Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Multilayer microcapsules showing unique charge-controlled permeability have been successfully fabricated by employing poly(styrene sulfonate) (PSS)-doped CaCO3 particles as templates. Encapsulation of the PSS molecules is thus achieved after core removal. Scanning force microscopy (SFM), UV-vis, Raman spectroscopy, an…
We have examined the influence of two aspects of surfactant structure--tail branching and tail organization--on the orientational ordering (so-called anchoring) of water-immiscible, thermotropic liquid crystals in contact with aqueous surfactant solutions. First, we evaluated the influence of branches in surfactant ta…
The synthesis of double-wall carbon nanotubes (DWCNTs) with highly unperturbed inner shells is reported using the catalytic vapor deposition method. Temperature dependent and high resolution Raman measurements show an enhanced phonon life-time of the inner tubes with respect to the outer ones and similar diameter SWCN…
The electron spin resonance (ESR) of nanoscale molecular magnet ${\rm V}_{15}$ is studied. Since the Hamiltonian of ${\rm V}_{15}$ has a large Hilbert space and numerical calculations of the ESR signal evaluating the Kubo formula with exact diagonalization method is difficult, we implement the formula with the help of…
We investigate the conformation of long polyelectrolyte chains attached to colloidal latex particles by cryogenic transmission electron microscopy (cryo-TEM). The dense grafting of the polyelectrolyte chains ("polyelectrolyte brush") leads to a confinement of the counterions and a concomitantly high osmotic pressure w…
A Ti4+-exchanged montmorillonite (Ti4+-mont) and a hydrotalcite (HT) are strong solid Brønsted acid and base, and these two clay catalysts could be used in a single reactor without neutralization of active sites. Because the Ti4+-mont have active acid site in the narrow interlayers, the base sites of large HT particle…
The formation of narrow size dispersed and nanometer size aggregates (clusters) of cadmium selenide (CdSe) quantum dots (QDs) and their temperature-sensitive photoluminescence (PL) spectral properties close to room temperature (298 K) are discussed. CdSe QDs formed stable clusters with an average diameter of approxima…
Working in the Wannier representation, we derive an expression for the orbital magnetization of a periodic insulator. The magnetization is shown to be comprised of two contributions, an obvious one associated with the internal circulation of bulk-like Wannier functions in the interior, and an unexpected one arising fr…
Magnetically Modulated Optical Nanoprobes (MagMOONs) are magnetic particles that indicate their angular orientation by emitting varying intensities of light for different orientations and have shown promise for a variety of applications. In this letter we describe a new method to fabricate uniform magnetic half-shell…
Recent experimental results on granular gas in Knudsen regime excited by a vibrating piston in micro-gravity have measured distribution p(I) of impacts I with a fix target. They give p(I) scaling as exp(-I/Io). This distribution leads to a probability distribution function of speed v along z varying approximately as f…
Abstract For Abstract see ChemInform Abstract in Full Text.
With six polymorphs coexisting at room temperature, 5-methyl-2-[(2-nitrophenyl)amino]-3-thiophenecarbonitrile (ROY) is the top system in the current Cambridge Structural Database (Feb. 2005) for the number of polymorphs of solved crystal structures. Here we report two new ROY polymorphs, Y04 and YT04, and the crystal…
We perform first principles calculations on work functions of single wall carbon nanotubes, which can be divided into two classes according to tube diameter (D). For class I tubes (D > 1 nm), work functions lie within a narrow distribution (approximately 0.1 eV) and show no significant chirality or diameter dependence…
ZnO nanocrystals with various shapes (see Figure) have been synthesized via non-hydrolytic ester elimination sol–gel reactions between zinc acetate and 1,12-dodecanediol. Uniform anisotropic cone-shaped, hexagonal cone-shaped, and rod-shaped ZnO nanocrystals have been synthesized using various surfactants.
Simulations of the absorption efficiency using the discrete dipole approximation (DDA) method and taking into account the real shape of gold nanorods are reported. A dominant surface plasma band corresponding to the longitudinal resonance is observed. Its maximum position lambda(max) shifts to the red as the aspect ra…
We investigated the two-photon-induced photoluminescence properties of single gold nanorods by scanning near-field spectroscopy. The process was found to be initiated by a sequential one-photon absorption for creating a pair of an electron and a hole in the sp and d bands. Photoluminescence is then radiated when the e…
This DOI is not currently attached to any metadata records. DOIs can’t actually ever be deleted (they’re persistent), but sometimes our members create DOIs in error. We do have a process to approximate deletion which we follow only in rare cases where the DOI has been genuinely created in error, and most crucially, if…
The contact fracture behaviors of fine-grained Ti3SiC2 and coarse-grained high purity Ti3SiC2 are examined by the Hertzian indentation and Vickers indentation technique. The Vickers hardness of bulk Ti3SiC2 is as low as 5.3~6.3 Gpa, and the Hertzian contact stress-strain curves for Ti3SiC2 deviate much from linearity,…
Sol-gel coatings of TiO2 have been prepared from TiO2 sol and deposited by a dip-coating technique on 316L stainless steel sheets to study their electrochemical behavior in corrosive solutions. The influence of the coatings on the chemical corrosion of the substrate was evaluated by potentiodynamic polarization curves…
It has been established that the new circular dichroism beamline CD12 has sufficiently high flux at low wavelengths to cause apparent irradiation problems with protein samples while their synchrotron radiation circular dichroism (SRCD) spectra are being collected. The cause of this effect has been extensively investig…