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Verification of Selective Adsorption of Polymer on Filler Surface in a Binary Immiscible Polymer Solution Blend Based on Nanoconfinement: Changing the Aggregate Structure and the Surface Character of Carbon Black

Masayuki Kawazoe、Hatsuo Ishida2009-07-27Macromolecules

The limiting cause of nanoconfinement of rubber molecules for their selective adsorption onto filler surface has been examined by changing: (1) the void size of carbon black aggregates, (2) the atomic scale roughness and chemical character of carbon black surface, and (3) the kind of filler from carbon black to silica…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

A numerical study of projectile impact on thin aluminium plates

M Raguraman、Anindya Deb、G. Jagadeesh2009-07-27Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

This article deals with a simulation-based study of the impact of projectiles on thin aluminium plates using LS-DYNA by modelling plates with shell elements and projectiles with solid elements. In order to establish the required modelling criterion in terms of element size for aluminium plates, a convergence study of…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsElectromagnetic Launch and Propulsion Technology

Structural origin for the change of the order of ferroelectric phase transition in triglycine sulfate/selenate systems

Rajul Ranjan Choudhury、R. Chitra2009-07-27Journal of Physics Condensed Matter

Crystal structures of triglycine selenate (TGSe) and triglycine sulfate (TGS) obtained from single crystal neutron diffraction are compared. The double well single cell local potential experienced by the non-planar amino group of one of the three glycine ions (GI) of these two isostructural crystals is obtained using…

Nonlinear Optical Materials ResearchSolid-state spectroscopy and crystallographyCrystallization and Solubility Studies

Morphological Investigation of Mn12Single-Molecule Magnets Adsorbed on Au(111)

Gonzalo Otero、Emi Evangelio、Celia Rogero 等 7 位作者2009-07-27Langmuir

We report on the adsorption of Mn(12) single-molecule magnets bearing external biphenyl groups on Au(111) surfaces after a simple dipping procedure. Topographic AFM images confirm that the biphenyl groups favor the adsorption of the molecules without the need of functionalization with thiols or thioether groups. The f…

Magnetic properties of thin filmsMagnetism in coordination complexesAdvanced NMR Techniques and Applications

Fabrication and optical properties of thin silica‐coated CdSe/ZnS quantum dots

Ye Sun、Francesco Masia、W. Langbein 等 4 位作者2009-07-27physica status solidi (a)

Abstract We demonstrate the fabrication of thin silica‐coated CdSe/ZnS colloidal quantum dots using a reverse microemulsion method. Spherical particles of <20 nm diameter with a single dot in the centre of a thin silica shell of good morphology are achieved, promising for biophotonic applications where hydrophilic…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesPhotonic Crystals and Applications

Syntheses, Crystal Structures, and Magnetic Properties of Two Cyclic Clusters Comprising Six Iron(III)/Manganese(III) Ions and Entrapping Sodium Ions

Pei‐Pei Yang、Haibin Song、Xi-Feng Gao 等 5 位作者2009-07-27Crystal Growth & Design

The reaction of iron or manganese salt with sodium 2-{[bis(2-hydroxyethyl)amino]methyl}-4-methylphenate (NaH 2 L) in CH 3 OH/CH 3 CN solution represents a good synthetic route to the cation molecular wheels [NaFe(III) 6 L 6 ]OH·1.5CH 3 CN ( 1 ) and [NaMn(III) 6 L 6 ]OH·CH 3 OH·0.75H 2 O ( 2 ), respectively. Single-cry…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Polarization rotation contributions to dielectric nonlinearity in 65Pb(Mg1/3Nb2/3)O3–35PbTiO3 single crystals

Ashley Bernal、Nazanin Bassiri‐Gharb2009-07-27Applied Physics Letters

The dielectric response of 65Pb(Mg1/3Nb2/3)O3–35PbTiO3 (PMN-35PT) single crystals is reported for ac field amplitudes up to ∼3.5 kV/cm over a frequency range from 3 Hz to 1 kHz. The nonlinear dielectric response is described by a Rayleigh-like analysis, indicating extrinsic contributions from nonlinear and hysteretic…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Topologically Matching Supramolecular n/p‐Heterojunction Architectures

Rajesh S. Bhosale、Alejandro Perez‐Velasco、Velayutham Ravikumar 等 14 位作者2009-07-27Angewandte Chemie

Zueinander passende Formen müssen die Komponenten beim Aufbau supramolekularer Photosysteme mit n/p-Heteroübergang auf festen Trägern haben. Die Systeme überzeugen durch eine effiziente Photostromerzeugung, eine vorteilhafte kritische Dicke, glatte Oberflächen und ein fehlerfreies Ansprechen auf funktionelle Sonden fü…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

A New “Bones/Muscles” Strategy for Preparing Highly Conducting Single‐Walled Carbon‐Nanotube Films with Ultrahigh Transparency

Hongliang Zhang、Dacheng Wei、Yunqi Liu 等 10 位作者2009-07-27Small

Ultrahigh-transmittance conducting films (UHTCFs) of single-walled carbon-nanotubes (SWNTs) are prepared by combined direct-synthesis and solution-based methods. Perfect two-dimensional SWNT TCFs (P2DTCFs) act as “bones” and SWNT bundles as “muscles” that fill in the uncovered areas (see picture). The sheet resistance…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Oxygen‐assisted photoinduced structural transformation in amorphous Ge–S films

Yoshifumi Sakaguchi、D. A. Ténné、M. Mitkova2009-07-27physica status solidi (b)

