Materials Literature
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The magnetic properties of isolated TbPc(2) molecules supported on a Cu(100) surface are investigated by X-ray magnetic circular dichroism at 8 K in magnetic fields up to 5 T. The crystal field and magnetic properties of single molecules are found to be robust upon adsorption on a metal substrate. The Tb magnetic mome…
Optical second-harmonic generation from gold nanoparticles is investigated both experimentally and theoretically. The contribution of octupoles is reported for the first time in the second-harmonic emission pattern, by using an harmonic polarization in the scattering plane. The experimental results presented here for…
Unbiased search on the potential energy surface of medium-sized boron clusters, with B(80), B(74), and B(68) as representatives, was carried out using simulated annealing incorporated with first-principles molecular dynamics. These boron clusters thermodynamically prefer the B(12)-centered core-shell structures, which…
The plasmon resonances in metallic nanorods are investigated using fully quantum mechanical time-dependent density functional theory. The computed optical absorption curves display well-defined longitudinal and transverse plasmon resonances whose energies depend on the aspect ratio of the rods, in excellent agreement…
Silica-titania hollow nanoparticles (HNPs) with uniform diameters of 25, 50, 75, 100, and 125 nm were fabricated by dissolution and redeposition method in order to evaluate size dependent cellular response. Surface-modified HNPs with cationic, anionic, and neutral functional group were prepared by silane treatment. We…
Hybrid supercapacitor electrodes with remarkable specific capacitance have been fabricated by coaxially coating manganese oxide thin films on a vertically aligned carbon nanofiber array. Ultrathin manganese oxide layers are uniformly coated around each carbon nanofiber via cathodic electrochemical deposition, likely b…
Nanostructured materials are difficult to prepare rapidly and as large structures. The present study is thus significant because a rapid preparation procedure for large, flat, smooth, and optically transparent cellulose nanopaper structures is developed using a semiautomatic sheet former. Cellulose/inorganic hybrid na…
Polyaniline nanotubes (PANI NTs) base has been utilized as an adsorbent for the removal of cationic dyes such as methylene blue (MB) from aqueous solution. This observation was evidenced from the measurements of quartz crystal microbalance (QCM) and UV−visible spectroscopy. Experiments were conducted by varying parame…
A unified approach to covalently functionalize graphene nanosheets based on nitrene chemistry is reported. This strategy is simple and efficient, allowing various functional moieties (e.g., hydroxyl, carboxyl, amino, bromine, long alkyl chain, etc.) and polymers (e.g., poly(ethylene glycol), polystryene) to covalently…
An elastomeric, healable, supramolecular polymer blend comprising a chain-folding polyimide and a telechelic polyurethane with pyrenyl end groups is compatibilized by aromatic pi-pi stacking between the pi-electron-deficient diimide groups and the pi-electron-rich pyrenyl units. This interpolymer interaction is the ke…
A indústria de papel e celulose representa um dos mais expressivos setores industriais do mundo, sendo de grande importância para a economia mundial. Na América do Sul, devido à grande disponibilidade de recursos florestais, O Brasil e o Chile são os maiores produtores de celulose. O Brasil produz em torno de 6 milhõe…
Recentemente, a dopagem de semicondutores (envolvendo compostos II-VI, IV-VI, III-V, e do grupo-IV) com espécies magnéticas tem sido extensivamente investigada em função do seu potencial em spintrônica. Neste contexto, semicondutores magnéticos baseados no Si e no Ge são atraentes devido à sua compatibilidade com a in…
In this work we studied the synthesis and characterization of europium diphenylamine-4-sulfonateat different reaction media and their behavior of two techniquesof thermal analysis(TG/DTG and DSC). The compounds synthesized in aqueous solution (Compound A) and in water-ethanol (Compound B), were characterized by the fo…
Die Reduktion von Schadstoff-Emissionen und des Kraftstoffverbrauches sind für die Einhaltung von immer strenger werdenden Abgasgrenzwerten zum Schutz der menschlichen Gesundheit und der Vegetation von großer gesellschaftlicher Bedeutung.Ob Deutschland die innerstädtischen Immissionsgrenzwerte der Europäischen Union (…
Выделены основные виды озеленения зданий и сооружений: озеленение кровель и озеленение фасадов.Проведен аналитический обзор объектов отечественного и зарубежного опыта проектирования зданийс озелененной кровлей. Выявлены основные композиционные и функциональные характеристикизданий с озелененной кровлей. Систематизиро…
Advanced vehicle technologies alternative to the conventional IC engine vehiclesarereferredtoasalternativevehicles.Electricvehicles(EV),hybrid electricvehicles(HEV),plug-inhybridvehicles(PHEV),andfuelcellelectricvehicles(FCEV)areallexamplesofalternativevehicles.Thischapter presentsthearchitecturesanddesignofthesealter…
Americanae nace como un proyecto conjunto que surge dentro de la Red Europea de Información y Documentación sobre América Latina (REDIAL), y que ha afrontado la Biblioteca de la Agencia Española de Cooperación Internacional para el Desarrollo (AECID). Esta nueva biblioteca virtual hace más accesibles los libros digita…
Recent progresses in analytical methods associated with combinatorial chemistry have been summarized in several recent reviews (Egner and Bradley 1997; Gallop and Fitch 1998; Balkenhohl et al. 1997; Deben et al. 1998; Shapiro et al. 1997; Yan 1998; Yan and Gremlich 1999; Schneider and Anslyn 1999; Gillie et al. 2000;…
The details of the domain structure of the incommensurate antiferroelectric structure in La-doped zirconium-rich lead zirconate titanate have been revealed in detail for the first time. The structure is dominated by 60° domain boundaries close to {101} planes of the primitive perovskite cell; and tilts of the perovski…
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