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Response of Titanium-Isopropoxide-Based Heterogeneous Amphiphilic Polymer Catalysts for Transesterification

Gayan Nawaratna、Sandun Fernando、Sushil Adhikari2010-07-21Energy & Fuels

Transesterification is a widely used reaction in the chemical industry. Currently, industrial-scale transesterification is primarily performed via homogeneous catalysts. Because of downstream separation issues, there is a need for effective heterogeneous catalysts. However, heterogeneous catalysts introduce the drawba…

Biodiesel Production and Applicationsbiodegradable polymer synthesis and propertiesChemical Synthesis and Reactions

Dynamics of surface structure evolution in colloidal adsorption: Charge patterning and polydispersity

Damien D. Brewer、Michael Tsapatsis、Satish Kumar2010-07-21The Journal of Chemical Physics

Kinetics, surface structures, and extent of surface coverage in adsorption of spherical colloids onto uniform and charge-patterned surfaces are studied using dynamic simulations. A Brownian dynamics simulation methodology is developed to account for double-layer and van der Waals interactions between particles and the…

Material Dynamics and PropertiesPickering emulsions and particle stabilizationElectrostatics and Colloid Interactions

Sodium titanate nanobelt as a microparticle to induce clay flocculation with CPAM

Xuyan Zhang、Wenxia Liu2010-07-21BioResources

Sodium titanate nanobelt was synthesized by treating titanium dioxide hydrothermally in concentrated sodium hydroxide solution. The product was characterized by SEM analysis and zeta potential measurement. It served as a microparticle to constitute a microparticle retention system with cationic polyacrylamide (CPAM),…

Clay minerals and soil interactionsLandfill Environmental Impact StudiesGrouting, Rheology, and Soil Mechanics

Comparative antioxidant activity of an extract of Lithraea molleoides and an isolated 5‐alkyl resorcinol derivative. Effects on the proliferation of normal and tumoral lymphocytes

Paula López、Graciela Ferraro、Claudia Anesini2010-07-21Phytotherapy Research

Lithraea molleoides (Vell.) Engl. (Anacardiaceae), is known in South America for its medicinal properties: antiarthritic, haemostatic, diuretic, tonic and useful for the treatment of respiratory diseases. Previously the isolation of a new cytotoxic 5-alkyl resorcinol derivative, 1,3-dihydroxy-5-(tridec-4',7'-dienyl) b…

Fungal Biology and ApplicationsPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Diffusivity and Climatic Simulation of Hybrid Foams

Amit A. Desai、John P. Basbagill、Steven Nutt 等 4 位作者2010-07-21Journal of Cellular Plastics

Hybrid composite phenolic foams reinforced with glass and aramid fibers were prepared and evaluated as potential materials for insulation and cladding applications. In particular, moisture uptake, flammability, and accelerated aging experiments were performed. A statistical approach was employed to model and predict t…

Cellular and Composite StructuresPolymer composites and self-healingFlame retardant materials and properties

Monte Carlo simulator of realistic x‐ray beam for diagnostic applications

Marco Bontempi、Lucia Andreani、Pier Luca Rossi 等 4 位作者2010-07-21Medical Physics

PURPOSE: Monte Carlo simulation is a very useful tool for radiotherapy and diagnostic radiology. Yet even with the latest PCs, simulation of photon spectra emitted by an x-ray tube is a time-consuming task, potentially reducing the possibility to obtain relevant data such as dose evaluations, simulation of geometric s…

Advanced Radiotherapy TechniquesDigital Radiography and Breast ImagingRadiation Shielding Materials Analysis

Changes in the endogenous BMP expression during redifferentiation of chondrocytes in 3D cultures

Christian Albrecht2010-07-21International Journal of Molecular Medicine

Engineering cartilage tissue is challenging, mainly because chondrocytes lose their differentiated phenotype when cultured in monolayer. The aim of this study was to analyse the influence of 3D-culture conditions on the redifferentiation of chondrocytes, devoting special attention to BMPs. Dedifferentiated chondrocyte…

