, we ar…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Resistance-dependent amplitude of random telegraph-signal noise in resistive switching memories

Daniele Ielmini、F. Nardi、C. Cagli2010-02-01Applied Physics Letters

Resistive-switching memory (RRAM) is attracting a considerable interest for the development of high-density nonvolatile memories. However, several scaling and reliability issues still affect the development path of RRAM. This work addresses random telegraph-signal noise (RTN) of the RRAM current, potentially affecting…

Advanced Memory and Neural ComputingElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

What Do We Really Know about Cellulose Biosynthesis in Higher Plants?

Gea Guerriero、Johanna Fugelstad、Vincent Bulone2010-02-01Journal of Integrative Plant Biology

Cellulose biosynthesis is one of the most important biochemical processes in plant biology. Despite the considerable progress made during the last decade, numerous fundamental questions related to this key process in plant development are outstanding. Numerous models have been proposed through the years to explain the…

Advanced Cellulose Research StudiesPolysaccharides and Plant Cell WallsPlant nutrient uptake and metabolism

The packing properties of superellipsoids

Gary W. Delaney、Paul W. Cleary2010-02-01Europhysics Letters (EPL)

We investigate the properties of packings of frictionless non-spherical particles utilizing a dynamic particle expansion technique. We employ superquadric particles (superellipsoids), which allows us to explore how a broad range of particle shapes affect both the macroscopic and the local configurational properties of…

Material Dynamics and PropertiesGranular flow and fluidized bedsPickering emulsions and particle stabilization

Role of Ceria in Oxidative Dehydrogenation on Supported Vanadia Catalysts

M. V. Ganduglia-Pirovano、Cristina Popa、Joachim Sauer 等 10 位作者2010-02-01Journal of the American Chemical Society

The effect of the suppport on oxidative dehydrogenation activity for vanadia/ceria systems is examined for the oxidation of methanol to formaldehyde by use of well-defined VO(x)/CeO(2)(111) model catalysts. Temperature-programmed desorption at low vanadia loadings revealed reactivity at much lower temperature (370 K)…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

A 64Mb MRAM with clamped-reference and adequate-reference schemes

Kenji Tsuchida、Tsuneo Inaba、K. Fujita 等 16 位作者2010-02-01OpenAlex

A 64 Mb spin-transfer-torque MRAM in 65 nm CMOS is developed. A 47 mm2die uses a 0.3584 ¿m2cell with a perpendicular-TMR device. To achieve read-disturb immunity for the reference cell, a clamped-reference scheme is adopted. An adequate-reference scheme is implemented to suppress read-margin degradation due to the res…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsFerroelectric and Negative Capacitance Devices

Accurate Estimate of the Critical Exponent ν for Self-Avoiding Walks via a Fast Implementation of the Pivot Algorithm

Nathan Clisby2010-02-01Physical Review Letters

We introduce a fast implementation of the pivot algorithm for self-avoiding walks, which we use to obtain large samples of walks on the cubic lattice of up to 33x10{6} steps. Consequently the critical exponent nu for three-dimensional self-avoiding walks is determined to great accuracy; the final estimate is nu=0.587…

Protein Structure and DynamicsTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Long-term performance of a plant microbial fuel cell with Spartina anglica

R.A. Timmers、David P. B. T. B. Strik、H.V.M. Hamelers 等 4 位作者2010-02-01Applied Microbiology and Biotechnology

The plant microbial fuel cell is a sustainable and renewable way of electricity production. The plant is integrated in the anode of the microbial fuel cell which consists of a bed of graphite granules. In the anode, organic compounds deposited by plant roots are oxidized by electrochemically active bacteria. In this r…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsMicrobial Fuel Cells and Bioremediation

Origins of Elasticity in Intermediate Filament Networks

Yi‐Chia Lin、Norman Y. Yao、Chase P. Broedersz 等 6 位作者2010-02-01Physical Review Letters

Intermediate filaments are common structural elements found in abundance in all metazoan cells, where they form networks that contribute to the elasticity. Here, we report measurements of the linear and nonlinear viscoelasticity of networks of two distinct intermediate filaments, vimentin and neurofilaments. Both exhi…

Cellular Mechanics and InteractionsPolymer Surface Interaction StudiesSkin and Cellular Biology Research

Solar‐Energy Production and Energy‐Efficient Lighting: Photovoltaic Devices and White‐Light‐Emitting Diodes Using Poly(2,7‐fluorene), Poly(2,7‐carbazole), and Poly(2,7‐dibenzosilole) Derivatives

Serge Beaupré、Pierre‐Luc Boudreault、Mario Leclerc2010-02-01Advanced Materials

World energy needs grow each year. To address global warming and climate changes the search for renewable energy sources with limited greenhouse gas emissions and the development of energy-efficient lighting devices are underway. This Review reports recent progress made in the synthesis and characterization of conjuga…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Enhancement of fruit shelf life by suppressing N -glycan processing enzymes

