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Molecularly imprinted therapeutic contact lenses

Charles J. White、Mark E. Byrne2010-04-21Expert Opinion on Drug Delivery

IMPORTANCE OF THE FIELD: There exists a considerable unmet need for more efficacious delivery of ocular therapeutics. Contact lenses have been developed with high loading and controllable sustained release to overcome limited patient compliance and significant ocular transport limitations. This can best be achieved by…

Polymer Surface Interaction StudiesOcular Surface and Contact LensAnalytical Chemistry and Sensors

Impacts of Morphology and Crystallite Phases of Titanium Oxide on the Catalytic Ozonation of Phenol

Shuang Song、Zhiwu Liu、Zhiqiao He 等 7 位作者2010-04-21Environmental Science & Technology

TiO(2) nanomaterial is widely used for catalytic ozonation. In the present work, TiO(2) nanostructures with various morphology and crystallite phases were synthesized by a hydrothermal method, followed by calcination using Degussa P25 as precursor. The nanotube, nanorod, and nanowire forms were obtained by varying the…

TiO2 Photocatalysis and Solar CellsCatalytic Processes in Materials ScienceAdvanced oxidation water treatment

A High‐Speed Passive‐Matrix Electrochromic Display Using a Mesoporous TiO2 Electrode with Vertical Porosity

Wu Weng、Tetsuya Higuchi、Masao Suzuki 等 11 位作者2010-04-21Angewandte Chemie

Klar und deutlich: Ein leistungsstarkes und schnelles elektrochromes Display (ECD) mit passiver Matrix wurde aus einem Leukofarbstoff und einer nanoporösen TiO2-Elektrode konstruiert (siehe Bild). Die senkrechten Poren verhindern eine Bewegung der Farbstoffmoleküle und führen dadurch zu klaren Bildern bei hohen Freque…

Transition Metal Oxide NanomaterialsAnalytical Chemistry and SensorsElectrowetting and Microfluidic Technologies

Liquid-phase laser ablation

Koichi Sasaki、Noriharu Takada2010-04-21Pure and Applied Chemistry

The irradiation of an intense laser pulse onto a solid target immersed in liquid produces dense plasma. The plasma produced by liquid-phase laser ablation has unique features at high pressure and temperature, which are never realized by liquid-phase discharges. Another unique characteristic of liquid-phase laser ablat…

Diamond and Carbon-based Materials ResearchLaser-induced spectroscopy and plasmaLaser-Ablation Synthesis of Nanoparticles

A High‐Speed Passive‐Matrix Electrochromic Display Using a Mesoporous TiO2 Electrode with Vertical Porosity

Wu Weng、Tetsuya Higuchi、Masao Suzuki 等 11 位作者2010-04-21Angewandte Chemie International Edition

On display: A high-speed and high-quality passive-matrix electrochromic display (ECD) is constructed from a leuco dye and a TiO2 nanoporous electrode (see picture). The vertical pores prevent the drifting of the colored dye molecules, leading to a clear image at high driving speeds. With full-color features, this kind…

Transition Metal Oxide NanomaterialsAnalytical Chemistry and SensorsElectrowetting and Microfluidic Technologies

Control of Solid‐State Dye‐Sensitized Solar Cell Performance by Block‐Copolymer‐Directed TiO2 Synthesis

Pablo Docampo、Stefan Guldin、Morgan Stefik 等 10 位作者2010-04-21Advanced Functional Materials

Abstract Hybrid dye‐sensitized solar cells are typically composed of mesoporous titania (TiO2), light‐harvesting dyes, and organic molecular hole‐transporters. Correctly matching the electronic properties of the materials is critical to ensure efficient device operation. In this study, TiO2 is synthesized in a well‐de…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesPolyoxometalates: Synthesis and Applications

Hydrogenation of Nitrobenzene to Aniline over Silica Gel Supported Nickel Catalysts

Junhua Wang、Zhenle Yuan、Renfeng Nie 等 5 位作者2010-04-21Industrial & Engineering Chemistry Research