Osteoarthritis Treatment and MechanismsAngiogenesis and VEGF in CancerSilk-based biomaterials and applications

Scavenging Free Radicals To Preserve Enhancement and Extend Relaxation Times in NMR using Dynamic Nuclear Polarization

Pascal Miéville、Puneet Ahuja、Riddhiman Sarkar 等 12 位作者2010-07-21Angewandte Chemie

Länger leben dank Vitamin C: N-Oxid-Radikale, die weithin zur dynamischen Kernpolarisation eingesetzt werden, können beim Auflösen durch Abfangreagentien wie Natriumascorbat (Vitamin C) reduziert werden, wodurch Polarisierungsverluste während des Transfers vermieden und transversale wie longitudinale Relaxationszeiten…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies

Characterization of a Six-Coordinate Ferrous High-Spin Heme with Both Intramolecular Axial Carboxylic Acid and Pyridine

Ismail Hijazi、Thierry Roisnel、Pascale Even‐Hernandez 等 7 位作者2010-07-21Journal of the American Chemical Society

Synthesis of a bis-strapped porphyrin with a pyridyl residue on one side and a malonic acid on the other side gives after iron(II) insertion a six-coordinate complex in which both apical groups are the two axial ligands of the iron atom. Unexpectedly, this six-coordinate iron(II) complex proves to be high-spin, likely…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsHemoglobin structure and function

Triplet contribution to the Josephson current in the nonequilibrium superconductor/ferromagnet/superconductor junction

I. V. Bobkova、A. M. Bobkov2010-07-21Physical Review B

The Josephson current through a long $s$-wave superconductor/weak ferromagnet/$s$-wave superconductor weak link is studied theoretically in the regime of nonequilibrium spin-dependent occupation of electron states in the ferromagnetic interlayer. While under the considered nonequilibrium conditions, the standard super…

Physics of Superconductivity and MagnetismQuantum and electron transport phenomenaMagnetic and transport properties of perovskites and related materials

Dynamics in the Process of Formation of Anisotropic Chitosan Hydrogel

Takao Yamamoto、Naoko Tomita、Yasuyuki Maki 等 4 位作者2010-07-21The Journal of Physical Chemistry B

To control the dynamics of dialysis-induced anisotropic gel formation, we have derived a theoretical expression for the development of the gel layer for a simple case where no cross-link sites for cross-linking agents exists and the inflow and the outflow of low molecular weight components through the dialysis membran…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesMicro and Nano Robotics

The Software Architecture of the New Vertical-Stabilization System for the JET Tokamak

Teresa Bellizio、G. De Tommasi、P. McCullen 等 8 位作者2010-07-21IEEE Transactions on Plasma Science

The need to improve the performance of modern tokamak operations has led to a further development of the plasma shape and position control systems. In particular, extremely elongated plasmas, with high vertical-instability growth rate, are envisaged to reach the required performance for ignition. This request for bett…

Magnetic confinement fusion researchFusion materials and technologiesSuperconducting Materials and Applications

Anti‐complement activity of isolated compounds from the roots of Clerodendrum bungei Steud.

Soo‐Ki Kim、Sangbuem Cho、Hyung‐In Moon2010-07-21Phytotherapy Research

To determine the anti-complement activity of natural diterpenes, chromatographic separation of the acetone-soluble fraction from the roots of Clerodendrum bungei (Verbenaceae) led to the isolation of five diterpenoids. An acetone-soluble extract of the roots of C. bungei exhibited significant anti-complement activity…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Improving Thermal Recovery Time for Soft-Starter-Connected AC Motors With Intermittent Periodic Duty Cycles

Pinjia Zhang、Yi Du、T.G. Habetler 等 4 位作者2010-07-21IEEE Transactions on Industry Applications

The thermal characteristics of de-energized ac motors are largely different from those of operating ac motors. For ac motors operated with intermittent periodic duty cycles, conventional techniques largely overestimate the required thermal recovery time in each operating cycle, which results in the reduction of usage…

