Materials Literature
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Abstract The reaction between a cobalt porphycene complex, [CoII(TPrPc)] (TPrPc is a dianion of 2,7,12,17-tetrapropylporphycene), and dioxygen was investigated by means of UV–vis, ESR, and resonance Raman (RR) spectroscopies. These spectra indicate the formation of [CoIII–O2−•]. In the presence of pyridine as an axial…
Bridged oxycarbosilane monomers are excellent precursors for the formation of spin on porous low-k materials using sacrificial pore generators. The measured Young's modulus numbers for the as-synthesized thin films without any post porosity toughening are the highest by far of any that we have observed for porous film…
The continuous downscaling of interconnect dimensions in combination with the introduction of porous low-k materials has increased the number of integration challenges tremendously. The paper focuses mainly on the impact of porous low-k dielectrics on interconnect reliability. Numerous reliability issues are induced b…
Copper (Cu) dual-damascene interconnects with self-formed MnSi/sub x/O/sub y/ barrier layer using a copper-manganese (Cu-Mn) alloy seed layer is successfully fabricated for the first time. No delamination is found in the chemical mechanical polishing process, probably because of better adhesion strength between the Mn…
Abstract A dinuclear copper(II) complex, [Cu2(L)](ClO4)2, of the macrocyclic ligand (H2L) derived from the [2:2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane, was reacted with [Cr(ox)3]3− and [Co(CN)6]3− to produce [Cu2(L)]3[Cr(ox)3]2·6MeOH (1) of a discrete octanuclear structure and [Cu2(L)]3[Co…
Abstract Studies into solvent resistance and aging properties of blends of natural rubber and epoxidized low molecular weight natural rubber were carried out. Vulcanization of the blends using the semi‐efficient vulcanization (semi‐EV) system was found to have curing advantages over conventional vulcanization (CV) and…
We found that 90° domain walls are absorptive to oxygen vacancies and the absorbing degree was related with the morphology of 90° domain walls: curved 90° domain walls are more absorptive to oxygen vacancies compared with straight 90° domain walls. Therefore, in ferroelectric materials with curved 90° domain walls, th…
Silicon nitride (Si 3 N 4 ) ceramics, prepared with Y 2 O 3 and Al 2 O 3 sintering additives, have been densified in air at temperatures of up to 1750°C using a conventional MoSi 2 element furnace. At the highest sintering temperatures, densities in excess of 98% of theoretical have been achieved for materials prepare…
The impact of surface and grain boundary scattering on the design of multi-level interconnect networks and their latency distributions is reported. For the 18-nm technology node (year 2018), it is shown that, despite more than 4/spl times/ increase in resistivity of copper for minimum size interconnects, the increase…
Abstract The synthesis, electronic absorption, fluorescence (λ f , λ ex , Φ f , τ f ) and photoisomerization (Φ t→c , photostationary state composition) properties of 3‐(4‐nitrophenylethenyl‐ E )‐NH‐indole ( 1 ), 3‐(4‐nitrophenylethenyl‐ E )‐ N ‐ethylindole ( 2 ) and 3‐(4‐nitrophenyl ethenyl‐ E )‐ N ‐benzenesulfonylin…
Abstract Tin and lead nanoparticles and metal sponges were prepared by reducing Me 2 Si(N t Bu) 2 Sn ( 7 ) and Me 2 Si(N t Bu) 2 Pb ( 9 ) with [H 2 AlO t Bu] ( 3 ), [HAl(O t Bu) 2 ] ( 13 ), [H 2 AlOSiMe 2 t Bu] ( 8 ), and [(Me 2 t BuSiO) 2 AlH] ( 15 ). Together with dihydrogen and the metals in their elemental state t…
Abstract The action of alkali treatment in both aqueous and alcoholic media is investigated to attain silk‐like polyester fabric. The use of alkoxide solutions is more effective on polyester fabric. Rapid loss in weight up to 15–20% occurs at ambient conditions. Immersion and padding techniques are applied. The effect…
Using a Femtosecond Transient Thermoreflectance (FTT) technique, we studied the thermomechanical properties of two Si∕SiGe superlattices. A theoretical model is presented which agrees well with the experimental results and allows us to determine the cross-plan thermal conductivity of the superlattices at room temperat…
The wavevector-dependent shear viscosity, eta(k), is evaluated for a range of temperatures in a supercooled binary Lennard-Jones liquid. The mode coupling theory of Keyes and Oppenheim (Phys. Rev. A 1973, 8, 937) expresses the self-diffusion constant, D, in terms of eta(k). Replacing eta(k) with the usual viscosity, e…
Abstract A series of nanocomposite hydrogels were prepared from acrylic acid (AA), N ‐isopropylacrylamide (NIPAAm), and intercalated hydrotalcite (IHT) by photopolymerization. The influence of the intercalating content of 2‐acrylamido‐2‐methyl propane sulfonic acid (AMPS) in HT on the swelling and mechanical propertie…
Abstract A new class of optically active poly(amide–imide–urethane)s (PAIUs) was synthesized via a two‐step diisocyanate route under microwave irradiation. In these reactions, 4,4′‐methylene‐bis(4‐phenylisocyanate) was reacted with bis( p ‐amido benzoic acid)‐ N ‐trimellitylimido‐ L ‐leucine and poly(ethylene glycol d…
Abstract Step heating melt polycondensation was adopted in the preparation of polyamides based on 1,16‐octadecane diacid and α,ω(CH 2 ) 2 n diamines ( n = 1–6). The structure was confirmed by various spectroscopic techniques (IR, Raman, 1 H‐NMR, and 13 C‐NMR). High molecular masses were obtained only in the presence…
We found that the optically isotropic (I(M)) mesophase observed recently below the nematic phase of the bent-core liquid crystal 4-chlororesorcinol bis[4-(4-n-dodecyloxybenzoyloxy)benzoate] shows ferroelectric-type switching. Polarizing microscopic, electric current, dielectric, and dynamic light scattering studies le…
Quantum tunneling of magnetization (QTM) in an $\mathrm{Fe}$-substituted single molecular magnet ${\mathrm{Mn}}_{11}\mathrm{Fe}$ has been studied by ac susceptibility measurements in ${\mathrm{Mn}}_{11}\mathrm{Fe}∕{\mathrm{Mn}}_{12}$ mixed crystal. Although the blocking temperature of the ${\mathrm{Mn}}_{11}\mathrm{Fe…
Abstract High‐conversion (HC) copolymers of aniline and o‐methoxyaniline (o‐anizidine) were synthesized for the first time by chemical oxidative copolymerization by using various polymerization techniques (simultaneous or consecutive introduction of comonomers into the polymerizing system). Low‐conversion (LC) copolym…