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FTIR spectroscopy combined with quantum chemical calculations to investigate adsorbed nitrate on aluminium oxide surfaces in the presence and absence of co-adsorbed water

Jonas Baltrušaitis、Jennifer D. Schuttlefield、Jan H. Jensen 等 4 位作者2007-01-01Physical Chemistry Chemical Physics

Surface reactions of nitrogen oxides with aluminium oxide particles result in the formation of adsorbed nitrate. Specifically, when alpha-Al(2)O(3) and gamma-Al(2)O(3) particles are exposed to gas-phase NO(2) and HNO(3) adsorbed nitrate forms on the surface. In this study, Fourier transform infrared (FTIR) spectroscop…

Catalytic Processes in Materials ScienceIndustrial Gas Emission ControlAdvanced Photocatalysis Techniques

Gelating-induced supramolecular chirality of achiral porphyrins: chiroptical switch between achiral molecules and chiral assemblies

Yuangang Li、Tianyu Wang、Minghua Liu2007-01-01Soft Matter

Chiral low molecular weight organogelators which can gel nearly all kinds of common organic solvents were designed. The gelators could also form organogels with other functional compounds, which could not form the organogel themselves. Achiral porphyrins were employed as functional compounds to form the co-gel with th…

Photochromic and Fluorescence ChemistryPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

Interfacial rheology of stable and weakly aggregated two-dimensional suspensions

Sven Reynaert、Paula Moldenaers、Jan Vermant2007-01-01Physical Chemistry Chemical Physics

The interfacial rheological properties of stable and weakly aggregated two-dimensional suspensions are studied experimentally using a magnetic rod interfacial rheometer. Particle monolayers with well controlled structures were prepared. Charged polystyrene particles create two-dimensional colloidal crystals at the wat…

Pickering emulsions and particle stabilizationMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Facile transformation of hydrophilic cellulose into superhydrophobic cellulose

Shenghai Li、Haibo Xie、Suobo Zhang 等 4 位作者2007-01-01Chemical Communications

Superhydrophobic cellulose-based materials coupled with transparent, stable and nanoscale polymethylsiloxane coating have been successfully achieved by a simple process via chemical vapor deposition, followed by hydrolyzation and polymerization.

Electrohydrodynamics and Fluid DynamicsSurface Modification and SuperhydrophobicityAdvanced Cellulose Research Studies

Solvent-free selective oxidation of benzyl alcohol by molecular oxygen over uranium oxide supported nano-gold catalyst for the production of chlorine-free benzaldehyde

Vasant R. Choudhary、Rani Jha、Prabhas Jana2007-01-01Green Chemistry

A detailed investigation on the production of chlorine-free benzaldehyde in the solvent-free oxidation of benzyl alcohol by O2 over nano-gold supported on U3O8 has been carried out. Influence of different catalyst parameters (different methods of gold deposition on U3O8, gold loading and particle size, and catalyst ca…

Oxidative Organic Chemistry ReactionsCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Highly spin-polarized tunneling in fully epitaxial Co2Cr0.6Fe0.4Al∕MgO∕Co50Fe50 magnetic tunnel junctions with exchange biasing

Takao Marukame、Takayuki Ishikawa、Shinya Hakamata 等 6 位作者2007-01-01Applied Physics Letters

Fully epitaxial magnetic tunnel junctions (MTJs) with exchange biasing were fabricated with a full-Heusler alloy Co2Cr0.6Fe0.4Al (CCFA) thin film and a MgO tunnel barrier, where a Co50Fe50 upper electrode was used in a synthetic ferrimagnetic Co50Fe50∕Ru∕Co90Fe10 trilayer exchange-biased with an IrMn layer through the…

Heusler alloys: electronic and magnetic propertiesMagnetic properties of thin filmsMagnetic and transport properties of perovskites and related materials

Silicon nitride ceramics - review of structure, processing and properties

Stuart Hampshire2007-01-01Journal of Achievements of Materials and Manufacturing Engineering

Purpose: Purpose of this paper is the applying of new technology in injection moulding technique and investigation of reinforcement of PC as dispersed phase inside PP matrix (Table 1). Second aim of work is enrichment of those composites by nanoclay and analyzing mechanical behaviour of nanocomposites. Design/methodol…

Material Properties and ApplicationsTribology and Wear AnalysisAdvanced ceramic materials synthesis

The Apparent Constant-Phase-Element Behavior of an Ideally Polarized Blocking Electrode

Vicky Mei-Wen Huang、Vincent Vivier、Mark E. Orazem 等 5 位作者2007-01-01Journal of The Electrochemical Society

Two numerical methods were used to calculate the influence of geometry-induced current and potential distributions on the impedance response of an ideally polarized disk electrode. A coherent notation is proposed for local and global impedance which accounts for global, local, local interfacial, and both global and lo…

Smart Materials for ConstructionCorrosion Behavior and InhibitionConcrete Corrosion and Durability

Metal complexes of cyclen and cyclam derivatives useful for medical applications: a discussion based on thermodynamic stability constants and structural data

Rita Delgado、Vı́tor Félix、Luı́s M. P. Lima 等 4 位作者2007-01-01Dalton Transactions

A series of the most common chelators used in magnetic resonance imaging (MRI) and in radiopharmaceuticals for medical diagnosis and tumour therapy, H(4)dota, H(4)teta, H(8)dotp and H(8)tetp, is examined from a chemical point of view. Differences between 12- and 14-membered tetraazamacrocyclic derivatives with methylc…