Electric Motor Design and AnalysisSensorless Control of Electric MotorsMagnetic Properties and Applications

Reactive power compensation in a steel industrial plant with several operating electric arc furnaces utilizing open-loop controlled TCR/FC compensators

Arash Dehestani Kolagar、Arash Kiyoumarsi、Mohhamad Ataei 等 4 位作者2010-07-21European Transactions on Electrical Power

Electric arc furnaces (EAFs) produce voltage fluctuations and flicker because of the reactive power severe variations. Furthermore, these loads absorb a large amount of reactive power. The static VAr compensators (SVCs) have been widely used by the industrial customers with arc furnaces to compensate the reactive powe…

Power System Optimization and StabilityPower Quality and HarmonicsMagnetic Properties and Applications

Influence of Macrodiol on Phase Separation and Crystallization Processes in Hard-Phase Reinforced Polyurethane Elastomers Based on Isocyanates of Variable Conformational Mobility

Cristina Prisăcariu、Elena Scorţanu2010-07-21International Journal of Polymer Analysis and Characterization

An investigation was performed to determine how aspects of microstructural changes in polyurethane elastomers vary with composition: the hard segment and soft segment were varied in a family of six segmented copolyurethane elastomers. Two hard segments were compared, based on the rigid model diisocyanate 4,4′-methylen…

Polymer composites and self-healingComposite Material MechanicsInnovations in Concrete and Construction Materials

A Dynamically Entangled Coordination Polymer: Synthesis, Structure, Luminescence, Single‐Crystal‐to‐Single‐Crystal Reversible Guest Inclusion and Structural Transformation

A. Aijaz、Prem Lama、Parimal K. Bharadwaj2010-07-21European Journal of Inorganic Chemistry

Abstract A ZnII coordination polymer {[Zn2(cpa)2(bpy)]·3H2O}n (1) (cpa2– = 4‐(methoxycarbonyl)benzoate and bpy = 4,4′‐bipyridine) has been synthesized under solvothermal condition and structurally characterized. This coordination polymer has nanotubular threefold entangled (2D→3D) structure with embedded water molecul…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

The Influence of Solvent Processing on Polyester Bioabsorbable Polymers

Joanne Manson、Dorian Dixon2010-07-21Journal of Biomaterials Applications

Solvent-based methods are commonly employed for the production of polyester-based samples and coatings in both medical device production and research. The influence of solvent casting and subsequent drying time was studied using thermal analysis, spectroscopy and weight measurement for four grades of 50 : 50 poly(lact…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsAdvanced Drug Delivery Systems

Gastroprotective Activity Of Swietenia Mahagoni Seed Extract On Ethanol-Induced Gastric Mucosal Injury In Rats

Salma Saleh Alrdahe、Mahmood Ameen Abdulla、Shaharudin Abul Razak 等 5 位作者2010-07-21OpenAlex

Swietenia mahagoni have been used in traditional medicine for treatment of different diseases. Present study was performed to evaluate anti-ulcerogenic activity of ethanol seed extract against ethanol induced gastric mucosal injury in rats. Six groups of rats were orally pre-treated respectively with carboxymethyl cel…

Family Business Performance and SuccessionPhytochemical compounds biological activitiesPhytochemistry and Bioactive Compounds

Experimental and modeling studies on the solubility of sub‐ and supercritical carbon dioxide (scCO2) in potato starch and derivatives

Henky Muljana、Francesco Picchioni、Hero J. Heeres 等 4 位作者2010-07-21Polymer Engineering and Science

Abstract The solubility of CO2 in native potato starch (NPS) and potato starch acetate (SA) at two different temperatures (50°C and 120°C) and various pressures (up to 25 MPa) was determined using a magnetic suspension balance. Within the experimental window, a maximum solubility of 31 mg CO2/gsample for NPS and 79.4…

Phase Equilibria and ThermodynamicsPolymer Foaming and CompositesAdsorption, diffusion, and thermodynamic properties of materials