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Excited state distortions in a charge transfer state of a donor–acceptor [2]rotaxane

Rachel M. Stephenson、Xianghuai Wang、Ali Coşkun 等 5 位作者2010-01-01Physical Chemistry Chemical Physics

The charge transfer excited state of a mechanically interlocked [2]rotaxane (R(4+)) with a donor 1,5-dioxynaphthalene (DNP) unit in the rod and the acceptor cyclobis(paraquat-p-phenylene) (CBPQT(4+)) ring component, along with the analogous non-interlocked [2]pseudorotaxane (P(4+)), is studied by resonance Raman spect…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Evolution of density fluctuation to a lamellar crystal in a poly(trimethylene terephthalate) film revealed by the resonance light scattering technique

Weiang Luo、Xudong Chen、Zhengfu Liao 等 6 位作者2010-01-01Physical Chemistry Chemical Physics

The dynamic process of cold crystallization of amorphous poly(trimethylene terephthalate) (PTT) was investigated with resonance light scattering (RLS). By using an enhanced scattering peak at 329 nm, which was in close proximity to the absorption band of PTT film, density fluctuation due to gradual transition from amo…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Amplitude dependence of the internal friction and Young’s modulus defect of polycrystalline indium

K. Sapozhnikov、S. Golyandin、S. Kustov2010-01-01Physics of the Solid State

The dependences of the internal friction and the Young’s modulus defect of polycrystalline indium on the oscillatory strain amplitude have been studied over a wide range of temperatures (7–320 K) and oscillatory strain amplitudes (10 −7 −3.5 × 10 −4 ) at oscillatory loading frequencies of about 100 kHz. It has been re…

Microstructure and mechanical propertiesIntermetallics and Advanced Alloy PropertiesElectromagnetic Effects on Materials

Theoretical study of model elementary reactions of dissociative addition of light hydrocarbons to the Ti-doped aluminide cluster Al12Ti

В. К. Кочнев、О. П. Чаркин、Н. М. Клименко2010-01-01Russian Journal of Inorganic Chemistry

The potential energy surfaces (PES), energies E , and activation barriers h of elementary reactions of dissociative addition of CH 4 and C 2 H 6 molecules to the Al 12 Ti cluster with a marquee structure in the singlet and triplet states were calculated within the B3LYP approximation of the density functional theory u…

Fullerene Chemistry and ApplicationsIntermetallics and Advanced Alloy PropertiesQuasicrystal Structures and Properties

Impact Of Surface And Grain Boundary Scattering On The Resistivity Of Nanometric Cu Interconnects

Katayun Barmak、Tik Sun、R. Coffey 等 6 位作者2010-01-01AIP conference proceedings

This work addresses the resistivity increase in Cu interconnects with decreasing line width. Recent published resistivity data for Cu interconnect lines is found to be accurately modeled by a fixed surface scattering specularity parameter, p = 0.52, and a grain boundary reflection coefficient, R = 0.43. In this model,…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Influence of compaction conditions on the structure and mechanical properties of potassium hexatitanate based ceramics

А. В. Гороховский、Tomas Sanchez‐Monjaras、J.I. Escalante-Garcı́a 等 5 位作者2010-01-01Technical Physics Letters

The influence of compacting pressure on the structure and mechanical properties of sintered ceramics based on weakly crystalline potassium polytitanate with a composition close to K 2 O · 6TiO 2 has been studied. It is established that an increase in the pressure during the uniaxial cold pressing of compacts leads to…

Advanced ceramic materials synthesisPolymer Nanocomposite Synthesis and IrradiationMaterial Properties and Applications