Lanthanide and Transition Metal ComplexesMagnetism in coordination complexesRadiopharmaceutical Chemistry and Applications

Glow Discharge Optical Emission Spectroscopy

Richard Payling、Thomas Nelis、Browner, Rick F 等 12 位作者2007-01-01RSC analytical spectroscopy series/RSC analytical spectroscopy monographs

Glow discharge optical emission spectroscopy (GDOES) is an essential technique for the direct analysis of bulk solids, for elemental surface analysis and for the depth profiling of thin films and industrial coatings. The technique has shown rapid growth in numbers of instruments, in breadth of applications, in improve…

Semiconductor materials and devicesAnodic Oxide Films and NanostructuresAnalytical Chemistry and Sensors

Study of Liquid Distribution during Capillary Rise in Fabrics Using an Electrical Resistivity Technique: Influence of Structure and Composition

Faten Fayala、Mohamed Hamdaouı、Patrick Perré 等 4 位作者2007-01-01Journal of Porous Media

An experimental technique has been developed for studying the liquid organization and distribution during capillary rise in fabrics. To detect the small quantity of water that travels along fabric, we used a new electrical method. This method is based on the measurement of the electrical resistance and led to the dete…

Textile materials and evaluationsAdvanced Cellulose Research StudiesDyeing and Modifying Textile Fibers

An Experimental Study on Thickness Loss of Wilton Type Carpets Produced with Different Pile Materials after Prolonged Heavy Static Loading. Part 2: Energy Absorption and Hysteresis Effect

Nihat Çelik、Erdem Koç2007-01-01Fibres and Textiles in Eastern Europe

In the first part of the article, an evaluation was made of the characteristic parameters defined as the squeezing susceptibility or compression sensitivity S, permanent deformation DP, elasticity E and resilience R, all quantities expressed in per cent, which determine the behaviours of carpets of different pile mate…

Natural Fiber Reinforced CompositesTextile materials and evaluationsMechanical Engineering and Vibrations Research

Synthesis-condition dependence of carbon nanotube growth by alcohol catalytic chemical vapor deposition method

Nobuhito Inami et al2007-01-01Science and Technology of Advanced Materials

We report the dependence of growth yield of single-walled carbon nanotubes (SWNTs) on heat-treatment time and catalyst film thickness by the alcohol catalytic chemical vapor deposition method. Three types of heat-treatment, synthesis of 30 min, synthesis of 30 min after annealing of 30 min, and synthesis of 60 min, we…

Fabrication of damascene Cu wirings using solid acidic catalyst

Keita Yagi et al2007-01-01Science and Technology of Advanced Materials

The copper damascene process is one of the most promising technologies for fabricating Cu wirings for electronic devices such as LSIs. In this research, the fabrication of damascene Cu wirings was conducted using solid acidic catalyst. When a Cu-plated wafer, whose oxide is a basic oxide is dipped into a mixture of ox…

Structural investigations of ε-FeGe at high pressure and low temperature

H. Wilhelm et al2007-01-01Science and Technology of Advanced Materials

The structural parameters of ε-FeGe have been determined at ambient conditions using single crystal refinement. Powder diffraction has been carried out to determine structural properties and compressibility for pressures up to 30 GPa and temperatures as low as 82 K. The discontinuous change in the pressure dependence…

Thermo-chemical properties and electrical resistivity of Zr-based arsenide chalcogenides

A. Schlechte, R. Niewa, M. Schmidt, G. Auffermann, Yu. Prots, W. Schnelle, D. Gnida, T. Cichorek, F. Steglich and R. Kniep2007-01-01Science and Technology of Advanced Materials

Ternary phases in the systems Zr–As–Se and Zr–As–Te were studied using single crystals of ZrAs1.40(1)Se0.50(1) and ZrAs1.60(2)Te0.40(1) (PbFCl-type of structure, space group P4/nmm) as well as ZrAs0.70(1)Se1.30(1) and ZrAs0.75(1)Te1.25(1) (NbPS-type of structure, space group Immm). The characterization covers chemical…

Preparation of titanium diboride TiB2 by spark plasma sintering at slow heating rate

Jürgen Schmidt et al2007-01-01Science and Technology of Advanced Materials

A systematic study of the spark plasma sintering of TiB2 starting from mixture of elemental powders was performed to investigate the temperature distribution between pressing tool and sinter body. The reaction mechanism and time-dependant evolution of the sintering behavior are established. The simultaneous applicatio…

Nanohot embossing using curved stage to replicate antireflection nanostructures onto light guide

Akihiro Funamoto et al2007-01-01Science and Technology of Advanced Materials

A nanohot embossing using a curved stage is proposed to improve the replication ratio of nanostructures at near the edge of a thick (sub-mm-order thickness) polymer substrate. The lower replication ratio at near the edge resulting from a conventional hot embossing is due to lower compressive stress, which is simulated…

Photosynthesis of hydrogen and methane as key components for clean energy system

Seng Sing Tan et al2007-01-01Science and Technology of Advanced Materials

While researchers are trying to solve the world's energy woes, hydrogen is becoming the key component in sustainable energy systems. Hydrogen could be produced through photocatalytic water-splitting technology. It has also been found that hydrogen and methane could be produced through photocatalytic reduction of carbo…