Materials Literature
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This paper evaluates the o-hydroxycinnamic platform for designing efficient caging groups with fluorescence reporting upon one- and two-photon excitation. The model cinnamates are easily prepared in one step by coupling commercial or readily available synthons. They exhibit a large one-photon absorption that can be tu…
A series of 2-iminopyrrole ligand precursors with increasing bulkiness [HNC4H3C(R)=N-2,6-R'2C6H3] (R = R' = H, 1a; R = Me, R'= H, 1b; R = H, R' = Me, 1c; R = R' = Me, 1d; R = H, R' = iPr, 1e; R = Me, R' = iPr, 1f) were synthesized and deprotonated with NaH to give the corresponding iminopyrrolyl sodium salts 2a-f. A s…
We present the synthesis, crystal structure, and temperature and field dependence of the magnetic properties of a new molecule-based magnet, [Co(hfac)2].BNO* (1), where hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato and BNO* is the chiral triplet bis(nitroxide), 1,3-bis(N-tert-butyl-N-oxylamino)-5-{1'-methyl-1'-[2' '-(S…
The structure and properties of the possible multiferroic, BiMnO 3, are calculated using the LDA+ U method of density functional theory. The symmetry is found to be centrosymmetric C 2/ c with zero ferroelectric polarization. The stereochemically active Bi lone pairs form local dipole moments which order in an anti-po…
We have designed a type of colloidal particle whose surface characteristics are sensitive to the pH of the aqueous phase in which they are dispersed. Particles of polystyrene latex stabilized by poly(acrylic acid) can act as stabilizers of aqueous foams by adsorbing at the air-water surface. Foams can be prepared and…
Multifluorescent silica nanoparticles were synthesized by the Stöber method using conjugates of (3-aminopropyl)triethoxysilane and fluorescent dye-N-hydroxysuccinimide esters. The nanoparticles containing the fluorescent dyes were well dispersed and showed high, stable, and tunable fluorescence intensities. In additio…
We report a detailed kinetic study of the RAFT polymerization of methyl 6- O -methacryloyl-α- d -glucoside (a methacrylic ester-type glycomonomer) with the chain transfer agent (CTA) (4-cyanopentanoic acid)-4-dithiobenzoate and initiator 4,4‘-azobis(4-cyanopentanoic acid) in homogeneous aqueous media. The influence of…
Novel coaxial structures consisting of nitrogen-doped carbon nanotube (MWNTs-CNx) cores with external concentric shells of pure carbon were produced by the pyrolysis of toluene over Fe-coated MWNTs-CNx. These materials were thoroughly characterized by SEM, HRTEM, X-ray diffraction, and TGA; a possible growth scenario…
The interaction of cyanobacterial biomass (Plectonema boryanum UTEX 485) with aqueous palladium(II) chloride (PdCl2 degrees ) has been investigated at 25-100 degrees C for up to 28 days. We report that the release of organic materials from the cyanobacteria promoted the precipitation of Pd(0) as crystalline spherical…
The regulation mechanism of organic additives on the crystallization of inorganic crystal is fundamentally important in biomineralization. Experimentally, it was found that the amino acids glycine (Gly) and glutamic acid (Glu) could lead to the formation of rod- and plate-like hydroxyapatite (HAP) crystallites, respec…
This paper considers fracture strength, fracture origins, and hydrothermal degradation of 3Y‐TZP with grain sizes in the range of 110–480 nm. Biaxial fracture strength testing was used to show that the fracture strength increases with grain size and is governed by the concurrent change in fracture toughness. Hydrother…
Nine one-dimensional (1D) lanthanide(III) coordination polymers with the formulas {[La(pta)(H 2 O) 4 ]·2H 2 O} n ( 1 ), {[Ln(pta)(H 2 O) 5 ]·4H 2 O} n [Ln = Sm ( 2 ), Eu ( 3 ), Tb ( 4 ), Ho ( 5 )], and {[Ln(pta)(H 2 O) 3 ]·4H 2 O} n [Ln = Dy ( 6 ), Er ( 7 ), Tm ( 8 ), Yb ( 9 )] (H 3 pta = 2,4,6-pyridinetricarboxylic a…
We use first-principles density functional theory (DFT) calculations to investigate the ground state structures of both BaCeO_{3} (BC) and Pd-doped BC (BCP). The relaxed structures match closely with recent experimental scattering studies, and also provide a local picture of how the BC perovskite lattice accommodates…
In this communication, we demonstrate an approach for shape control of PbTe nanocrystals. We succeeded in synthesizing three different shapes of PbTe nanoparticles, including cubes, cuboctahedra, and octahedra. These morphologies were prepared by changing the molar ratio between the Pb and Te precursors and also by ch…
Nanocubic La 2 Sn 2 O 7 photocatalysts with pyrochlore structure have been successfully synthesized by a one-pot hydrothermal method. The effects of alkaline concentration, reaction time, and hydrothermal temperature on the structures and morphologies of the resultant products were investigated. On the basis of charac…
The aim of this research was to synthesize magnesium hydroxide nanoparticles, which were further calcined to form magnesium oxide, using a spinning disk reactor. Magnesium hydroxide was prepared by continuously pumping two aqueous solutions of MgCl 2 and NaOH, respectively, into the chamber of the reactor, where a liq…
Polylactide (PLA) was melt blended with a biodegradable hyperbranched poly(ester amide) (HBP) to enhance its flexibility and toughness without sacrificing comprehensive performance. The advantage of using HBP was due to its unique spherical shape, low melt viscosity, and abundant functional end groups together with it…
Metal phosphides can have important properties such as superconductivity, magnetoresistance, magnetocaloric behavior, catalytic activity, and lithium intercalation capacity, which make them useful for a variety of technological applications. Bulk metal phosphides usually require high temperatures and harsh reaction co…
The observation of single sheets of graphite (graphene) presents new possibilities for carbon-based nanoelectronics. We report defect tolerant configurations for a nearly reflectionless 120 degrees turn and nearly reflectionless symmetric and asymmetric splitters, which can be cut from graphene. Connections between zi…
We perform molecular dynamics simulations of water in the presence of hydrophobic/hydrophilic walls at T = 300 K and P = 0 GPa. For the hydrophilic walls, we use a hydroxylated silica model introduced in previous simulations [Lee, S. H.; Rossky, P. J. J. Chem. Phys. 1994, 100, 3334. Giovambattista, N.; Rossky, P. J.;…