Controlling the volumetric parameters of nitrogen-doped carbon nanotube cups

Brett L. Allen、Matthew B. Keddie、Alexander Star2010-01-01Nanoscale

Analogous to multiwalled carbon nanotubes, nitrogen-doped carbon nanotube cups (NCNCs) have been synthesized with defined volumetric parameters (diameter and segment lengths) by controlling the catalyst particle size and the concentration of nitrogen precursor utilized in the chemical vapor deposition (CVD) reaction,…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Compositional Improvement of Ln[sub 0.435]Ba[sub 0.145]Sr[sub 0.4]Fe[sub 0.8]Co[sub 0.2]O[sub 3−δ] IT-SOFC Cathodes Performance by Multiple Lanthanide Substitution

José M. Serra、Vicente B. Vert2010-01-01Journal of The Electrochemical Society

A series of materials based on the perovskite Ln 0.435 Ba 0.145 Sr 0.4 Fe 0.8 Co 0.2 O 3 − δ system ( Ln = La 1 − x − y Pr x Sm y ) has been characterized as intermediate temperature solid oxide fuel cell (IT-SOFC) cathodes. Among the different La, Pr, and Sm combinations, those containing at a time Sm and La or alter…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Dielectric Spectroscopy of Epoxy Resin with and without Inorganic Nanofillers

Ilona Pleşa2010-01-01OpenAlex

In this work, the real component of the relative permittivity and the loss tangent of epoxy resin with and without inorganic nano-fillers are determined by dielectric spectroscopy. The nano-fillers used in this study were alumina (Al2O3), silica (SiO2) and titania (TiO2). The dielectric spectroscopy measurements were…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Possible trends of renewable organic fillers and pigments derived from natural resources for sustainable development of paper industry

Jing Shen、Zhanqian Song、Xueren Qian2010-01-01BioResources

The use of traditional inorganic fillers and pigments for both filling and coating applications in papermaking may have certain limitations in such aspects as recyclability and combustibility. Novel renewable organic fillers and pigments derived from natural resources can possibly be completely recyclable, combustible…

Advanced Cellulose Research StudiesMicroplastics and Plastic PollutionPigment Synthesis and Properties

Lattice dynamics of YVO4 at high pressures

F. J. Manjón、P. Rodríguez‐Hernández、Alfonso Muñoz 等 7 位作者2010-01-01Physical Review B

We report an experimental and theoretical lattice-dynamics study of yttrium orthovanadate YVO4 up to 33 GPa together with a theoretical study of its structural stability under pressure. Raman-active modes of the zircon phase are observed up to 7.5 GPa, where the onset of an irreversible zircon-to-scheelite phase trans…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Polymer biocomposites with renewable sources

Stanisław Kuciel、P. Kuźniar、Aneta Liber-Kneć2010-01-01Archives of Foundry Engineering

Nowadays production of natural biodegradable polymer composites is an important research topic on the stage of renewable sources implementation instead of petrochemical sources. In this work, possibilities of processing biocomposites on the base on different types of biopolymers – polylactide (PLA), thermoplastic star…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Utilização de revestimentos/filmes edíveis para aplicações alimentares

Ana C. Pinheiro、Miguel A. Cerqueira、Bartolomeu Warlene Silva de Souza 等 6 位作者2010-01-01RepositóriUM (Universidade do Minho)

A indústria alimentar procura constantemente novas estratégias para aumentar o tempo de prateleira dos alimentos. Nos últimos anos, os filmes e revestimentos edíveis têm sido considerados uma das tecnologias com potencial para alcançar tais objectivos, assegurando a segurança microbiológica e a protecção dos alimentos…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsAgricultural and Food Sciences

Dielectric and impedance performances of giant dielectric constant oxide CaCu3Ti4O12

Luo Xiao-Jing、Yang Chang-Ping、Xueping Song 等 4 位作者2010-01-01Acta Physica Sinica

采用固相烧结法合成了单相巨介电常数氧化物CaCu3Ti4O12(CCTO).用阻抗分析仪分析了10—420 K温度范围内的介电频谱和阻抗谱特性,并结合ZVIEW软件进行了模拟.结果表明:温度高于室温时,频谱出现两个明显的弛豫台阶,低频弛豫介电常数随温度升高而显著增大,表现出热离子极化特点;温度低于室温时,频谱表现出类德拜弛豫,且高、低平台介电常数值基本不随温度变化,表现出界面极化特点和较好的温度稳定性.频谱中依次出现的介电弛豫对应于阻抗谱中

