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Generation of colour centres in yttria-stabilized zirconia by heavy ion irradiations in the GeV range

Jean‐Marc Costantini、F. Beuneu、K. Schwartz 等 4 位作者2010-07-16Journal of Physics Condensed Matter

We have studied the colour centre production in yttria-stabilized zirconia (ZrO(2):Y(3 +)) by heavy ion irradiation in the GeV range using on-line UV-visible optical absorption spectroscopy. Experiments were performed with 11.4 MeV amu(-1) (127)Xe, (197)Au, (208)Pb and (238)U ion irradiations at 8 K or room temperatur…

Advanced Condensed Matter PhysicsIon-surface interactions and analysisNuclear materials and radiation effects

Synthesis of a New Hyperbranched Polyaminoester and Its Use as a Reactive Modifier in Anionic Curing of DGEBA Thermosets

Mireia Morell、Xavier Fernández‐Francos、Xavier Ramis 等 4 位作者2010-07-16Macromolecular Chemistry and Physics

Abstract The synthesis and characterization of a new hyperbranched PAE with a flexible structure and terminal hydroxyl groups is reported. The influence of PAE in the anionic curing of DGEBA with 1‐methylimidazole was studied. The curing reaction was investigated by DSC and FT‐IR. The covalent incorporation of the mod…

Epoxy Resin Curing ProcessesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Synthesis of Octaglycosylated Zinc(II) Phthalocyanines

Michael Hanack、Thomas Ziegler、Zafar Iqbal 等 5 位作者2010-07-16Synthesis

For the first time, octaglycosylated zinc(II) phthalocyanines in which the sugar part is protected by acetyl groups and the deprotected zinc(II) phthalocyanines were synthesized and characterized. The sugars glucose, galactose, lactose, cellobiose, and maltose are anomerically attached either via oxygen or sulfur to t…

Carbohydrate Chemistry and SynthesisPorphyrin and Phthalocyanine ChemistryFluorine in Organic Chemistry

Screening of the Raman response in multiband superconductors: Application to iron pnictides

C. Sauer、G. Blumberg2010-07-16Physical Review B

We performed model calculations of Raman responses for multiband two-dimensional superconductors. The multiband effects of screening in the ${A}_{1g}$ symmetry channel were investigated analytically and numerically for a band-structure model mimicking angle-resolved photoemission spectroscopy data on iron-pnictide mat…

Iron-based superconductors research

Expanding Micelle Nanolithography to the Self-Assembly of Multicomponent Core−Shell Nanoparticles

Beri N. Mbenkum、A. Dı́az-Ortiz、Lin Gu 等 5 位作者2010-07-16Journal of the American Chemical Society

Size, composition, and pattern formation are crucial elements in the fabrication of functional multicomponent nanoparticles (NPs). Self-assembly techniques provide relevant control over NP size distribution (down to a few nanometers in diameter), but more importantly, such techniques are amenable for practical applica…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsBlock Copolymer Self-Assembly

Changes in Small-Angle X-ray Scattering Parameters Observed upon Binding of Ligand to Rabbit Muscle Pyruvate Kinase Are Not Correlated with Allosteric Transitions

Aron W. Fenton、Rachel Williams、Jill Trewhella2010-07-16Biochemistry

Protein fluorescence and small-angle X-ray scattering (SAXS) have been used to monitor effector affinity and conformational changes previously associated with allosteric regulation in rabbit muscle pyruvate kinase (M(1)-PYK). In the absence of substrate [phosphoenolpyruvate (PEP)], SAXS-monitored conformational change…

Protein Structure and DynamicsEnzyme Structure and FunctionErythrocyte Function and Pathophysiology

Scaling of the elastic contribution to the surface free energy of a nematic liquid crystal on a sawtoothed substrate

José Enríque、Chi-Tuong Pham、P. Patrı́cio2010-07-16Physical Review E

We characterize the elastic contribution to the surface free energy of a nematic liquid crystal in the presence of a sawtooth substrate. Our findings are based on numerical minimization of the Landau-de Gennes model and analytical calculations on the Frank-Oseen theory. The nucleation of disclination lines (characteri…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsAdhesion, Friction, and Surface Interactions

Indium Tin Oxide@Carbon Core–Shell Nanowire and Jagged Indium Tin Oxide Nanowire

Yong Wang、Liqiang Lu、Fengdan Wu2010-07-16Nanoscale Research Letters

This paper reports two new indium tin oxide (ITO)-based nanostructures, namely ITO@carbon core-shell nanowire and jagged ITO nanowire. The ITO@carbon core-shell nanowires (~50 nm in diameter, 1-5 μm in length,) were prepared by a chemical vapor deposition process from commercial ITO nanoparticles. A carbon overlayer (…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsConducting polymers and applications

Functionalization of Linear and Star-Shaped Polyglycidols with Vinyl Sulfonate Groups and Their Reaction with Different Amines and Alcohols

Daniel Haamann、Helmut Keul、Doris Klee 等 4 位作者2010-07-16Macromolecules

Linear and star-shaped polyglycidols were prepared using ethoxy ethyl glycidyl ether (EEGE) as monomer and 3-phenyl-1-propanol and dipentaerythritol as initiator, respectively. These polymers were treated with 2-chloroethylsulfonyl chloride to form reactive vinyl sulfonate end groups. The high reactivity of the vinyl…

Dendrimers and Hyperbranched PolymersSynthesis and properties of polymersAntimicrobial agents and applications