Abstract We report our results of continuous illumination of Ge 46 S 54 chalcogenide glass films with bandgap light in air. The outcome of this process is the formation of Ge–S backbone depleted in germanium. We relate this to consumption of some of the germanium available in the initial material due to the occurrence…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Diffusion within α-CuI studied usingab initiomolecular dynamics simulations

Chris E. Mohn、Svein Stølen、S. Hull2009-07-27Journal of Physics Condensed Matter

The structure and dynamics of superionic α-CuI are studied in detail by means of ab initio Born-Oppenheimer molecular dynamics simulations. The extreme cation disorder and a soft immobile face centred cubic sublattice are evident from the highly diffuse atomic density profiles. The Cu-Cu pair distribution function and…

ZnO doping and propertiesCopper-based nanomaterials and applicationsnanoparticles nucleation surface interactions

Structural phase transition inBa(Fe0.973Cr0.027)2As2single crystals

Sergey L. Bud’ko、S. Nandi、Ni Ni 等 9 位作者2009-07-27Physical Review B

We present thermodynamic, structural, and transport measurements on $\text{Ba}{({\text{Fe}}_{0.973}{\text{Cr}}_{0.027})}_{2}{\text{As}}_{2}$ single crystals. All measurements reveal sharp anomalies at $\ensuremath{\sim}112\text{ }\text{K}$. Single crystal x-ray diffraction identifies the structural transition as a fir…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Controlling Orientation and Functionalization in Thin Films of Block Copolymers

Chansub Lee、Seung‐Hyun Kim、Thomas P. Russell2009-07-27Macromolecular Rapid Communications

Functionalizing and controlling nanostructures resulting from block copolymer self-assembly are key factors in defining their application. In this work, a simple but quite general route to achieve both goals simultaneously is discussed. In thin films of polystyrene-block-poly(vinyl pyridine) (PS-b-PVP) with small conc…

Organic Electronics and PhotovoltaicsAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Characterization and cytocompatibility of surface modified polyamide66

Juan Shen、Yubao Li、Yi Zuo 等 7 位作者2009-07-27Journal of Biomedical Materials Research Part B Applied Biomaterials

The chemical modification of polyamide66 (PA66) membrane by graft polymerization with methacrylic acid (MAA) was initiated under ultraviolet light. Subsequently, covalent immobilization of bioactive surface was obtained by coupling gelatin to the MAA graft chains with the aid of a water-soluble carbodiimide (WSC). The…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolymer Surface Interaction Studies

Synthesis of Liquid‐Crystalline Colloids in Nonpolar Media and their Manipulation in Electric Fields

Sönke Haseloh、Rudolf Zentel2009-07-27Macromolecular Chemistry and Physics

Abstract The first synthesis of anisotropic liquid‐crystalline colloids in silicone oil by a direct (radical) polymerization of a monomer in THF/silicone oil mixtures with the help of siloxane containing stabilizers is described. The size of the colloids is in the lower µm range and can be adjusted by varying the mixt…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsElectrowetting and Microfluidic Technologies

Probing formally forbidden optical transitions in PbSe nanocrystals by time- and energy-resolved transient absorption spectroscopy

Juleon M. Schins、M. Tuan Trinh、Arjan J. Houtepen 等 4 位作者2009-07-27Physical Review B

The first two peaks of the optical extinction spectrum of PbSe nanocrystals in solution have been assigned in the literature to the $1{\text{S}}_{\text{h}}1{\text{S}}_{\text{e}}$ and $1{\text{P}}_{\text{h}}1{\text{P}}_{\text{e}}$ transitions. In the present work we assign the transitions causing extinction in the ener…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Correlation-induced corrections to the band structure of boron nitride: A wave-function-based approach

Alexandrina Stoyanova、Liviu Hozoi、Peter Fulde 等 4 位作者2009-07-27The Journal of Chemical Physics

We present a systematic study of the correlation-induced corrections to the electronic band structure of zinc-blende BN. Our investigation employs an ab initio wave-function-based local Hamiltonian approach which offers a rigorous theoretical framework for the calculation of the polarization and local charge redistrib…

Graphene research and applicationsGaN-based semiconductor devices and materialsBoron and Carbon Nanomaterials Research

Monitoring Collagen Transcription by Vascular Smooth Muscle Cells in Fibrin-Based Tissue Constructs

Justin S. Weinbaum、Jie Qi、Robert T. Tranquillo2009-07-27Tissue Engineering Part C Methods

Current methods for measuring collagen content in engineered tissues are incompatible with monitoring of collagen production because they require destruction of the tissue. We have implemented a luciferase-based strategy to monitor collagen production noninvasively. Fibrin-based tissue constructs made using vascular s…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsCell Adhesion Molecules Research

Modelling the evolution of vein microstructure with phase‐field techniques – a first look

Jürgen Hubert、Heike Emmerich、János L. Urai2009-07-27Journal of Metamorphic Geology

Abstract Vein microstructures in the Earth's crust contain a wealth of information on the physical conditions of crystal growth, but correct interpretation requires an improved understanding of the processes involved. In this paper the processes involved in the formation of veins are briefly reviewed, and the possibil…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Dynamics of Quantized Auger Recombination in CdSe Nanocrystals Studied by Femtosecond Intraband Pump–Probe Spectroscopy

Akihiro Ueda、Takeshi Tayagaki、Yoshihiko Kanemitsu2009-07-27Journal of the Physical Society of Japan

The dynamics of quantized Auger recombination in CdSe nanocrystals was studied by femtosecond intraband pump–probe spectroscopy at room temperature. The intraband transient absorption signals increase linearly with excitation laser intensity, while the interband transient absorption signals saturate at high excitation…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films