Vijaykumar S. Meli、Sumit Ghosh、Thangavelu Prabha 等 6 位作者2010-02-01Proceedings of the National Academy of Sciences

In a globalized economy, the control of fruit ripening is of strategic importance because excessive softening limits shelf life. Efforts have been made to reduce fruit softening in transgenic tomato through the suppression of genes encoding cell wall-degrading proteins. However, these have met with very limited succes…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingPlant Gene Expression Analysis

Beating the Walker Limit with Massless Domain Walls in Cylindrical Nanowires

Ming Yan、Attila Kákay、Sebastian Gliga 等 4 位作者2010-02-01Physical Review Letters

We present a micromagnetic study on the current-induced domain-wall motion in cylindrical Permalloy nanowires with diameters below 50 nm. The transverse domain walls forming in such thin, round wires are found to differ significantly from those known from flat nanostrips. In particular, we show that these domain walls…

Physics of Superconductivity and MagnetismMagnetic properties of thin filmsMagnetic Properties and Applications

Three-Dimensional Molecular Theory of Solvation Coupled with Molecular Dynamics in Amber

Tyler Luchko、Sergey Gusarov、Daniel R. Roe 等 7 位作者2010-02-01Journal of Chemical Theory and Computation

We present the three-dimensional molecular theory of solvation (also known as 3D-RISM) coupled with molecular dynamics (MD) simulation by contracting solvent degrees of freedom, accelerated by extrapolating solvent-induced forces and applying them in large multi-time steps (up to 20 fs) to enable simulation of large b…

Protein Structure and DynamicsEnzyme Structure and FunctionAdvanced NMR Techniques and Applications

Interpretation of admittance, capacitance-voltage, and current-voltage signatures in Cu(In,Ga)Se2 thin film solar cells

Tobias Eisenbarth、Thomas Unold、Raquel Caballero 等 5 位作者2010-02-01Journal of Applied Physics

A series of Cu(In,Ga)Se2 (CIGS) thin film solar cells with differently prepared heterojunctions has been investigated by admittance spectroscopy, capacitance-voltage (CV) profiling, and temperature dependent current-voltage (IVT) measurements. The devices with different CdS buffer layer thicknesses, with an In2S3 buff…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsSemiconductor materials and interfaces

Equilibrium Study of Protein Denaturation by Urea

Deepak R. Canchi、Dietmar Paschek、Angel E. Garcı́a2010-02-01Journal of the American Chemical Society

Though urea is commonly used to denature proteins, the molecular mechanism of its denaturing ability is still a subject of considerable debate. Previous molecular dynamics simulation studies have sought to elucidate the mechanism of urea denaturation by focusing on the pathway of denaturation rather than examining the…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Antitumor Effect of Plasma Treatment on U87 Glioma Xenografts: Preliminary Results

Marc Vandamme、Éric Robert、Sabrina Pesnel 等 9 位作者2010-02-01Plasma Processes and Polymers

Abstract This work was conducted to evaluate the potential antitumor effect of an in vivo plasma treatment on a U87‐luc glioma tumor. A pulsed DBD with µs pulses at moderate power was used for treatment. Electrical analyses and spectroscopic measurements were realized to characterize plasma properties. We showed that…

Silicon Nanostructures and PhotoluminescenceNeuroscience and Neural Engineeringbioluminescence and chemiluminescence research

Biopharmaceutical Parameters to Consider in Order to Alter The Fate of Nanocarriers After Oral Delivery

Emilie Roger、Frédéric Lagarce、Emmanuel Garcion 等 4 位作者2010-02-01Nanomedicine

Oral route is the most common route for the delivery of drugs because it is simple to implement and improves patient compliance and quality of life. However, oral absorption is limited by various physiological barriers and remains a scientific challenge. Nanometric-sized drug delivery systems are being extensively stu…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

Biopolymeric nanoparticles

Sushmitha Sundar、Joydip Kundu、Subhas C. Kundu2010-02-01Science and Technology of Advanced Materials

This review on nanoparticles highlights the various biopolymers (proteins and polysaccharides) which have recently revolutionized the world of biocompatible and degradable natural biological materials. The methods of their fabrication, including emulsification, desolvation, coacervation and electrospray drying are des…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesElectrohydrodynamics and Fluid Dynamics

Graphene mode-lockers for fiber lasers functioned with evanescent field interaction

Yong‐Won Song、Sung‐Yeon Jang、Won-Suk Han 等 4 位作者2010-02-01Applied Physics Letters

Employing graphene as an intracavity passive power modulating element, we demonstrate the efficient laser pulsation in high pulse-energy regime with evanescent field interaction between the propagating light and graphene layer. Graphene is prepared by the solution based reduction of graphene oxide, and dispersed homog…

Diamond and Carbon-based Materials ResearchLaser-Matter Interactions and ApplicationsAdvanced Fiber Laser Technologies