Conductivity and dielectric constant of nanotube/polymer composites

Yuichi Hazama、Naoki Ainoya、Jun Nakamura 等 4 位作者2010-07-16Physical Review B

The complex ac admittance of a thin film of carbon nanotube/polymer composites depending on both the concentration and the alignment of nanotubes has been studied. The complex ac admittance and the current intensity distribution is numerically calculated using a transfer matrix method, where the discretized mesh model…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Structural Evolution of a Colloidal Crystal Fiber during Heating and Annealing Studied by in Situ Synchrotron Small Angle X-ray Scattering

Shanshan Hu、Jens Rieger、Zhiyong Yi 等 8 位作者2010-07-16Langmuir

The structural evolution of a colloidal crystal fiber during heating and annealing was followed by in situ synchrotron small-angle X-ray scattering. The polymer dispersion (with a particle size of 118 nm) from which the fibers were formed by directed drying contained emulsifier and salt. A cellular structure formed up…

Hydrogels: synthesis, properties, applicationsMaterial Dynamics and PropertiesAdvanced Cellulose Research Studies

Strong coupling to magnetic fluctuations in the charge dynamics of iron-based superconductors

Jason Hancock、Seyed Iman Mirzaei、J. Gillett 等 8 位作者2010-07-16Physical Review B

We present a comprehensive comparison of the infrared charge response of two systems, characteristic of classes of the 122 pnictide $({\text{SrFe}}_{2}{\text{As}}_{2})$ and 11 chalcogenide $({\text{Fe}}_{1.087}\text{Te})$ Fe compounds with magnetically ordered ground states. In the 122 system, the magnetic phase shows…

Iron-based superconductors research

Band structures and transport properties of zigzag graphene nanoribbons with antidot arrays

Ying‐Tao Zhang、Qingming Li、You‐Cheng Li 等 5 位作者2010-07-16Journal of Physics Condensed Matter

We study the band and transport features of zigzag graphene nanoribbon with an antidot lattice. It is found that an antidot lattice could turn semi-metal graphene into a semiconductor. The size of the band gap can be tuned by the position of the antidots and the distance D between the two nearest antidots. For a finit…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Investigating the plasma chemistry for the synthesis of carbon nanotubes/nanofibres in an inductively coupled plasma-enhanced CVD system: the effect of processing parameters

M Mao、Annemie Bogaerts2010-07-16Journal of Physics D Applied Physics

A parameter study is carried out for an inductively coupled plasma used for the synthesis of carbon nanotubes or carbon nanofibres (CNTs/CNFs), by means of the Hybrid Plasma Equipment Model. The influence of processing parameters including gas ratio for four different gas mixtures typically used for CNT/CNF growth (i.…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Nanoscale Precipitation Coating: The Deposition of Inorganic Films through Step-by-Step Spray-Assembly

Gabriela Popa、Fouzia Boulmedais、Peng Zhao 等 10 位作者2010-07-16ACS Nano

Thin films and surface coatings play an important role in basic and applied research. Here we report on a new, versatile, and simple method ("precipitation coating") for the preparation of inorganic films, based on the alternate spraying of complementary inorganic salt solutions against a receiving surface on which th…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesPolymer Surface Interaction Studies

Nonlinear behaviour of electrostatically actuated carbon nanotube-based devices

Mansour Rasekh、S.E. Khadem、Meisam Tatari2010-07-16Journal of Physics D Applied Physics

In this paper nonlinear behaviour of electrostatically actuated carbon nanotubes (CNTs) is investigated. The model comprises a clamped–clamped CNT suspended over a graphite ground electrode plate from which a potential difference is imposed. The actuation is based on ac and dc applied voltages and it is assumed that t…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Assessing a solids-biased density-gradient functional for actinide metals

Per Söderlind、A. Gonis2010-07-16Physical Review B

Recent developments of new electron exchange and correlation functionals within density-functional theory include a solids-biased modification of the popular Perdew-Burke-Ernzerhof (PBE) functional and is referred to as PBEsol. The latter is claimed to remove a bias toward free-atom energies in the former and is there…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsNuclear Materials and Properties

Embedded Binary Eutectic Alloy Nanostructures: A New Class of Phase Change Materials

S. J. Shin、J. Guzmán、Chris Yuan 等 14 位作者2010-07-16Nano Letters

Phase change materials are essential to a number of technologies ranging from optical data storage to energy storage and transport applications. This widespread interest has given rise to a substantial effort to develop bulk phase change materials well suited for desired applications. Here, we suggest a novel and comp…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Location of gap nodes in the organic superconductors κ−(ET)2Cu(NCS)2 and κ−(ET)2Cu[N(CN)2]Br determined by magnetocalorimetry

Liam Malone、O. Taylor、J.A. Schlueter 等 4 位作者2010-07-16Physical Review B

We report specific-heat measurements of the organic superconductors $\ensuremath{\kappa}\text{\ensuremath{-}}{(\text{ET})}_{2}\text{Cu}{(\text{NCS})}_{2}$ and $\ensuremath{\kappa}\text{\ensuremath{-}}{(\text{ET})}_{2}\text{Cu}[\text{N}{(\text{CN})}_{2}]\text{Br}$. When the magnetic field is rotated in the highly condu…

Magnetism in coordination complexesRare-earth and actinide compoundsOrganic and Molecular Conductors Research

The First Example of Main‐Chain Cyclic Azobenzene Polymers

Xu Xu、Nianchen Zhou、Jian Zhu 等 7 位作者2010-07-16Macromolecular Rapid Communications

A novel main-chain azobenzene cyclic polymer, cyclic-PEHPA, has been successfully synthesized by 'click' cyclization of the α-alkyne-ω-azido hetero-difunctional linear precursors (linear-PEHPA), which is synthesized by a step-growth polymerization of the 3'-ethynylphenyl[4-hexyl-(2-azido-2-methyl- propionate) phenyl]…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistrySynthesis and properties of polymers