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Size effects under plastic deformation of microcrystals and nanocrystals

G. A. Malygin2010-01-01Physics of the Solid State

A theoretical analysis of size effects in plastically deformed crystals with transverse sizes in micro and nanometer ranges has been performed in the framework of the dislocation-kinetic approach. The analysis is based on the evolution equation of the dislocation density in these crystals and takes into account the ge…

Microstructure and mechanical propertiesNonlocal and gradient elasticity in micro/nano structuresSurface Treatment and Residual Stress

Mechanical properties of rubber-wood fiber filled pvcenr blend

Chantara Thevy Ratnam、Siti Fazlina Radin、Shuhaily Shamsuddin2010-01-01OpenAlex

The effect of rubber-wood fiber (RWF) on the mechanical properties of the 50/50 polyvinyl chloride/epoxidized natural rubber (PVC/ENR) blend was investigated over a range of fiber loadings (0 to 30%). The RWF filled PVC/ENR blend was prepared by using a Haake mixer at 150oC mixing temperature, 10 min. total mixing tim…

Structural Behavior of Reinforced ConcretePolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

A New Scheme and Microstructural Model for 3D Full 5-directional Braided Composites

Zhang、Fan、Liu 等 8 位作者2010-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

三维(3D ) 编织了 composites 是一种先进的并且被使用在航空并且太空航行学地更广泛地。3D 的优点,用法,缺乏和编织 composites 被分析的劣势,和改进材料的性质的可能的途径被介绍,也就是说完整的 5-directional 编织了的 3D 的一种新类型 composites 被开发。做这类预先形成的方法被建议。这被指出四步的编织它是最可能的认识到工业化生产几乎没在 composites'properties 上有效果。由分析模拟模型,材料的优点与 3D 4-di- rectional 和 5-directional 材料相比被介绍。最后,一个微结构模型被分析为未来打基础这些 composites 的理论分析。

Advanced ceramic materials synthesisAdditive Manufacturing and 3D Printing TechnologiesManufacturing Process and Optimization

Preparation and Characterization of Zinc Oxide Nanoparticles and a Study of the Anti-microbial Property of Cotton Fabric Treated with the Particles

M. Muthusamy2010-01-01OpenAlex

Nanotechnology is an emerging interdisciplinary technology that has been booming in many areas during the recent decade. Nanostructures are capable of enhancing the physical properties of conventional textiles, in areas such as antimicrobial properties, water repellence, soil resistance, antistatic, anti-infrared and…

Nanoparticles: synthesis and applications

Electrochemical Reduction of Oxygen and Nitric Oxide at Low Temperature on La[sub 1−x]Sr[sub x]CoO[sub 3−δ] Cathodes

Kent Kammer Hansen2010-01-01Journal of The Electrochemical Society

Six perovskites were synthesized and characterized by powder X-ray diffraction and cyclic voltammetry on conical electrodes in either air or nitric oxide in argon at 200, 300, and . At , the current densities in air was the highest for the strontium-free cobaltite, whereas the current densities were the highest for in…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Transformer Linear Section Model Order Reduction with an Improved Pole Clustering

M. Srinivsan、Academics Dean2010-01-01OpenAlex

This paper presents a reduction technique which was the detailed lumped parameter linear transformer model order as a starting point and allows its reductions to any size of the model order specified by the user. An improved clustering algorithm is employed in the proposed method to obtain the reduced order denominato…

Power Quality and HarmonicsMagnetic Properties and ApplicationsPower Transformer Diagnostics and Insulation