Nanosized silica gel supported Ni catalysts that have average Ni particle size of 3.7, 11.4, and 11.8 nm were prepared by facile impregnation of different Ni precursors and used for hydrogenation of nitrobenzene (NB). These catalysts were characterized by N 2 adsorption, X-ray diffraction, and transmission electron mi…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Inkjet Printing of Conductive Silver Patterns by Using the First Aqueous Particle-Free MOD Ink without Additional Stabilizing Ligands

Stephan F. Jahn、Thomas Blaudeck、Reinhard R. Baumann 等 8 位作者2010-04-21Chemistry of Materials

The chemical and physical properties of [AgO 2 C(CH 2 OCH 2 ) 3 H] ( 3 ) and its use as an aqueous, ligand-free MOD ink (MOD = metal−organic decomposition) for piezo inkjet printing is discussed. The printed, thermal, or photochemical sintered silver features are electrically conductive on glass (2.7 × 10 7 S m −1 ) a…

Gold and Silver Nanoparticles Synthesis and ApplicationsInnovative Microfluidic and Catalytic Techniques InnovationNanomaterials and Printing Technologies

Photochemical Fate: The First Step Determines Efficiency of H2 Formation with a Supramolecular Photocatalyst

Stefanie Tschierlei、Michael Karnahl、Martin Presselt 等 9 位作者2010-04-21Angewandte Chemie International Edition

The color of the incident light determines the efficiency of the hydrogen evolution mediated by a supramolecular photocatalyst. This finding demonstrates the importance of the Franck–Condon point in artificial photosynthesis systems and should have an impact on their design.

Advanced Photocatalysis TechniquesCO2 Reduction Techniques and CatalystsAdvanced Nanomaterials in Catalysis

Observation of Chiral Aggregate Growth of Perylene Derivative in Opaque Solution by Circularly Polarized Luminescence

Hiroyuki Tsumatori、Takuya Nakashima、Tsuyoshi Kawai2010-04-21Organic Letters

The concentration-dependent enhancement of the luminescence dissymmetry factor has suggested that pi-conjugated chiral perylene derivatives in a high concentrated opaque solution grow to aggregated structures with higher optical chirality.

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Fabrication, Optical Modeling, and Color Characterization of Semitransparent Bulk‐Heterojunction Organic Solar Cells in an Inverted Structure

Tayebeh Ameri、Gilles Dennler、Christoph Waldauf 等 10 位作者2010-04-21Advanced Functional Materials

Abstract Semitransparent inverted organic photodiodes are fabricated with a Baytron PH500 ethylene‐glycol layer/silver grid as the top electrode. Reasonable performances are obtained under both rear‐ and front‐side illumination and efficiencies up to 2% are achieved. Some light is shed on visual prospects through opti…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNanowire Synthesis and Applications

Recent Advances in Enzymatic Fuel Cells: Experiments and Modeling

Ivan Ivanov、Tanja Vidaković‐Koch、Kai Sundmacher2010-04-21Energies

Enzymatic fuel cells convert the chemical energy of biofuels into electrical energy. Unlike traditional fuel cell types, which are mainly based on metal catalysts, the enzymatic fuel cells employ enzymes as catalysts. This fuel cell type can be used as an implantable power source for a variety of medical devices used…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Bombesin functionalized gold nanoparticles show in vitro and in vivo cancer receptor specificity

Nripen Chanda、Vijaya Kattumuri、Ravi Shukla 等 17 位作者2010-04-21Proceedings of the National Academy of Sciences

Development of cancer receptor-specific gold nanoparticles will allow efficient targeting/optimum retention of engineered gold nanoparticles within tumors and thus provide synergistic advantages in oncology as it relates to molecular imaging and therapy. Bombesin (BBN) peptides have demonstrated high affinity toward g…

Nanoparticle-Based Drug DeliveryNeuropeptides and Animal PhysiologyPeptidase Inhibition and Analysis

