Materials Literature
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The usefulness of azopyridinium methyl iodide salts for designing new promising light-controlled molecular switches is presented. Large absorbance changes have been produced in the samples by irradiation with light at lambda = 355 nm. The thermal recovery of the initial state took place completely within 130-450 ms, w…
ZnO nanorod films are increasingly used as an alternative to nanoporous TiO 2 as the electron conductor in semiconductor-sensitized nanoporous solar cells (SSSCs). Semiconductor light absorbers deposited onto ZnO by chemical bath deposition (CBD) tend to form poorly covering deposits of isolated clusters. We show how…
We describe the length-dependent exciton dynamics in DNA-wrapped single-walled carbon nanotubes (SWNTs) using time-resolved photoluminescence (PL) excitation correlation spectroscopy. We demonstrate that the effective PL lifetimes have substantial upper limits in longer SWNTs. Our results suggest that the exciton diff…
The flow behaviour of Ti–5Al–5Mo–5V–3Cr with an initial microstructure containing acicular α platelets has been characterised during isothermal subtransus forging. Flow softening was observed, following yielding and limited hardening, for all investigated temperatures and strain rates, before a steady state flow regim…
A subtle interplay of supramolecular aggregation, crystal symmetry, and bistable proton sites in NH + ···N hydrogen bonds in 1,4-diazabicyclo[2.2.2]octane hydroiodide (dabcoHI, [C 6 H 13 N 2 ] + I − ) leads to the giant dielectric response in this compound. This unique feature disappears on increasing the temperature…
(1)H nuclear magnetic resonance (NMR) field cycling relaxometry has been applied to study the dynamics of homologues of glycerol (propylene glycol, 2,3-butandiol, glycerol, threitol, xylitol, sorbitol) and non-alcohol liquids (o-terphenyl, tristyrene, 3-fluoroaniline, m-toluidine). A broad range of temperatures (200-4…
Doping dependence of the spin fluctuations and the electron correlations in the effective five-band Hubbard model for iron pnictides is investigated using the fluctuation-exchange approximation. For a moderate hole doping, we find a dominant low-energy spin excitation at $\mathbit{Q}=(\ensuremath{\pi},0)$, which becom…
Abstract Coextruded recycled polyethylene and wood‐flour composites with core–shell structure were manufactured using a pilot‐scale coextrusion line. The influence of wood loadings and thickness of the shell layer and core quality on mechanical and water absorption properties of the composites were investigated. Core–…
Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is “alloyed” with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each dis…
Limited access: Silica nanoparticles functionalized with alcohols and thiols have been used for the chromofluorogenic detection of nerve agent mimics. In the absence of the mimics, the thiol groups (yellow circles) react with squaraine dyes (blue diamonds) and result in the bleaching of the solution. In the presence o…
The self-assembly of [Nb(IV)(CN)(8)](4-) with different 3d metal centers in an aqueous solution and an excess of pyrazole resulted in the formation of four 3D isostructural compounds {[M(II)(pyrazole)(4)](2)[Nb(IV)(CN)(8)].4H(2)O}(n), where M(II) = Mn, Fe, Co, and Ni for 1-4, respectively. All four assemblies crystall…
We introduce half-wave and quarter-wave retarders based on the dispersion properties of guided-mode resonance elements. We design the wave plates using numerical electromagnetic models joined with the particle swarm optimization method. The wave plates operate in reflection. We provide computed results for reflectance…
The pseudoternary (Ge,Pb,Sn)Te system is characterized by demixing to both Pb- and Ge- rich telluride submicrometer and nanosized domains. The present study is concerned with the thermoelectric (TE) properties of the quasi-ternary (Ge 0.6 Pb 0.3 Sn 0.1 )Te compound at 390 °C, during the demixing process over lengthy p…
Abstract The use of pyrrolidinium‐based ionic liquids (ILs) in asymmetric electric double‐layer capacitors (AEDLC) with positive and negative carbon electrodes of different weight is a powerful strategy for developing safe, high specific‐energy supercapacitors operating at >3.5 V. The preparation and characterisation…
As recently discovered, matriptase-2, a type II transmembrane serine protease, plays a crucial role in body iron homeostasis by down-regulating hepcidin expression, which results in increased iron levels. Thus, matriptase-2 represents a novel target for the development of enzyme inhibitors potentially useful for the t…
The response of the superconducting state and crystal structure of LiFeAs to chemical substitutions on both the Li and the Fe sites has been probed using high-resolution X-ray and neutron diffraction measurements, magnetometry, and muon-spin rotation spectroscopy. The superconductivity is extremely sensitive to compos…
Abstract Sunflower oil (SO) is a renewable resource that can be epoxidized, and the epoxidized SO has potential uses as an environmentally friendly in polymeric formulations, especially for poly (vinyl chloride) (PVC). Epoxidized sunflower oil (ESO) was prepared by treating the oil with peracetic acid generated in sit…
Dithienobismoles having a bismole ring fused with a bithiophene system were prepared by the reactions of β,β′-dilithiobithiophenes with aryldihalobismuthanes, as novel phosphorescence materials.
The photophysical properties of two pairs of squaraine molecules where two oxygen atoms in a squaraine bridge are replaced with sulfur atoms are investigated. This substitution leads to an inversion of the lowest singlet π−π* electronic transition by an n−π* transition, effectively reducing the energy difference betwe…
Recent experiments on thermoelectric characterization of doped quaternary compounds of sattanite or kesterite-type ${\text{Cu}}_{2}{\text{ZnSnSe}}_{4}$, ${\text{Cu}}_{2}{\text{ZnSnS}}_{4}$, and ${\text{Cu}}_{2}{\text{CdSnSe}}_{4}$, show promise for their use as bulk thermoelectrics. In this paper we present and discus…