Materials Literature
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Self-assembled monolayers (SAMs) can decorate surfaces with `smart´ functional units possessing reversible stimulus-response behavior for optical, thermal, magnetic or redox-chemical stimuli. An independent performance of individual functional groups in such a film is desirable, which can be, in particular, ensured by…
A representation of partially spatially coherent and partially polarized stationary electromagnetic fields is given in terms of mutually uncorrelated, transversely shifted, fully coherent, and polarized elementary electric-field modes. This representation allows one to propagate non-paraxial partially coherent vector…
Membrane permeabilization is achieved via numerous techniques involving the use of molecular agents such as peptides used in antimicrobial therapy. Although high efficiency is reached, the permeabilization mechanism remains global with a noticeable lack of control. To achieve localized control and more gradual increas…
Abstract A large number of cotton‐like ultralong β‐SiC nanowires (NWs) were successfully synthesized via a simple catalyst‐free carbothermal reduction approach using a carbonaceous silica xerogel as raw materials. The length of the NWs is in the millimeter range and the diameter of the NWs is about 130 nm. The ultralo…
The triiodide ion I(3)(-) exhibits a complex photodissociation behavior, the dynamics of which are not yet fully understood. As a first step toward determining the full potential energy surfaces of this species for subsequent simulations of its dissociation processes, we investigate the performance of different electr…
An algorithm for the solution of the linear response equation in the random phase approximation is presented. All entities including frequency arguments, matrices, and vectors, are assumed to be complex, and it represents the core equation solver needed in complex polarization propagator approaches where nonstimulated…
A new class of macrocyclic and acyclic molecules was synthesized by the Mannich reactions of dipyrrolylmethanes to investigate anion recognition. The X-ray structures of the macrocycle and sulfate complexes are reported.
Functionalized copolyimides continue to attract much attention as membrane materials because they can fulfill the demands for industrial applications. Thus not only good separation characteristics but also high temperature stability and chemical resistance are required. Furthermore, it is very important that membrane…
We demonstrate the synthesis of large-scale high-quality single-crystalline γ-Mo 2 N fibers using α-MoO 3 fibers as precursors by temperature-programmed reactions with NH 3 . The formation mechanism is discussed, and the morphology, structure, composition, and chemical states of the prepared fibers were characterized…
(6−4) Photolyases are enzymes utilizing light to repair DNA pyrimidine−pyrimidone photolesions. The first step of enzyme function involves absorption of a photon and electron transfer from a flavin adenine dinucleotide anion (FADH − ) to the (6−4) lesion-inducing repair, that is, splitting of the covalently bound nucl…
The effect of prior deformation on mechanical behavior as a function of size is investigated for body-centered cubic (bcc) molybdenum (Mo) pillars. Experiments were performed using focused ion beam (FIB) manufactured [0 0 1] and [2 3 5] Mo micro/nanopillars, which were compressed, re-FIB machined, and compressed again…
Optical nanoantennas are capable of enhancing the near-field intensity and confining optical energy within a small spot size. We report a novel metal-dielectric-metal coupled-nanorods antenna integrated on the facet of a quantum-cascade laser. Finite-difference time-domain simulations showed that, for dielectric thick…
In Escherichia coli and many other bacterial species, the glycolytic enzyme enolase is a component of the multi-enzyme RNA degradosome, an assembly that is involved in RNA processing and degradation. Enolase is recruited into the degradosome through interactions with a small recognition motif located within the degrad…
This work describes the synthesis of highly conducting antimony‐doped tin oxide (ATO) nanocrystals prepared via a nonaqueous sol–gel route in the size range of 4–6 nm and provides insights into its electrical properties. The antimony composition was varied from 1 to 18 mol% and the lowest resistivity (4.0 × 10 −4 Ω·cm…
Since the advent of HAART, there have been substantial improvements in HIV patient survival; however, the prevalence of HIV associated dementia has increased. Importantly, HIV positive individuals who smoke progress to HIV associated neurological conditions faster than those who do not. Recent in vitro data have shown…
Three-dimensional finite-difference time-domain simulations were performed to explore the excitation of surface plasmon resonances in long silver (Ag) nanowires. In particular, we show that it is possible to generate plasmonic wave packets that can propagate along the nanowire by exciting superpositions of surface pla…
A wide variety of nanoscale hollow spheres can be obtained via a microemulsion approach. This includes oxides (e.g., ZnO, TiO₂, SnO₂, AlO(OH), La(OH)₃), sulfides (e.g., Cu₂S, CuS) as well as elemental metals (e.g., Ag, Au). All hollow spheres are realized with outer diameters of 10-60 nm, an inner cavity size of 2-30…
The 4,4'-bipyridine-based zwitterionic monocarboxylate ligand, 4,4'-dipyridinio-1-acetate (L), is used as coligand to construct novel magnetic coordination polymers with mixed azide and carboxylate bridges. Two compounds, [Co(2)(L)(2)(N(3))(4)(H(2)O)] x 4 H(2)O (1) and [Mn(6)(L)(4)(N(3))(12)(H(2)O)] x 5 H(2)O (2), hav…
Polyphosphazene-based electrolytes containing different iodide salts were studied as components of dye-sensitized solar cells (DSSCs). Electrolytes based on hexa[methoxyethoxyethoxycyclotriphosphazene] (MEE trimer) with dissolved LiI, NaI, NH 4 I, and 1-methyl-3-propylimidazolium (PMII) and I 2 were examined by ac con…
BACKGROUND: Magnesium stearate (MgSt) is widely used as a lubricant in the production of tablets. However, the amount added to a formulation is often too high or it is poorly mixed, which can lead to the production of tablets whose properties are out of specifications. METHOD: The objective of this work was to investi…