Influence of Acellular Natural Lung Matrix on Murine Embryonic Stem Cell Differentiation and Tissue Formation

Joaquin Cortiella、Jean A. Niles、Andrea Cantu 等 10 位作者2010-04-21Tissue Engineering Part A

We report here the first attempt to produce and use whole acellular (AC) lung as a matrix to support development of engineered lung tissue from murine embryonic stem cells (mESCs). We compared the influence of AC lung, Gelfoam, Matrigel, and a collagen I hydrogel matrix on the mESC attachment, differentiation, and sub…

Pluripotent Stem Cells ResearchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Gold nanoparticles: opportunities and challenges in nanomedicine

Rochelle R. Arvizo、Resham Bhattacharya、Priyabrata Mukherjee2010-04-21Expert Opinion on Drug Delivery

IMPORTANCE OF THE FIELD: Site-specific drug delivery is an important area of research that is anticipated to increase the efficacy of the drug and reduce potential side effects. Owing to this, substantial work has been done developing non-invasive and targeted tumor treatment with nanoscale metallic particles. AREAS C…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsCancer Research and Treatment

Kinetic Analysis of Catalytic Reduction of 4-Nitrophenol by Metallic Nanoparticles Immobilized in Spherical Polyelectrolyte Brushes

Stefanie Wunder、Frank Polzer、Yan Lü 等 5 位作者2010-04-21The Journal of Physical Chemistry C

We present a study on the catalytic reduction of 4-nitrophenol by sodium borohydride in the presence of metal nanoparticles. The nanoparticles are embedded in spherical polyelectrolyte brushes, which consist of a polystyrene core onto which a dense layer of cationic polyelectrolyte brushes are grafted. The average siz…

Nanoparticle-Based Drug DeliveryCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Process for protection of aluminum nitride powder against hydrolysis with sodium tripolyphosphate as dispersant

Ali Ceylan2010-04-21Advances in Applied Ceramics Structural Functional and Bioceramics

In the present study, the hydrolysis behaviour of aluminum nitride (AlN) powder with and without dispersant [sodium tripolyphosphate (STPP, Na5P3O10) has been investigated in aqueous milling media to avoid hydrolysis and improve dispersion. The moderate amount of dispersant for good dispersion was found to be 0·015 g…

Advanced ceramic materials synthesisAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Exchange bias associated with magnetic glass state in Gd5Ge4

S. Yuan、Jun‐Yi Ge、Shixun Cao 等 6 位作者2010-04-21Journal of Applied Physics

The exchange bias phenomena associated with the magnetic glass state at low temperatures in Gd5Ge4 are studied. The exchange bias effect originates from the exchange coupling between the ferromagnetic islands and antiferromagnetic matrix in the magnetic glass state. It is found that the exchange bias in Gd5Ge4 is stro…

Theoretical and Computational PhysicsMagnetic and transport properties of perovskites and related materialsPhase-change materials and chalcogenides

Thermal and Mechanical Properties of Dried Foam Films and Their Incorporation of Water-Soluble Compounds

Jian Jin、Weifeng Bu、Izumi Ichinose2010-04-21Langmuir

Dried foam films (DFFs), which are free-standing reversed bilayers covering the holes of micrometers, are obtained by using several types of surfactants. In this article, we examined the formation of DFFs from a wide range of surfactants, systematically changing the headgroup, the counterion, the length and number of…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

The effect of partial substitution of Ge for Ga on the elastic and magnetoelastic properties of Fe–Ga alloys

Gabriela Petculescu、Andrada-Oana Mandru、W. M. Yuhasz 等 8 位作者2010-04-21Journal of Applied Physics

Both components of the tetragonal magnetoelastic constant b1: the saturation magnetostriction, λγ,2=(3/2)λ100, and the magnetic-field saturated shear elasticity, c′=(c11−c12)/2, were investigated over a wide temperature range for the magnetostrictive Fe1−x−yGaxGey alloys, (x+y≅0.125, 0.185, and 0.245; x/y≅1 and 3). Th…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications